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Femtosecond Molecular Flattening in [Cu(dmp)2]+ Probed by X-ray Emission Spectroscopy and Solution Scattering

Tae-Kyu Choi, Dmitry Khakhulin, György Vankó, Zoltán Németh, Jakub Szlachetko, Makina Yabashi, Thomas J. Penfold, Wojciech Gawelda, and Tetsuo Katayama

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Abstract

Femtosecond electronic and nuclear dynamics in [Cu(dmp)2]+ complex upon 550 nm photoexcitation are studied with X-ray emission spectroscopy and X-ray solution scattering, revealing pseudo Jahn-Teller distortion (~410 fs) coupled with coherent vibrational motion.

© 2020 The Author(s)

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