2D-IR Spectroscopy of Intermolecular Ion-Water Coupling

Joanna Borek; Fivos Perakis; Peter Hamm

doi:10.1364/HILAS.2012.JT2A.40

Research in Optical Sciences
OSA Technical Digest (Optica Publishing Group, 2012),
paper JT2A.40
•https://doi.org/10.1364/HILAS.2012.JT2A.40

2D-IR Spectroscopy of Intermolecular Ion-Water Coupling

Joanna Borek, Fivos Perakis, and Peter Hamm

High Intensity Lasers and High Field Phenomena 2012

Berlin Germany
19–21 March 2012
ISBN: 978-1-55752-939-8

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J. Borek, F. Perakis, and P. Hamm, "2D-IR Spectroscopy of Intermolecular Ion-Water Coupling," in Research in Optical Sciences, OSA Technical Digest (Optica Publishing Group, 2012), paper JT2A.40.

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Abstract

We present 2–color 2D–IR spectra of saturated aqueous solutions of pseudohalide and azide ions to extract the intermolecular coupling between the ion and its surrounding water molecules and thus measure solvation shell dynamics.

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