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Optical Response of a Chiral Molecule and Circular Dichroism in Second-Harmonic Generation

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Abstract

Surface second-harmonic generation has been found experimentally and theoretically to be capable of detecting chirality of a surface and of discriminating between the two enantiomers of a chiral molecule. ’ We calculate the second-order nonlinear optical response of a chiral molecule using a simple classical model and calculate the circular dichroism in second-harmonic generation from a thin film of chiral molecules.

© 1995 Optical Society of America

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