Ti3+ in Fluoride Crystals

D. R. Gabbe; H. P. Jenssen

doi:10.1364/ASSL.1985.ThB3

Advanced Solid State Lasers
OSA Technical Digest (Optica Publishing Group, 1985),
paper ThB3
•https://doi.org/10.1364/ASSL.1985.ThB3

Ti³⁺ in Fluoride Crystals

D. R. Gabbe and H. P. Jenssen

Advanced Solid State Lasers 1985

Arlington, Virginia United States
ISBN:

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Titanium-Doped Sapphire (ThB)

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D. R. Gabbe and H. P. Jenssen, "Ti3+ in Fluoride Crystals," in Advanced Solid State Lasers, Vol. 85.8 of OSA Technical Digest (Optica Publishing Group, 1985), paper ThB3.

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Abstract

In general, Ti³⁺ is more easily incorporated in fluoride crystals than in oxide crystals. The characteristic absorption and emission of Ti³⁺ has been observed in both K₂NaScF₆ and SrAlF₅, Compared to Al₂O₃ the spectra are, as expected, red shifted. At cryogenic temperatures the fluorescent quantum efficiency is high and the fluorescent lifetime is appreciably longer than in Al₂O₃. At room temperature the emission is almost completely quenched in the crystals studied so far.

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