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Vibrational mode-specific ultrafast photodissociation dynamics of chlorine dioxide in solution

H. Fidder, F. Tschirschwitz, O. Dühr, and E. T. J. Nibbering

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Abstract

We show that solution-phase photodissociation of OClO in the A2A2-state exhibits vibrational mode-specific features. We monitor wave-packet motions around 400 nm and deduce that some vibronic states live longer than 1 ps in solution.

© 2000 Optical Society of America

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