Infrared methane spectra between 1120 cm<sup>−1</sup> and 1800 cm<sup>−1</sup>: a new atlas

R. D. Blatherwick; A. Goldman; B. L. Lutz; P. M. Silvaggio; R. W. Boese

doi:10.1364/AO.18.003798

Applied Optics
Vol. 18,
Issue 22,
pp. 3798-3804
(1979)
•https://doi.org/10.1364/AO.18.003798

Infrared methane spectra between 1120 cm⁻¹ and 1800 cm⁻¹: a new atlas

R. D. Blatherwick, A. Goldman, B. L. Lutz, P. M. Silvaggio, and R. W. Boese

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R. D. Blatherwick, A. Goldman, B. L. Lutz, P. M. Silvaggio, and R. W. Boese, "Infrared methane spectra between 1120 cm⁻¹ and 1800 cm⁻¹: a new atlas," Appl. Opt. 18, 3798-3804 (1979)

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Abstract

A new atlas of CH₄ lines in the 1120–1800-cm⁻¹ region has been generated, based on laboratory spectra taken with a Nicolet interferometer at 0.06-cm⁻¹ resolution with 635-cm path length at pressures of 0.98 Torr, 4.86 Torr, and 19.97 Torr. A compilation of line positions and line intensities includes 1339 CH₄ lines, several hundred of which have not been previously observed.

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SEQ. NO.	POSITION (cm⁻¹)	$S (\frac{cm}{molecule})$
1	1200.707	3.5E-23
2	1200.778	3.6E-23
3	1201.134	1.1E-21
4	1201.643	2.7E-22
5	1201.760	4.9E-23
6	1202.422	6.6E-22
7	1202.724	5.3E-22
8	1203.042	1.9E-22
9	1203.181	1.9E-22
10	1203.387	1.7E-22
11	1203.583	1.4E-22
12	1203.692	1.1E-22
13	1204.034	4.4E-22
14	1204.328	3.3E-23
15	1204.768	2.6E-23
16	1205.401	2.4E-23
17	1205.651	4.6E-23
18	1205.928	2.2E-22
19	1206.030	3.1E-23
20	1207.835	1.1E-21
21	1208.701	5.2E-23
22	1209.695	2.8E-22
23	1209.808	4.1E-22
24	1209.920	9.0E-23
25	1210.000	1.3E-21
26	1210.078	7.8E-22
27	1210.672	1.9E-21
28	1210.786	9.4E-22
29	1211.328	6.4E-22
30	1211.676	2.8E-23
31	1211.878	1.4E-21
32	1211.984	8.0E-21
33	1212.287	3.0E-23
34	1212.715	1.7E-23
35	1213.186	2.5E-23
36	1213.544	5.3E-23
37	1214.058	5.8E-23
38	1214.365	1.6E-23
39	1214.684	4.9E-23
40	1215.660	5.8E-23
41	1215.950	1.5E-22
42	1216.205	5.2E-21
43	1216.326	1.0E-21
44	1216.630	8.2E-22
45	1217.272	2.2E-23
46	1217.448	5.2E-23
47	1217.624	1.8E-21
48	1217.990	2.0E-21
49	1218.628	1.9E-21
50	1218.744	2.1E-23
51	1218.947	2.6E-23
52	1219.082	4.9E-23
53	1219.648	6.3E-21
54	1220.190	3.3E-21
55	1220.345	4.5E-23
56	1220.857	5.2E-21
57	1220.975	5.0E-23
58	1221.086	3.2E-23
59	1221.376	7.1E-23
60	1221.475	3.6E-23
61	1221.640	2.0E-23
62	1221.881	5.6E-21
63	1222.315	1.9E-23
64	1222.458	5.3E-23
65	1222.642	2.8E-21
66	1222.922	1.6E-22
67	1223.154	2.1E-21
68	1223.354	1.4E-21
69	1223.483	3.3E-23
70	1223.628	1.6E-23
71	1223.876	1.0E-22
72	1223.988	8.7E-21

SEQ. NO.	POSITION (cm⁻¹)	$S (\frac{cm}{molecule})$
1	1300.140	3.5E-22
2	1300.176	3.5E-22
3	1300.280	1.0E-20
4	1300.465	2.1E-20
5	1300.619	4.0E-23
6	1300.751	4.7E-22
7	1300.924	7.1E-23
8	1301.103	6.4E-23
9	1501.210	3.1E-21
10	1301.294	3.8E-22
11	1301.369	2.3E-20
12	1301.490	5.5E-21
13	1301.548	4.9E-20
14	1301.662	4.0E-21
15	1301.821	1.7E-20
16	1302.036	8.5E-20
17	1302.206	6.3E-22
18	1302.455	7.8E-21
19	1302.776	1.5E-19
20	1302.948	3.0E-23
21	1303.204	1.0E-23
22	1303.376	5.0E-20
23	1303.569	6.2E-20
24	1303.710	7.7F-20
25	1303.955	2.4E-20
26	1304.029	1.0E-21
27	1304.230	5.1E-20
28	1304.341	5.3E-21
29	1304.472	2.9E-20
30	1304.611	1.0E-19
31	1304.699	9.2E-22
32	1304.851	9.8E-20
33	1305.010	1.5E-19
34	1305.105	1.4E-20
35	1305.293	2.2E-20
36	1305.417	1.6E-19
37	1305.572	7.2E-20
38	1305.661	5.7E-20
39	1305.697	1.1E-20
40	1305.809	2.2E-19
41	1305.913	6.6E-20
42	1305.992	6.7E-20
43	1306.055	5.0E-20
44	1306.120	1.9E-19
45	1306.260	2.5E-19
46	1306.438	1.2E-19
47	1306.629	1.5E-20
48	1306.836	1.2E-21
49	1306.949	7.7E-23
50	1307.0 34	2.9E-23
51	1307.146	6.5E-23
52	1307.220	1.5E-22
53	1308.387	9.3E-23
54	1308.540	1.5E-21
55	1308.937	3.6E-23
56	1309.116	4.7E-23
57	1309.211	4.7E-23
58	1309.654	4.0E-23
59	1311.689	5.2E-23
60	1311.136	4.3E-23
61	1311.230	4.3E-23
62	1311.430	4.3E-20
63	1311.894	5.8E-23
64	1312.155	4.0E-23
65	1313.296	8.7E-23
66	1313.419	4.7E-23
67	1313.518	2.1E-23
68	1313.723	5.6E-22
69	1313.784	2.4E-22
70	1313.900	1.8E-22
71	1313.038	9.6E-23
72	1313.530	2.9E-22
73	1313.918	5.3E-23
74	1315.076	1.3E-23
75	1315.323	1.8E-23
76	1315.496	3.8E-23
77	1315.641	3.8E-23
78	1316.487	3.8E-23
79	1316.563	1.8E-23
80	1316.825	4.4E-20
81	1317.454	1.7E-23
82	1318.198	1.0E-22
83	1318.340	7.0E-23
84	1313.637	1.1E-21
85	1318.714	8.6E-23
86	1318.809	4.9E-22
87	1318.954	1.0E-21
88	1319.463	2.1E-22
89	1319.200	9.6E-23
90	1319.311	1.1E-22
91	1319.795	2.1E-22
92	1319.896	9.0E-23
93	1320.145	3.2E-23
94	1320.397	1.0E-22
95	1320.479	2.3E-22
96	1321.376	5.4E-23
97	1321.814	6.0E-23
98	1322.083	7.2E-20
99	1322.152	2.7E-20
100	1322.584	3.6E-23
101	1322.935	1.8E-22
102	1323.240	1.8E-22
103	1323.371	5.8E-23
104	1323.552	8.3E-22
105	1323.882	2.6E-21
106	1324.010	8.0E-22
107	1324.187	2.2E-21
108	1324.398	2.3E-22
109	1324.580	7.9E-23
110	1324.661	4.6E-23
111	1324.756	3.6E-23
112	1324.832	5.4E-23

SEQ. NO.	POSITION (cm⁻¹)	$S (\frac{cm}{molecule})$
1	1401.103	3.9E-23
2	1401.678	3.7E-23
3	1402.582	1.5F-22
4	1403.486	7.2E-23
5	1403.942	4.2E-23
6	1403.976	2.7E-23
7	1404.281	3.6E-23
8	1404.361	2.6E-22
9	1404.552	5.6E-23
10	1404.718	4.3E-23
11	1404.794	7.7E-23
12	1404.933^*	2.3E-22
13	1405.544	3.7E-23
14	1405.713	3.1E-23
15	1405.830	7.5E-22
16	1406.734	2.6E-23
17	1407.208	3.6E-23
18	1407.278	3.5E-23
19	1407.589	2.6F-22
20	1408.081	1.3E-23
21	1409.075	5.6E-23
22	1409.173	1.1E-23
23	1409.780	4.4E-23
24	1410.251	2.1E-22
25	1410.692	7.0E-23
26	1411.055	3.0E-23
27	1411.148	1.3E-22
28	1411.303	7.7E-23
29	1411.384	6.2E-23
30	1411.450	3.2E-23
31	1411.867	2.1E-23
32	1412.008	2.1E-23
33	1412.169	1.0E-21
34	1412.623	2.7E-22
35	1413.032	1.5E-22
36	1413.272	1.1E-22
37	1413.464	3.0E-23
38	1414.975	7.3E-23
39	1415.049	6.5E-23
40	1415.924	3.5E-23
41	1416.209	4.7E-23
42	1416.462	3.5E-23
43	1416.520	4.3E-23
44	1416.669	6.0E-23
45	1417.154^*	2.8E-23
46	1417.228^*	4.3E-23
47	1418.290	1.3E-22
48	1418.368	2.1E-21
49	1418.849	8.9E-22
50	1419.197^*	5.7E-23
51	1420.551	1.6E-23
52	1421.980	9.0E-23
53	1421.297	3.1E-23
54	1422.938	2.5E-22
55	1423.485	1.3E-22
56	1424.179^*	5.7E-23
57	1424.396	5.7E-23
58	1424.444	4.5E-23

SEQ. NO.	POSITION (cm⁻¹)	$S (\frac{cm}{molecule})$
1	1200.707	3.5E-23
2	1200.778	3.6E-23
3	1201.134	1.1E-21
4	1201.643	2.7E-22
5	1201.760	4.9E-23
6	1202.422	6.6E-22
7	1202.724	5.3E-22
8	1203.042	1.9E-22
9	1203.181	1.9E-22
10	1203.387	1.7E-22
11	1203.583	1.4E-22
12	1203.692	1.1E-22
13	1204.034	4.4E-22
14	1204.328	3.3E-23
15	1204.768	2.6E-23
16	1205.401	2.4E-23
17	1205.651	4.6E-23
18	1205.928	2.2E-22
19	1206.030	3.1E-23
20	1207.835	1.1E-21
21	1208.701	5.2E-23
22	1209.695	2.8E-22
23	1209.808	4.1E-22
24	1209.920	9.0E-23
25	1210.000	1.3E-21
26	1210.078	7.8E-22
27	1210.672	1.9E-21
28	1210.786	9.4E-22
29	1211.328	6.4E-22
30	1211.676	2.8E-23
31	1211.878	1.4E-21
32	1211.984	8.0E-21
33	1212.287	3.0E-23
34	1212.715	1.7E-23
35	1213.186	2.5E-23
36	1213.544	5.3E-23
37	1214.058	5.8E-23
38	1214.365	1.6E-23
39	1214.684	4.9E-23
40	1215.660	5.8E-23
41	1215.950	1.5E-22
42	1216.205	5.2E-21
43	1216.326	1.0E-21
44	1216.630	8.2E-22
45	1217.272	2.2E-23
46	1217.448	5.2E-23
47	1217.624	1.8E-21
48	1217.990	2.0E-21
49	1218.628	1.9E-21
50	1218.744	2.1E-23
51	1218.947	2.6E-23
52	1219.082	4.9E-23
53	1219.648	6.3E-21
54	1220.190	3.3E-21
55	1220.345	4.5E-23
56	1220.857	5.2E-21
57	1220.975	5.0E-23
58	1221.086	3.2E-23
59	1221.376	7.1E-23
60	1221.475	3.6E-23
61	1221.640	2.0E-23
62	1221.881	5.6E-21
63	1222.315	1.9E-23
64	1222.458	5.3E-23
65	1222.642	2.8E-21
66	1222.922	1.6E-22
67	1223.154	2.1E-21
68	1223.354	1.4E-21
69	1223.483	3.3E-23
70	1223.628	1.6E-23
71	1223.876	1.0E-22
72	1223.988	8.7E-21

SEQ. NO.	POSITION (cm⁻¹)	$S (\frac{cm}{molecule})$
1	1300.140	3.5E-22
2	1300.176	3.5E-22
3	1300.280	1.0E-20
4	1300.465	2.1E-20
5	1300.619	4.0E-23
6	1300.751	4.7E-22
7	1300.924	7.1E-23
8	1301.103	6.4E-23
9	1501.210	3.1E-21
10	1301.294	3.8E-22
11	1301.369	2.3E-20
12	1301.490	5.5E-21
13	1301.548	4.9E-20
14	1301.662	4.0E-21
15	1301.821	1.7E-20
16	1302.036	8.5E-20
17	1302.206	6.3E-22
18	1302.455	7.8E-21
19	1302.776	1.5E-19
20	1302.948	3.0E-23
21	1303.204	1.0E-23
22	1303.376	5.0E-20
23	1303.569	6.2E-20
24	1303.710	7.7F-20
25	1303.955	2.4E-20
26	1304.029	1.0E-21
27	1304.230	5.1E-20
28	1304.341	5.3E-21
29	1304.472	2.9E-20
30	1304.611	1.0E-19
31	1304.699	9.2E-22
32	1304.851	9.8E-20
33	1305.010	1.5E-19
34	1305.105	1.4E-20
35	1305.293	2.2E-20
36	1305.417	1.6E-19
37	1305.572	7.2E-20
38	1305.661	5.7E-20
39	1305.697	1.1E-20
40	1305.809	2.2E-19
41	1305.913	6.6E-20
42	1305.992	6.7E-20
43	1306.055	5.0E-20
44	1306.120	1.9E-19
45	1306.260	2.5E-19
46	1306.438	1.2E-19
47	1306.629	1.5E-20
48	1306.836	1.2E-21
49	1306.949	7.7E-23
50	1307.0 34	2.9E-23
51	1307.146	6.5E-23
52	1307.220	1.5E-22
53	1308.387	9.3E-23
54	1308.540	1.5E-21
55	1308.937	3.6E-23
56	1309.116	4.7E-23
57	1309.211	4.7E-23
58	1309.654	4.0E-23
59	1311.689	5.2E-23
60	1311.136	4.3E-23
61	1311.230	4.3E-23
62	1311.430	4.3E-20
63	1311.894	5.8E-23
64	1312.155	4.0E-23
65	1313.296	8.7E-23
66	1313.419	4.7E-23
67	1313.518	2.1E-23
68	1313.723	5.6E-22
69	1313.784	2.4E-22
70	1313.900	1.8E-22
71	1313.038	9.6E-23
72	1313.530	2.9E-22
73	1313.918	5.3E-23
74	1315.076	1.3E-23
75	1315.323	1.8E-23
76	1315.496	3.8E-23
77	1315.641	3.8E-23
78	1316.487	3.8E-23
79	1316.563	1.8E-23
80	1316.825	4.4E-20
81	1317.454	1.7E-23
82	1318.198	1.0E-22
83	1318.340	7.0E-23
84	1313.637	1.1E-21
85	1318.714	8.6E-23
86	1318.809	4.9E-22
87	1318.954	1.0E-21
88	1319.463	2.1E-22
89	1319.200	9.6E-23
90	1319.311	1.1E-22
91	1319.795	2.1E-22
92	1319.896	9.0E-23
93	1320.145	3.2E-23
94	1320.397	1.0E-22
95	1320.479	2.3E-22
96	1321.376	5.4E-23
97	1321.814	6.0E-23
98	1322.083	7.2E-20
99	1322.152	2.7E-20
100	1322.584	3.6E-23
101	1322.935	1.8E-22
102	1323.240	1.8E-22
103	1323.371	5.8E-23
104	1323.552	8.3E-22
105	1323.882	2.6E-21
106	1324.010	8.0E-22
107	1324.187	2.2E-21
108	1324.398	2.3E-22
109	1324.580	7.9E-23
110	1324.661	4.6E-23
111	1324.756	3.6E-23
112	1324.832	5.4E-23

Abstract

Cited By

Figures (6)

Tables (3)

Applied Optics