Ultrafast Solute Vibrational Spectral Change in Solvation Process

John B. Asbury; Yongqiang Wang; Tianquan Lian

doi:10.1364/UP.2000.TuF57

Ultrafast Phenomena
OSA Trends in Optics and Photonics (Optica Publishing Group, 2000),
paper TuF57
•https://doi.org/10.1364/UP.2000.TuF57

Ultrafast Solute Vibrational Spectral Change in Solvation Process

John B. Asbury, Yongqiang Wang, and Tianquan Lian

International Conference on Ultrafast Phenomena 2000

Charleston, South Carolina United States
ISBN: 1-55752-640-0

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Poster Session 2 (TuF)

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J. B. Asbury, Y. Wang, and T. Lian, "Ultrafast Solute Vibrational Spectral Change in Solvation Process," in Ultrafast Phenomena, T. Li, ed., Vol. 43 of OSA Trends in Optics and Photonics (Optica Publishing Group, 2000), paper TuF57.

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Abstract

Using femtosecond infrared spectroscopy, we have found that the magnitude and dynamics of CO stretch frequency shift of Re(dmbpy)(CO)₃Cl in its MLCT excited state varied with the polarity and solvation time in a series of solvents.

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