Probing Local Structure of Ionic Liquids with Picosecond Time-resolved Raman Spectroscopy

Koichi Iwata; Kyosuke Yoshida; Hiro-o Hamaguchi

Conference on Lasers and Electro-Optics/Pacific Rim 2007
(Optica Publishing Group, 2007),
paper WB3_7

Probing Local Structure of Ionic Liquids with Picosecond Time-resolved Raman Spectroscopy

Koichi Iwata, Kyosuke Yoshida, and Hiro-o Hamaguchi

Conference on Lasers and Electro-Optics/Pacific Rim 2007

Seoul Republic of Korea
ISBN: 1-4244-1174-2

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Chemistry (WB3)

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K. Iwata, K. Yoshida, and H. Hamaguchi, "Probing Local Structure of Ionic Liquids with Picosecond Time-resolved Raman Spectroscopy," in Conference on Lasers and Electro-Optics/Pacific Rim 2007, (Optica Publishing Group, 2007), paper WB3_7.

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Abstract

Vibrational cooling kinetics of the first excited singlet (S₁) state of trans-stilbene in ionic liquids was measured with picosecond time-resolved Raman spectroscopy. There was no correlation observed between the cooling rate and the thermal diffusivity of the solvent, suggesting the presence of local structures in the ionic liquids.

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