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Optica Publishing Group
  • International Quantum Electronics Conference
  • OSA Technical Digest (Optica Publishing Group, 1986),
  • paper WII3

Raman spectrum of predissociating H2S

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Abstract

Emission spectroscopy of photodissociating molecules provides interesting insights into the short-time dynamics of bond ruptures.1,2 We report here a resolved H2S photoemission spectrum after excitation at 193 nm, although its electronic spectrum in this wavelength region is diffuse. The electronic spectrum of H2S between 250 and 170 nm is nearly continuous probably due to predissociation X˜(1A1)1B11A2.3

© 1986 Optical Society of America

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