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Electronic Energy Transfer Between Donor and Acceptor Adlayers on Single-Crystal Surfaces: Distance and Coverage Dependence

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Abstract

Electronic energy transfer in surface adlayers is a mechanism of fundamental importance to surface photochemical processes. In this study, the electronic energy transfer from a donor p-terphenyl (TP) adlayer to an acceptor 9,10-diphenylanthracene (DPA) adlayer was studied using quantum yield measurements at 30 K and 85 K. These investigations employed an Al2O3(0001) crystal surface as a two-dimensional support on which donor, spacer and acceptor adlayers could be sequentially adsorbed. The quantum yield measurements were performed in ultra high vacuum (UHV) utilizing laser induced fluorescence techniques.

© 1991 Optical Society of America

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