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Conferences > UP > 2014 > 07.Mon.P1 > 07.Mon.P1.20

Detection of the G(–H)● Radical in the Electronic Deactivation of the G–C Watson-Crick Base Pair

Katharina Röttger and Friedrich Temps

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Abstract

Transient absorption spectroscopy of the G–C base pair revealed the formation of the G(–H)● radical with lifetime 3 ps in the electronic deactivation. This radical is the key intermediate in an electron-coupled proton transfer.

© 2014 Optical Society of America

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