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Ultrafast changes in lattice symmetry probed by coherent phonons at the onset of the photoinduced phase transition in VO2

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Abstract

We show that the coherent phonon spectrum, probed by whitelight spectroscopy, can be a marker for photoinduced structural transitions. In VO2, the lattice potential symmetry is completely changed on ultrafast timescales before ionic motion occurs.

© 2012 Optical Society of America

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