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Observation of Single Molecule Dynamic Behaviors with SERS: Desorption and Conformation Switching

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Abstract

Reproducible ultrahigh SERS enhancement in deterministic plasmonic hotspots allows chemical events on the single molecule level to be observed in real time, including plasmon-driven dimerization of 4NBT to DMAB, DMAB desorption and trans-cis conformation switching.

© 2016 Optical Society of America

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