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  • Spectral Hole-Burning and Luminescence Line Narrowing: Science and Applications
  • Technical Digest Series (Optica Publishing Group, 1992),
  • paper TuB7
  • https://doi.org/10.1364/SHBL.1992.TuB7

Proteins and Pressure: Compressibilities and Volume Fluctuations as measured by Spectral Hole Burning

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Abstract

Spectral Holes are extremely sensitive to external pressure changes Ap [1], They shift and broaden already at pressure changes as low as 0.1 MPa. In this paper we focus on the frequency shift s of the holes. The frequency shift can be interpreted in a simple way on the basis of two system parameters. These are the isothermal compressibility n and the solvent shift v, of the burnt molecules: The conditions under which eq. 1 holds follow from the more general Laird-Skinner model [2].

© 1992 Optical Society of America

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