Abstract

Electrochromic smart windows are able to vary their throughput of radiant energy by low-voltage electrical pulses. This function is caused by reversible shuttling of electrons and charge balancing ions between an electrochromic thin film and a transparent counter electrode. The ion transport takes place via a solid electrolyte. Charge transport is evoked by a voltage applied between transparent electrical conductors surrounding the electrochromic film/electrolyte/counter electrode stack. This review summarizes recent progress concerning (i) calculated optical properties of crystalline WO₃, (ii) electrochromic properties of heavily disordered W oxide and oxyfluoride films produced by reactive magnetron bias sputtering, (iii) novel transparent reactively sputter deposited Zr-Ce oxide counter electrodes, and (iv) a new proton-conducting antimonic-acid-based polymer electrolyte. Special in-depth presentations are given on elastic light scattering from W-oxide-based films and of electronic bandstructure effects affecting opto-chronopotentiometry data in Zr-Ce oxide. The review also contains some new device data for an electrochromic smart window capable of very high optical transmittance.

© 1998 Optical Society of America