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Optica Publishing Group
  • The Thirteenth International Conference on Ultrafast Phenomena
  • 2002 OSA Technical Digest Series (Optica Publishing Group, 2002),
  • paper MD3
  • https://doi.org/10.1364/UP.2002.MD3

Directly measuring the coupling of solvent intermolecular modes to photoinduced chemical reaction

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Abstract

Resonant pump off-resonant probe OKE spectroscopy was performed to study the coupling of solvent molecular modes to the electronic excitation of the solute. The intermolecular solvent modes of a range of polar and polarizable solvent including chloroform and acetonitrile respond differently to the electronic excitation of Coumarin 153.

© 2002 Optical Society of America

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