Infrared Dispersion of Some Oxide Glasses

I. H. Malitson; G. W. Cleek; O. N. Stavroudis; L. E. Sutton

doi:10.1364/AO.2.000741

Applied Optics
Vol. 2,
Issue 7,
pp. 741-747
(1963)
•https://doi.org/10.1364/AO.2.000741

Infrared Dispersion of Some Oxide Glasses

I. H. Malitson, G. W. Cleek, O. N. Stavroudis, and L. E. Sutton

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I. H. Malitson, G. W. Cleek, O. N. Stavroudis, and L. E. Sutton, "Infrared Dispersion of Some Oxide Glasses," Appl. Opt. 2, 741-747 (1963)

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Abstract

The refractive indices of silicate, germanate, calcium aluminate, and tellurite glasses have been determined in the wavelength range from about 0.4 μ to 5.3 μ. The experimental data for the silicate and germanate glasses were fitted to a Sellmeier dispersion equation of the form n² = 1 + ∑A_jλ²/(λ² − λ_j²). Dispersive curves were plotted which indicate the expected dispersion, contribution to chromatic aberration, and resolution of the glasses as a function of wavelength.

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Oxide	F40	F52	F53	F110	F998	F75	F356
SiO₂	50	50	50	50		5
GeO₂					45
BaO	30	26	22	20	18
CaO						48.5
TeO₂							84
Al₂O₃						41.5	16
TiO₂	20	20	20	20	10
La₂O₃		4	8	10	7
MgO						5
ZnO					10
Ba₂O₅					1
TaF₂					4
ZrO₂					5

Melt no. ν-values		F40^a 34.6	F52^a 34.3	F53^a 34.3	F110^a 34.4	F998^b 32.9	F75^c	F356^d

Wavelength (μ)	Source
0.40465	Hg	1.79148	1.81859	1.84447		1.90302
0.43583	Hg	1.78011	1.80682	1.83233	1.84181	1.88997
0.48613	H	1.76721	1.79342	1.81851	1.82786	1.87470
0.54607	Hg	1.75697	1.78274	1.80748	1.81677	1.86242	1.67524	1.9689
0.57696	Hg	1.75301	1.77864	1.80324	1.81250	1.85770	1.67254
0.57907	Hg	1.75276	1.77838	1.80298	1.81225	1.85741	1.67237	1.9507
0.58926	Na	1.75161	1.77719	1.80174	1.81098	1.85597
0.64385	Cd	1.74643	1.77181	1.79619	1.80538	1.84986	1.66797
0.65628	E	1.74546	1.77078	1.79513	1.80432	1.84866
0.85212	Cs	1.73502	1.75993	1.78392	1.79301	1.83632
0.89440	Cs	1.73358	1.75841	1.78237	1.79144	1.83462
1.01398	Hg	1.73020	1.75491	1.77877	1.78783	1.83082	1.65626	1.9197
1.12866	Hg	1.72766	1.75229	1.77606	1.78514	1.82801	1.65438	1.9158
1.3622	Hg	1.72353	1.74806	1.77175	1.78078	1.82374		1.9101
1.39506	Hg	1.72311	1.74762	1.77128	1.78026	1.82331
1.4695	Cs	1.72198	1.74649	1.77018
1.517	Didy^e	1.72132	1.74581	1.76955	1.77854	1.82167
1.52952	Hg	1.72111	1.74559	1.76921	1.77821	1.82142	1.64943	1.9071
1.681	Poly^f	1.71892	1.74336	1.76698
1.6932	Hg		1.74323		1.77583	1.81930	1.64765
1.7092	Hg	1.71857	1.74298	1.76669	1.77557	1.81908		1.9044
1.81307	Hg	1.71704	1.74154	1.76506	1.77414		1.64635
1.918	Didy	1.71537	1.73985	1.76340		1.81644
1.97009	Hg	1.71479	1.73927	1.76274	1.77178		1.64459	1.9015
2.1526	TcB^g	1.71202	1.73640	1.75995	1.76891	1.81364		1.8977
2.167	Poly	1.71186	1.73624	1.75976	1.76878
2.2493	Hg	1.71062	1.73497					1.8966
2.3254	Hg	1.70935	1.73372	1.75723	1.76622		1.64042
2.4374	TcB	1.70750	1.73184	1.75537	1.76437	1.81000		1.8941
2.5947	H₂O	1.70462	1.72901	1.75245	1.76121	1.80797
2.6119	H₂O
2.6685	H₂O					1.80680
2.6738	H₂O	1.70336	1.72770	1.75126	1.76017
2.7248	H₂O	1.70255	1.72677	1.75034
2.735	SiO₂	1.70214	1.72652	1.75000
2.7397	H₂O					1.80541
3.2434	TcB	1.69186	1.71613	1.73965	1.74855
3.2668	Poly	1.69116	1.71541	1.73896			1.62668
3.3026	Poly	1.69032	1.71459	1.73809		1.79706
3.4188	Poly						1.62398
3.422	Poly	1.68755	1.71170	1.73533	1.74421	1.79490
3.5070	Poly	1.68544	1.70964	1.73318	1.74218	1.79345	1.62243
3.5564	TcB	1.68414	1.70838	1.73201	1.74086	1.79250
3.7067	TeB	1.68010	1.70440	1.72797	1.73690	1.78968
4.2247	H₂O		1.68847
4.253	H₂O	1.66268	1.68711	1.71212
4.2553	H₂O					1.77863		1.8597
4.258	H₂O				1.71989		1.60645
5.138	Poly					1.75437
5.3034	TeB					1.74956
5.343	Poly					1.74805

Melt number	F40	F52	F53	F110	F998
A₁	1.058985	1.042879	1.0862603	1.4069616	1.3100200
A₂	0.912350	1.013832	1.0539325	0.7645296	1.0088036
A₃	1.137683	1.468522	2.0163678	1.5310273	1.9148552
λ₁²	0.0030489	0.0012197	0.0003761	0.0055175	0.0063054
λ₂²	0.0315103	0.0316516	0.032435	0.0362642	0.0326582
λ₃²	116.99181	144.58456	190.93270	147.23650	235.40295
λ₁	0.0552168	0.0349236	0.0193921	0.0742800	0.0794068
λ₂	0.1775114	0.1779091	0.1800973	0.1904317	0.1807158
λ₃	10.816275	12.024332	13.817840	12.134105	15.342847

Oxide	F40	F52	F53	F110	F998	F75	F356
SiO₂	50	50	50	50		5
GeO₂					45
BaO	30	26	22	20	18
CaO						48.5
TeO₂							84
Al₂O₃						41.5	16
TiO₂	20	20	20	20	10
La₂O₃		4	8	10	7
MgO						5
ZnO					10
Ba₂O₅					1
TaF₂					4
ZrO₂					5

Melt no. ν-values		F40^a 34.6	F52^a 34.3	F53^a 34.3	F110^a 34.4	F998^b 32.9	F75^c	F356^d

Wavelength (μ)	Source
0.40465	Hg	1.79148	1.81859	1.84447		1.90302
0.43583	Hg	1.78011	1.80682	1.83233	1.84181	1.88997
0.48613	H	1.76721	1.79342	1.81851	1.82786	1.87470
0.54607	Hg	1.75697	1.78274	1.80748	1.81677	1.86242	1.67524	1.9689
0.57696	Hg	1.75301	1.77864	1.80324	1.81250	1.85770	1.67254
0.57907	Hg	1.75276	1.77838	1.80298	1.81225	1.85741	1.67237	1.9507
0.58926	Na	1.75161	1.77719	1.80174	1.81098	1.85597
0.64385	Cd	1.74643	1.77181	1.79619	1.80538	1.84986	1.66797
0.65628	E	1.74546	1.77078	1.79513	1.80432	1.84866
0.85212	Cs	1.73502	1.75993	1.78392	1.79301	1.83632
0.89440	Cs	1.73358	1.75841	1.78237	1.79144	1.83462
1.01398	Hg	1.73020	1.75491	1.77877	1.78783	1.83082	1.65626	1.9197
1.12866	Hg	1.72766	1.75229	1.77606	1.78514	1.82801	1.65438	1.9158
1.3622	Hg	1.72353	1.74806	1.77175	1.78078	1.82374		1.9101
1.39506	Hg	1.72311	1.74762	1.77128	1.78026	1.82331
1.4695	Cs	1.72198	1.74649	1.77018
1.517	Didy^e	1.72132	1.74581	1.76955	1.77854	1.82167
1.52952	Hg	1.72111	1.74559	1.76921	1.77821	1.82142	1.64943	1.9071
1.681	Poly^f	1.71892	1.74336	1.76698
1.6932	Hg		1.74323		1.77583	1.81930	1.64765
1.7092	Hg	1.71857	1.74298	1.76669	1.77557	1.81908		1.9044
1.81307	Hg	1.71704	1.74154	1.76506	1.77414		1.64635
1.918	Didy	1.71537	1.73985	1.76340		1.81644
1.97009	Hg	1.71479	1.73927	1.76274	1.77178		1.64459	1.9015
2.1526	TcB^g	1.71202	1.73640	1.75995	1.76891	1.81364		1.8977
2.167	Poly	1.71186	1.73624	1.75976	1.76878
2.2493	Hg	1.71062	1.73497					1.8966
2.3254	Hg	1.70935	1.73372	1.75723	1.76622		1.64042
2.4374	TcB	1.70750	1.73184	1.75537	1.76437	1.81000		1.8941
2.5947	H₂O	1.70462	1.72901	1.75245	1.76121	1.80797
2.6119	H₂O
2.6685	H₂O					1.80680
2.6738	H₂O	1.70336	1.72770	1.75126	1.76017
2.7248	H₂O	1.70255	1.72677	1.75034
2.735	SiO₂	1.70214	1.72652	1.75000
2.7397	H₂O					1.80541
3.2434	TcB	1.69186	1.71613	1.73965	1.74855
3.2668	Poly	1.69116	1.71541	1.73896			1.62668
3.3026	Poly	1.69032	1.71459	1.73809		1.79706
3.4188	Poly						1.62398
3.422	Poly	1.68755	1.71170	1.73533	1.74421	1.79490
3.5070	Poly	1.68544	1.70964	1.73318	1.74218	1.79345	1.62243
3.5564	TcB	1.68414	1.70838	1.73201	1.74086	1.79250
3.7067	TeB	1.68010	1.70440	1.72797	1.73690	1.78968
4.2247	H₂O		1.68847
4.253	H₂O	1.66268	1.68711	1.71212
4.2553	H₂O					1.77863		1.8597
4.258	H₂O				1.71989		1.60645
5.138	Poly					1.75437
5.3034	TeB					1.74956
5.343	Poly					1.74805

Abstract

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Equations (3)

Applied Optics