Abstract
There has been much recent attention given to understanding the effects of ultrafast solvent relaxation dynamics on the rates of chemical reactions in solution. For certain adiabatic electron-transfer reactions, the reaction coordinate is closely identified with the solvent relaxation coordinate1. Many of the rapid motions occurring in room temperature solution have previously been characterized individually. What we present are new femtosecond nonlinear optical spectroscopy results on some of the liquids thought to have "slow" relaxation, namely triacetin (CH3CO2CH2)2CH(O2CCH3) and ethylene glycol (1,2 ethanediol).
© 1993 Optical Society of America
PDF ArticleMore Like This
Yong Joon Chang and Edward W. Castner
TuD.17 International Conference on Ultrafast Phenomena (UP) 1994
Hans P. Deuel, Peijun Cong, and John D. Simon
WC.7 International Conference on Ultrafast Phenomena (UP) 1994
S Pommeret, T Gustavsson, J-C Mialocq, A Sackreiter, E Zeek, S Backus, HC Kapteyn, and MM Murnane
WL26 International Quantum Electronics Conference (IQEC) 1996