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Electronic/electrochemical alternation of a novel acceptor molecule Yb@C80 via simple chemical transformation

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Abstract

Metal-doped fullerenes are known as novel acceptor molecules in organic photovoltaics. We present the first chemical modification of a divalent metallofullerene Yb@C80 by carbene addition. Spectroscopic and crystallographic data suggest that its electronic and electrochemical properties have been effectively altered upon chemical functionalization.

© 2013 Optical Society of America

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