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Sub-10fs Photocurrent and Photoluminescence Action Spectroscopies of Organic Optoelectronic Devices Reveals Ultrafast Formation of Bound Excitonic States

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Abstract

We apply ultrafast pump-push-photocurrent and pump-push-photoluminescence spectroscopies to polyfluorene organic diode to track in time the bound exciton formation. ‘Cold’-excitons become bound within 10-fs while ‘hot’-excitons can dissociate spontaneously within 50-fs before acquiring bound character.

© 2022 The Author(s)

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Ultrafast spectroscopy of organic semiconductors

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