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Photophysical Consequences of Interactions between Conjugated Chromophores

S. Paquette, J. Rhinehart, D. McCamant, L. Rothberg, O. Kas, M. Charati, M. Galvin, and K. Kiick

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Abstract

We have studied phenylenevinylene chromophore pairs whose spacing and orientation are varied by coupling them to peptide backbones. Copious interchromophore photoexcitations are observed and explain reduced fluorescence yields in conjugated polymer films relative to solutions.

© 2010 Optical Society of America

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