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Solvation and Barrierless Electron Transfer : How Different Are the Dynamics?

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Abstract

Dynamic polar solvent effects on barrierless electron transfer reactions have been a subject of several detailed experimental studies in the recent years1. These studies have revealed a clear connection between dynamics of electron transfer from a locally excited (LE) state and the dynamics of solvation of the newly formed charge transfer state.

© 1990 Optical Society of America

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