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Circular dichroism of poly-D-glutamic acid adsorbed on air–water interfaces

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Abstract

A quartz cuvette was modified for use to determine the circular dichroism of molecules in thin films at air–water interfaces. By an application of the cuvette, circular dichroism spectra of poly-D-glutamic acid at air–water interfaces have been compared with circular dichroism spectra of the sample in aqueous solution. The results show that poly-D-glutamic acid is a beta structure on the surface of the solution in which the alpha helix or random coil is stable.

© 1975 Optical Society of America

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