Tunable diode laser measurements of widths of air- and nitrogen-broadened lines in the ν4 band of 13CH4

V. Malathy Devi; Curtis P. Rinsland; Mary Ann H. Smith; D. Chris Benner

doi:10.1364/AO.24.003321

Applied Optics
Vol. 24,
Issue 20,
pp. 3321-3322
(1985)
•https://doi.org/10.1364/AO.24.003321

Tunable diode laser measurements of widths of air- and nitrogen-broadened lines in the ν₄ band of ¹³CH₄

V. Malathy Devi, Curtis P. Rinsland, Mary Ann H. Smith, and D. Chris Benner

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V. Malathy Devi, Curtis P. Rinsland, Mary Ann H. Smith, and D. Chris Benner, "Tunable diode laser measurements of widths of air- and nitrogen-broadened lines in the ν₄ band of ¹³CH₄," Appl. Opt. 24, 3321-3322 (1985)

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Wavenumber^a (cm⁻¹)	Assignent ^a		Halfwidth
			Air-Broadened		N₂-Broadened
			AFGL 1982^a	Present study	Present study
1261.6382	P6	F12+F22	0.059	0.0605(7)	0.0611(3)
1264.1388	P6	E1+E1	0.057	0.0572(3)	0.0574(5)
1267.5920	P5	F22+F12	0.061	0.0624(10)	0.0627(9)
1267.9173	P5	E1+E1	0.061	0.0578(6)	0.0582(7)
1313.7224	R2	F11+F21	0.064	0.0647(6)	0,0645(2)
1313.7882	R2	E1+E1	0.049	0.0516(6)	0.0518(5)
1323.8951	R4	E1+E1	0.053	0.0518(4)	0.0519(2)
1324.0117	R4	F21+F11	0.061	0.0654(2)	0.0658(5)
1324.1785	R4	A21+A11	0.045	0.0593(4)	0.0593(3)
1328.3723	R5	F22+F12	0.059	0.0605(2)	0.0619(12)
1328.4675	R5	E1+E1	0.059	0.0517(9)	0.0523(6)
1328.9819	R5	F11+F21	0.059	0.0621(5)	0.0627(12)
1332.9706	R6	A21+A11	0.050	0.0584(7)	0.0589(3)
1333.1212	R6	F21+F11	0.057	0.0617(8)	0.0622(7)
1338.0074	R7	F12+F22	0.055	0.0598(9)	0.0593(3)
1342.1383	R8	F12+F22	0.054	0.0558(4)	0.0562(5)
1342.2414	R8	E2+E2	0.054	0.0470(3)	0.0472(3)
1344.1686	R8	E1+E1	0.054	0.0498(7)	0.0611(7)
1344.2156	R8	F21+F11	0.054	0.0501(7)	0.517[4)
1344.2965	R8	A21+A11	0.054	0.0431(3)	0.0443(2)
1348.7948	R9	F23+F13	0.053	0.0517(5)	0.0522(4)
1352.2320	R10	F21+F11	0.052	0.0542(3)	0.0545(3)
1355.5807	R11	F13+F23	0.051	0.0516(2)	0.0529(13)

Assignment	$b_{L}^{0}$ (air)		$b_{L}^{0}$ (N₂)
Assignment	¹²CH₄	¹³CH₄	¹²CH₄	¹³CH₄
R2 F11+F21	0.0626(3)	0.0647(6)	0.0638(2)	0.0645(2)
R2 E1+E1	0.0534(3)	0.0516(6)	0.0550(3)	0.0518(5)
R4 E1+E1	0.0547(2)	0.0518(4)	0.0550(4)	0.0519(2)
R4 F21+F11	0.0664(1)	0.0654(2)	0.0670(1)	0.0658(5)
R4 A21+A11	0.0586(3)	0.0593(4)	0.0589(2)	0.0593(3)
R5 F11+F21	0.0615(2)	0.0621(5)	0.0623(2)	0.0627(12)

Wavenumber^a (cm⁻¹)	Assignent ^a		Halfwidth
			Air-Broadened		N₂-Broadened
			AFGL 1982^a	Present study	Present study
1261.6382	P6	F12+F22	0.059	0.0605(7)	0.0611(3)
1264.1388	P6	E1+E1	0.057	0.0572(3)	0.0574(5)
1267.5920	P5	F22+F12	0.061	0.0624(10)	0.0627(9)
1267.9173	P5	E1+E1	0.061	0.0578(6)	0.0582(7)
1313.7224	R2	F11+F21	0.064	0.0647(6)	0,0645(2)
1313.7882	R2	E1+E1	0.049	0.0516(6)	0.0518(5)
1323.8951	R4	E1+E1	0.053	0.0518(4)	0.0519(2)
1324.0117	R4	F21+F11	0.061	0.0654(2)	0.0658(5)
1324.1785	R4	A21+A11	0.045	0.0593(4)	0.0593(3)
1328.3723	R5	F22+F12	0.059	0.0605(2)	0.0619(12)
1328.4675	R5	E1+E1	0.059	0.0517(9)	0.0523(6)
1328.9819	R5	F11+F21	0.059	0.0621(5)	0.0627(12)
1332.9706	R6	A21+A11	0.050	0.0584(7)	0.0589(3)
1333.1212	R6	F21+F11	0.057	0.0617(8)	0.0622(7)
1338.0074	R7	F12+F22	0.055	0.0598(9)	0.0593(3)
1342.1383	R8	F12+F22	0.054	0.0558(4)	0.0562(5)
1342.2414	R8	E2+E2	0.054	0.0470(3)	0.0472(3)
1344.1686	R8	E1+E1	0.054	0.0498(7)	0.0611(7)
1344.2156	R8	F21+F11	0.054	0.0501(7)	0.517[4)
1344.2965	R8	A21+A11	0.054	0.0431(3)	0.0443(2)
1348.7948	R9	F23+F13	0.053	0.0517(5)	0.0522(4)
1352.2320	R10	F21+F11	0.052	0.0542(3)	0.0545(3)
1355.5807	R11	F13+F23	0.051	0.0516(2)	0.0529(13)

Assignment	$b_{L}^{0}$ (air)		$b_{L}^{0}$ (N₂)
Assignment	¹²CH₄	¹³CH₄	¹²CH₄	¹³CH₄
R2 F11+F21	0.0626(3)	0.0647(6)	0.0638(2)	0.0645(2)
R2 E1+E1	0.0534(3)	0.0516(6)	0.0550(3)	0.0518(5)
R4 E1+E1	0.0547(2)	0.0518(4)	0.0550(4)	0.0519(2)
R4 F21+F11	0.0664(1)	0.0654(2)	0.0670(1)	0.0658(5)
R4 A21+A11	0.0586(3)	0.0593(4)	0.0589(2)	0.0593(3)
R5 F11+F21	0.0615(2)	0.0621(5)	0.0623(2)	0.0627(12)

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Applied Optics