Thermally Robust Electro-Optic Polymers

Christopher R. Moylan; Sally A. Swanson; Robert J. Twieg; C.A. Walsh; John I. Thackara; Robert D. Miller; Victor Y. Lee

doi:10.1364/OTFA.1993.WD.5

Organic Thin Films for Photonic Applications
Technical Digest Series (Optica Publishing Group, 1993),
paper WD.5
•https://doi.org/10.1364/OTFA.1993.WD.5

Thermally Robust Electro-Optic Polymers

Christopher R. Moylan, Sally A. Swanson, Robert J. Twieg, C.A. Walsh, John I. Thackara, Robert D. Miller, and Victor Y. Lee

Organic Thin Films for Photonic Applications 1993

Ontario Canada
5–7 October 1993
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C. R. Moylan, S. A. Swanson, R. J. Twieg, C. A. Walsh, J. I. Thackara, R. D. Miller, and V. Y. Lee, "Thermally Robust Electro-Optic Polymers," in Organic Thin Films for Photonic Applications, Technical Digest Series (Optica Publishing Group, 1993), paper WD.5.

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Abstract

Rational design of high-temperature stable electro-optical poled polymer materials requires custom synthesis of nonlinear chromophores, accurate measurement of their molecular hyperpolarizabilities and thermal stabilities, calculations to predict their nonlinearities at the desired wavelength, incorporation into thermally robust polymers, fabrication of test devices, and measurement of electro-optic coefficients. In this work, we describe the results of each step in this sequence for a variety of chromophores.

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