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Multidimensional Infrared Spectroscopy of a Peptide NH⋯O Intramolecular Hydrogen Bond

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Abstract

Stimulated three pulse photon echoes and heterodyned 2D-IR echoes of acetylproline- NHMe in CHCl3 are reported. Multidimensional IR spectroscopy clearly shows the potential to disentangle congested spectra by spreading them into two dimensions and expose multiple structures.

© 2006 Optical Society of America

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