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Ultrafast Infrared Studies of Ligand Rearrangement at Coordinatively Unsaturated Transition Metal Centers

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Abstract

Femtosecond infrared spectroscopy has been applied to the study of ligand rearrangement dynamics of coordinatively unsaturated transition metal complexes. A new site-diffusion model based on the Langevin equations is proposed to describe the observed rearrangement dynamics.

© 2000 Optical Society of America

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