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Conferences > OAM > 1993 > ThDDD > ThDDD.3

Femtosecond chemistry of O2/Pd(111): phonon-assisted electronic effects

J. A. Misewich, T. F. Heinz, A. Kalamarides, and M. M. T. Loy

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Abstract

Ultrafast laser pulses can produce high transient electronic temperatures (thousands of degrees) in a metal with only a modest rise in the lattice temperature. Recent studies of the desorption of NO molecules from a Pd(111) surface under such conditions revealed a novel desorption mechanism1 associated with this high electronic temperature.

© 1993 Optical Society of America

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