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Optica Publishing Group
  • Quantum Electronics and Laser Science Conference
  • OSA Technical Digest (Optica Publishing Group, 1991),
  • paper QWD43

Exicted electronic states of the tropyl (cyclo-C7H7) radical observed by resonance-enhanced multiphoton ionization spectroscopy

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Abstract

The tropyl radical has been prepared in a flow reactor [hydrogen abstraction from cyeloheptatriene (c-C7H8) by F or Cl] The spectra have been observed by resonance-enhanced multiphoton ionization (REMPI). The spectra are much stronger than, and distinct from, the spectra of the isomeric benzyl radical (C6-H5CH2), which was prepared in a similar manner. Spectra of these isomeric radicals will be useful for studying the combustion of aromatic hydrocarbons.

© 1991 Optical Society of America

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