A 40-fs time-resolved absorption study of cis-stilbene in solution: observation of coherent nuclear wavepacket motion in reactive excited state

Kunihiko Ishii; Satoshi Takeuchi; Tahei Tahara

14th International Conference on Ultrafast Phenomena
Technical Digest (CD) (Optica Publishing Group, 2004),
paper TuE31

A 40-fs time-resolved absorption study of cis-stilbene in solution: observation of coherent nuclear wavepacket motion in reactive excited state

Kunihiko Ishii, Satoshi Takeuchi, and Tahei Tahara

International Conference on Ultrafast Phenomena 2004

Niigata Japan
25–30 July 2004
ISBN: 3-54024-110-8

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Poster Session II (Exhibition) (TuE)

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K. Ishii, S. Takeuchi, and T. Tahara, "A 40-fs time-resolved absorption study of cis-stilbene in solution: observation of coherent nuclear wavepacket motion in reactive excited state," in 14th International Conference on Ultrafast Phenomena, Technical Digest (CD) (Optica Publishing Group, 2004), paper TuE31.

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Abstract

Photoisomerization reaction of cis-stilbene in solution was studied by time-resolved absorption spectroscopy with 40-fs resolution. Rapidly damping coherence of a ~220 cm⁻¹ vibrational mode was observed in the reactive excited state.

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