Abstract

Three-photon ionization is measured as the frequency of an optical pulse is tuned through two-photon resonance with the Rydberg series of potassium. When the intermediate Rydberg resonance is far below the ionization threshold, the standard resonance profile indicates the enhancement due to a single isolated level. However, as the frequency is tuned closer to threshold, continuous behavior is reached because of the coherent bandwidth of the short pulse and power broadening of the bound-bound transition line. Between these two limiting regions a transition region is observed where discrete and continuous features are manifested. The discrete nature is seen through resonance peaks that blend together as the threshold is approached. The continuous nature manifests itself through the creation of a coherent superposition state that produces localized radial motion. The laser pulse effectively probes the radial orbital motion of this wave packet. Since the ionization rate is drastically reduced while the wave packet is far from the core, drops in the ion signal are seen when the number of times the wavepacket can return to the core is reduced by one. These drops are abrupt because the electron travels much faster near the core in these highly elliptical orbits.

© 1992 Optical Society of America