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Transient Vibrational Heating of Molecules after Internal Conversion

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Abstract

After electronic excitation most organic molecules return to the electronic ground state via radiationless processes. Internal conversion is one of the most important relaxation mechanisms. There exists a great number of data on internal conversion rates which give only information on the time required by an ensemble of molecules to return from the first excited electronic state to the ground state So. After internal conversion the energy still resides in the individual molecule.

© 1986 Optical Society of America

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