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Coherent Nuclear Motion of Blue Copper Protein; Plastocyanin: Comparing LMCT and d-d Excitation

Yutaka Nagasawa, Kenji Fujita, Tetsuro Katayama, Yukihide Ishibashi, Hiroshi Miyasaka, Teruhiro Takabe, Satoshi Nagao, and Shun Hirota

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Abstract

Ultrafast transient absorption measurement was carried out for a blue copper protein, plastocyanin, with excitation at LMCT (597 nm) and d-d band (895 nm). Franck-Condon and Herzberg-Teller type coherent nuclear oscillations were observed.

© 2010 Optical Society of America

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