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Ultrafast Time-Domain Raman Study to Visualize Large-Amplitude Distortions in Copper Complexes

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Abstract

Time-resolved impulsive-Raman with narrowband photoexcitation was utilized to study structural dynamics of bis-diimine copper complex in solution. A copper-ligand symmetric stretch band showed up with frequency oscillation, demonstrating its anharmonic coupling with large-amplitude distortional motions.

© 2014 Optical Society of America

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