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Ultrafast Dynamics of RuII-polypyridyl Complexes – Photoinduced Ligand Dissociation Dynamics in Gas Phase and Solution

R. Israil, L. Schüssler, M. Schmitt, M. Grupe, P. Hütchen, W. R. Thiel, R. Diller, and C. Riehn

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Abstract

Ultrafast electronic dynamics and UV absorption of [RuII(bipyridine)2(nicotinamide)2]2+ isolated in an ion trap reveal by transient photodissociation short time constants and spectra comparable to transient absorption in solution. Ligand dissociation dynamics are elucidated.

© 2022 The Author(s)

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