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Hot-charge relaxation in lead halide perovskite: uncovering the bandgap dynamics, hot-biexciton effect and photo-bleaching shift

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Abstract

The hot-charge relaxation mechanisms remain contentious in lead halide perovskites, though regarded as frontrunners for future photovoltaics. A model uncovering the spectral and temporal band-edge evolution provides novel insights into many-body interplay and photo-bleaching shift.

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