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  • Conference on Lasers and Electro-Optics
  • OSA Technical Digest (Optica Publishing Group, 1993),
  • paper CWJ90

Effects of intrachain double bonds on ultrafast exciton relaxation in poly-alkyl and poly-alkoxy thiophenes

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Abstract

Among conjugated polymers with large non-linear optical susceptibilities and fast time response, poly-alkyl and poly-alkoxy thiophenes are gaining considerable interest in all optical switching and high-speed optoelectronics since they are soluble, chemically stable, and easily processable. Because of non-degeneracy of ground state and strong electron-phonon coupling, electron-hole pairs produced after photoexcitation remain bound to form self-trapped excitons, whose relaxation dynamics has been recently studied in poly(alkyl-thiophene)s.1,2

© 1993 Optical Society of America

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