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Direct Confirmation of the Woodward-Hoffmann Rule by Femtosecond Transient Soft X-ray Absorption

T. Sekikawa, N. Saito, Y. Kurimoto, N. Ishii, T. Mizuno, T. Kanai, J. Itatani, K. Saita, and T. Taketsugu

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Abstract

The chemical shifts of the carbon K-edge during the ring-opening dynamics of 1,3-cyclohexadiene observed by femtosecond transient soft X-ray absorption confirm that the stereochemistry of the ring-opening reaction follows the Woodward-Hoffmann rule.

© 2022 The Author(s)

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