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On Determining the Carbon Budget (CO2 and CO) of the Lower Thermosphere from Non-Equilibrium Infrared Radiance

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Abstract

The high resolution (1 cm-1) limb emission spectra taken with the CIRRIS 1A interferometer on STS-39 over tangent heights from 50 to 200 km provides an opportunity to test the detailed non-LTE models of the emission and investigate methods for determining the carbon budget of the lower thermosphere from coincident measurement of the 4.3 μm CO2 v3 band and the 4.7 μm CO band. Earlier theory (Kumer and James, 1977, López-Puertas et. al., 1986, López-Puertas and Taylor, 1989) did not have high resolution spectral data to thoroughly validate their theories. López-Puertas and Taylor (1989) compared their models to SAMS data, a situation that needed an additional line-by-line model to filter their model results in a manner similar to the pressure modulated radiometer measurement. The high resolution spectra provide a much more stringent test of the theoretical non-LTE infrared emission models. We limit our discussion to the daytime spectra for a number of reasons. (1) The solar excitation leads to a large increase in signal, increasing the altitude to which good spectra can be obtained, (2) the domination of solar excitation simplifies the determination of the CO and CO2 densities since other non-local earthshine processes become less important, and (3), the solar excitation of the CO2v3 states yields a rich spectrum including isotopic and hot-band emission.

© 1993 Optical Society of America

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