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Conferences > LS > 2009 > LSTuC > LSTuC4
  • Frontiers in Optics 2009/Laser Science XXV/Fall 2009 OSA Optics & Photonics Technical Digest
  • OSA Technical Digest (CD) (Optica Publishing Group, 2009),
  • paper LSTuC4
  • •https://doi.org/10.1364/LS.2009.LSTuC4

Ultrafast Soft X-ray Spectroscopy of Spin-crossover Dynamics in Solvated Transition-metal Complexes

N. Huse, H.-N. Cho, T.-K. Kim, L. Jamula, J. K. McCusker, and R. W. Schoenlein

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Abstract

We report the first femtosecond time-resolved soft x-ray measurements of solvated transition-metal complexes. L-edge spectroscopy directly reveals dynamic changes in ligand field splitting of 3d-orbitals associated with the spin transition, and mediated by ligand-bond changes.

© 2009 APS DLS

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