AFGL trace gas compilation: 1980 version

L. S. Rothman; A. Goldman; J. R. Gillis; R. H. Tipping; L. R. Brown; J. S. Margolis; A. G. Maki; L. D. G. Young

doi:10.1364/AO.20.001323

Applied Optics
Vol. 20,
Issue 8,
pp. 1323-1328
(1981)
•https://doi.org/10.1364/AO.20.001323

AFGL trace gas compilation: 1980 version

L. S. Rothman, A. Goldman, J. R. Gillis, R. H. Tipping, L. R. Brown, J. S. Margolis, A. G. Maki, and L. D. G. Young

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L. S. Rothman, A. Goldman, J. R. Gillis, R. H. Tipping, L. R. Brown, J. S. Margolis, A. G. Maki, and L. D. G. Young, "AFGL trace gas compilation: 1980 version," Appl. Opt. 20, 1323-1328 (1981)

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Abstract

A new edition of the AFGL trace gas compilation is now available. Absorption line parameters of positions, intensities, and halfwidths are given for the major bands of thirteen gases covering the spectral region from 0 to 10,000 cm⁻¹. In addition to updating the original gases (NO, SO₂, NO₂, and NH₃), the molecules HNO₃, OH, HF, HCl, HBr, HI, ClO, OCS, and H₂CO have been added to the compilation. The sources for the additions and modifications are described.

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Molecule	Isotope	Relative natural abundance	Molecule	Isotope	Relative Natural abundance
NO(8)	46	0.99390	HCl(15)	15	0.75519
				17	0.24466
SO₂(9)	626	0.94543
			HBr(16)	19	0.50532
NO₂(10)	646	0.99150		11	0.49452
NH₃(11)	4111	0.99585	HI(17)	17	0.99985
HNO₃(12)	146	0.98897	ClO(18)	56	0.75348
				76	0.24411
OH(13)	61	0.99744
			OCS(19)	622	0.93719
HF(14)	19	0.99985
			H₂CO(20)	126	0.98622

ν₀ (cm⁻¹)	Molecule/isotope	Band		ΣS_i^a		Range (cm⁻¹)	No. of lines
ν₀ (cm⁻¹)	Molecule/isotope	υ′	υ″	ΣS_i^a		Range (cm⁻¹)	No. of lines
	NO 46	0	0	3.217	0.798	5–98	112
1875.972	NO 46	1	0	503.4	124.825	1673–2072	637
3723.853	NO 46	2	0	8.301	2.058	3521–3901	550
	SO₂ 626	000	000	239.0	59.255	1–175	4132
517.75	SO₂ 626	010	000	389.9	97.677	433–617	3326
1151.7135	SO₂ 626	100	000	351.9	87.255	1048–1262	5812
1362.030	SO₂ 626	001	000	3080.	763.673	1316–1394	2075
2499.8701	SO₂ 626	101	000	71.37	17.695	2451–2528	2075
749.654	NO₂ 646	010	000	370.9	91.968	600–900	4594
1616.852	NO₂ 646	001	000	6113.	1515.625	1550–1657	3276
2906.073	NO₂ 646	101	000	257.9	63.947	2833–2937	1586
949.878	NH₃ 4111	0100	0000	2151.	533.403	609–1266	721
	HNO₃146	Pure rot		497.1	123.259	10–38	66
897.	HNO₃ 146	2ν₉		190.0	47.103	891–899	1079
1324 9	HNO₃ 146	ν₄		2744.	680.430	1326–1335	24
1709.568	HNO₃ 146	ν₂		1590.	394.129	1719–1730	1014
3569.6398	OH 61	1	0	173.1	42.922	3086–4011	166
	HF 19	0	0	5704.	1414.204	41–589	15
3961.4429	HF 19	1	0	1547.	383.671	3381–4339	25
7750.7949	HF 19	2	0	49.62	12.302	7143–7993	22
	HCl 17	0	0	262.0	64.969	21–382	19
	HCl 15	0	0	806.8	200.042	21–382	19
2883.8850	HCl 17	1	0	147.2	36.495	2486–3136	33
2885.9765	HCl 15	1	0	452.8	112.266	2459–3138	34
5663.9276	HCl 17	2	0	3.48	0.863	5304–5824	27
5667.9832	HCl 15	2	0	10.71	2.655	5272–5830	29
8340.9407	HCl 17	3	0	0.02	0.006	8125–8448	18
8346.7771	HCl 15	3	0	0.07	0.018	8059–8454	21
	HBr 11	0	0	234.6	58.163	17–338	21
	HBr 19	0	0	239.8	59.452	17–338	21
	HBr 11	1	1			65–129	5
	HBr 19	1	1			65–129	5
2558.5308	HBr 11	1	0	72.32	17.932	2195–2772	36
2558.9105	HBr 19	1	0	73.92	18.327	2195–2773	36
5026.6005	HBr 11	2	0	0.75	0.187	4712–5160	28
5027.3408	HBr 19	2	0	0.77	0.191	4713–5160	28
7404.1928	HBr 11	3	0	0.02	0.005	7205–7494	20
7405.2610	HBr 19	3	0	0.02	0.005	7206–7496	20
9690.9914	HBr 11	4	0	0.01	0.002	9506–9757	18
9692.3579	HBr 19	4	0	0.01	0.002	9508–9759	18
	HI 17	0	0	106.7	26.454	13–286	23
	HI 17	1	1	0.002		50–137	8
2229.5817	HI 17	1	0	1.758	0.436	2118–2398	26
4379.2261	HI 17	2	0	0.633	0.157	4117–4489	32
6448.0348	HI 17	3	0	0.343	0.085	6176–6520	30
8434.7076	HI 17	4	0	0.059	0.015	8190–8487	26
835.480	ClO 76	1	0	10.02	2.485	803–865	131
842.554	ClO 56	1	0	34.87	8.646	796–879	175
858.9677	OCS 622	1000	0000	109.8	27.220	818–891	181
2062.2	OCS 622	0001	0000	7881.	1954.116	2016–2089	181
2500	H₂CO 126	000002	000000	4.55		2744–2812	5
2655	H₂CO 126	001100	000000	0.59		2734–2734	1
2716.156	H₂CO 126	001001	000000	138.6		2700–2878	105
2782.457	H₂CO 126	100000	000000	828.8	205.494	2723–2842	424
2843.326	H₂CO 126	000010	000000	974.2	241.556	2704–2982	595
2905	H₂CO 126	010100	000000	38.13		2734–2999	28
3000.066	H₂CO 126	010001	000000	8.55		2897–2957	3

Molecule	Band	Frequency (cm⁻¹)	Intensity (%)	Halfwidths (%)
HF	0–1	1 × 10⁻⁴^a	1	15^b
	1–0	2.5 × 10⁻⁴^a	10	20^c
	2–0	1.5 × 10⁻³^a	10	20^d
H³⁵Cl	0–0	1 ×10⁻⁴^a	1	20^f
	1–0	1 × 10⁻²^e	10	20^f
	2–0	1 × 10⁻³^a	10	30^f
	3–0	1 × 10⁻²^e	15	30^f
H³⁷Cl	0–0	1 × 10⁻⁴^a	1	20^f
	1–0	1 × 10⁻²^g	10	20^f
	2–0	1 × 10⁻³^a	10	30^f
	3–0	1 × 10⁻²^g	15	30^f
H⁷⁹Br	0–0	1 × 10⁻⁴^h	1	30ⁱ
	1–1	1 × 10⁻⁴^h	2	30
	1–0	1 × 10⁻³^h	15	30
	2–0	1 × 10⁻³^h	15	30
	3–0	2 × 10⁻³^h	10	30
	4–0	5 × 10⁻³^h	10	30
H⁸¹Br	0–0	1 × 10⁻⁴^j	1	30ⁱ
	1–1	1 × 10⁻⁴^j	2	30
	1–0	1 × 10⁻³^j	15	30
	2–0	2 × 10⁻³^j	15	30
	3–0	2 × 10⁻³^j	10	30
	4–0	5 × 10⁻³^j	10	30
HI	0–0	1 × 10⁻⁴^k	1	30^l
	1–1	1 × 10⁻⁴^k	2	30
	1–0	3 × 10⁻³^k	15	30
	2–0	1 × 10⁻³^k	15	30
	3–0	1 × 10⁻³^k	10	30
	4–0	1 × 10⁻³^k	10	30

Molecule	Isotope	Relative natural abundance	Molecule	Isotope	Relative Natural abundance
NO(8)	46	0.99390	HCl(15)	15	0.75519
				17	0.24466
SO₂(9)	626	0.94543
			HBr(16)	19	0.50532
NO₂(10)	646	0.99150		11	0.49452
NH₃(11)	4111	0.99585	HI(17)	17	0.99985
HNO₃(12)	146	0.98897	ClO(18)	56	0.75348
				76	0.24411
OH(13)	61	0.99744
			OCS(19)	622	0.93719
HF(14)	19	0.99985
			H₂CO(20)	126	0.98622

ν₀ (cm⁻¹)	Molecule/isotope	Band		ΣS_i^a		Range (cm⁻¹)	No. of lines
ν₀ (cm⁻¹)	Molecule/isotope	υ′	υ″	ΣS_i^a		Range (cm⁻¹)	No. of lines
	NO 46	0	0	3.217	0.798	5–98	112
1875.972	NO 46	1	0	503.4	124.825	1673–2072	637
3723.853	NO 46	2	0	8.301	2.058	3521–3901	550
	SO₂ 626	000	000	239.0	59.255	1–175	4132
517.75	SO₂ 626	010	000	389.9	97.677	433–617	3326
1151.7135	SO₂ 626	100	000	351.9	87.255	1048–1262	5812
1362.030	SO₂ 626	001	000	3080.	763.673	1316–1394	2075
2499.8701	SO₂ 626	101	000	71.37	17.695	2451–2528	2075
749.654	NO₂ 646	010	000	370.9	91.968	600–900	4594
1616.852	NO₂ 646	001	000	6113.	1515.625	1550–1657	3276
2906.073	NO₂ 646	101	000	257.9	63.947	2833–2937	1586
949.878	NH₃ 4111	0100	0000	2151.	533.403	609–1266	721
	HNO₃146	Pure rot		497.1	123.259	10–38	66
897.	HNO₃ 146	2ν₉		190.0	47.103	891–899	1079
1324 9	HNO₃ 146	ν₄		2744.	680.430	1326–1335	24
1709.568	HNO₃ 146	ν₂		1590.	394.129	1719–1730	1014
3569.6398	OH 61	1	0	173.1	42.922	3086–4011	166
	HF 19	0	0	5704.	1414.204	41–589	15
3961.4429	HF 19	1	0	1547.	383.671	3381–4339	25
7750.7949	HF 19	2	0	49.62	12.302	7143–7993	22
	HCl 17	0	0	262.0	64.969	21–382	19
	HCl 15	0	0	806.8	200.042	21–382	19
2883.8850	HCl 17	1	0	147.2	36.495	2486–3136	33
2885.9765	HCl 15	1	0	452.8	112.266	2459–3138	34
5663.9276	HCl 17	2	0	3.48	0.863	5304–5824	27
5667.9832	HCl 15	2	0	10.71	2.655	5272–5830	29
8340.9407	HCl 17	3	0	0.02	0.006	8125–8448	18
8346.7771	HCl 15	3	0	0.07	0.018	8059–8454	21
	HBr 11	0	0	234.6	58.163	17–338	21
	HBr 19	0	0	239.8	59.452	17–338	21
	HBr 11	1	1			65–129	5
	HBr 19	1	1			65–129	5
2558.5308	HBr 11	1	0	72.32	17.932	2195–2772	36
2558.9105	HBr 19	1	0	73.92	18.327	2195–2773	36
5026.6005	HBr 11	2	0	0.75	0.187	4712–5160	28
5027.3408	HBr 19	2	0	0.77	0.191	4713–5160	28
7404.1928	HBr 11	3	0	0.02	0.005	7205–7494	20
7405.2610	HBr 19	3	0	0.02	0.005	7206–7496	20
9690.9914	HBr 11	4	0	0.01	0.002	9506–9757	18
9692.3579	HBr 19	4	0	0.01	0.002	9508–9759	18
	HI 17	0	0	106.7	26.454	13–286	23
	HI 17	1	1	0.002		50–137	8
2229.5817	HI 17	1	0	1.758	0.436	2118–2398	26
4379.2261	HI 17	2	0	0.633	0.157	4117–4489	32
6448.0348	HI 17	3	0	0.343	0.085	6176–6520	30
8434.7076	HI 17	4	0	0.059	0.015	8190–8487	26
835.480	ClO 76	1	0	10.02	2.485	803–865	131
842.554	ClO 56	1	0	34.87	8.646	796–879	175
858.9677	OCS 622	1000	0000	109.8	27.220	818–891	181
2062.2	OCS 622	0001	0000	7881.	1954.116	2016–2089	181
2500	H₂CO 126	000002	000000	4.55		2744–2812	5
2655	H₂CO 126	001100	000000	0.59		2734–2734	1
2716.156	H₂CO 126	001001	000000	138.6		2700–2878	105
2782.457	H₂CO 126	100000	000000	828.8	205.494	2723–2842	424
2843.326	H₂CO 126	000010	000000	974.2	241.556	2704–2982	595
2905	H₂CO 126	010100	000000	38.13		2734–2999	28
3000.066	H₂CO 126	010001	000000	8.55		2897–2957	3

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Tables (3)

Applied Optics