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Conferences > UP > 1994 > WC > WC.7

Importance of Femtosecond Solvent Motions on Electron-Transfer Reactions: A Study of Electrolyte Solutions

Hans P. Deuel, Peijun Cong, and John D. Simon

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Abstract

Electrolytes can influence chemical reaction dynamics in vastly different ways. In this paper we focus our attention on fast solvent motions in electrolyte solutions and their effect on the rate constants of electron transfer reactions. The experimental methodologies employed in this paper are femtosecond optically-heterodyne-detected Raman-induced-Kerr-effect spectroscopy (OHD RIKES) and transient absoption spectroscopy.

© 1994 Optical Society of America

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