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Conferences > UP > 1990 > MD > MD2

The Role of Vibrational Energy in the Ultrafast Photodissociation of Chromiumhexacarbonyl — A picosecond Raman Investigation

Soo-Chang Yu, Xiaobing Xu, Robert Lingle, and J.B. Hopkins

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Abstract

Photodissociation of Cr(CO)6 results in the loss of CO to form Cr(CO)5. In solution the pentacarbonyl species rapidly coordinates to the solvent and can therefore be used as a probe of solvent dynamics. Recent ultrafast studies of this simple reaction have resulted in controversy(1-6) regarding the dynamics of these various processes. We have used picosecond transient Raman spectroscopy to investigate the detailed dynamics of this reaction.

© 1990 Optical Society of America

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