The N2O infrared spectrum from 900 to 4700 cm−1 has been studied with a high-resolution Fourier-transform spectrometer. Measurements were made of line frequencies of several N2O isotopes for several ground-state and hot bands. A few of these bands are being reported for the first time, to my knowledge: the 1530–0330, 2330–0330, 0441–0440, 0441–0330, 0531–0330, and 1331–0330 bands of 14N216O. Also for the first time to my knowledge, perturbation-enhanced transitions in the 0710–0110 and 0730–0110 bands were assigned and measured. The frequencies have been analyzed to obtain a unique set of effective vibration–rotation parameters for each vibrational state. The results obtained from this research are of high accuracy for the ground-state and the first-excited-state bands of 14N216O, in which the computed frequencies derived from the least-squares fits are known to an absolute uncertainty of only ±4 × 10−5 for nonperturbed transitions.
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Values in cm−1 × 105.
Line finder frequency measurements only.
Table IV
Observed Line Positions (cm−1) of the 1200–0000, 1200–0200, and 1200–0110 Bands of N216Oa
J
1200–0000 Band
1200–0200 Band
1200–0110 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
2462.83276
2
0
1
2463.66728
-2
2461.15839
-3
1293.02435
-3
1872.39019
-3
1873.22486
-6
1
2
2464.50018
6
2460.31872
4
1296.36243
7
1875.73119
-6
1873.21760
-3
2
3
2465.33120
0
2459.47724
2
1876.56132
0
1873.20671
2
3
4
2466.16054
3
2458.63408
5
1298.01010
6
1290.48366
10
1877.38929
-1
1873.19212
2
4
5
2466.98806
0
2457.78914
1
1298.82857
5
1289.62966
6
1881.49732
-1
1873.17388
3
5
6
2467.81382
1
2456.94251
-0
1288.77220
8
1873.15198
5
6
7
2468.63779
2
2456.09420
4
1287.91125
12
7
8
2469.45987
-4
2455.24410
2
1287.04667
3
1866.46429
9
1873.09705
-0
8
9
2470.28019
-2
2454.39227
0
1286.17864
-2
1873.06408
1
9
10
2471.09869
3
2453.53866
-5
1882.31248
3
1864.75253
3
1873.02739
1
10
11
2471.91520
-2
2452.68333
-6
1284.43221
-3
1883.12535
-1
1863.89355
3
1872.98694
-2
11
12
2472.72989
-0
2451.82627
-3
1283.55373
-9
1863.03244
-1
1872.94280
0
12
13
2473.54259
-5
2450.96744
0
1305.24710
-2
1282.67194
1
1862.16926
0
1872.89487
0
13
14
2474.35341
-2
2450.10678
0
1306.03322
-1
1281.78650
-8
1861.30394
-1
1872.84314
-2
14
15
2475.16230
6
2449.24423
-8
1306.81570
-2
1280.89785
6
1886.35441
-2
1860.43648
-2
1872.78762
-4
15
16
2475.96902
-3
2448.38000
-1
1307.59463
4
1280.00564
9
1887.15585
-9
1859.56690
0
1872.72831
-2
16
17
2476.77379
-3
2447.51378
-8
1308.36969
-14
1887.95506
-1
1858.69517
5
1872.66515
0
17
18
2477.57659
7
2446.64577
-8
1309.14139
-5
1278.21085
8
1888.75185
3
1857.82112
-3
1872.59808
-2
18
19
2478.37706
-6
2445.77588
-6
1309.90951
8
1277.30825
0
1889.54602
-12
1856.94493
-3
1872.52714
-2
19
20
2479.17554
-5
2444.90404
-9
1310.67377
-1
1276.40235
3
1890.33802
2
1856.06651
-3
1872.45224
-5
20
21
2479.97188
-0
2444.03035
-3
1311.43460
11
1891.12734
-3
1855.18583
-3
1872.37343
-4
21
22
2480.96597
-0
2443.15460
-6
1274.58023
-3
1891.91421
0
1854.30289
-1
1872.29066
-0
22
23
2481.55781
-1
2442.27692
-4
1273.66405
-9
1872.20381
-5
23
24
2482.34739
0
2441.39722
-3
1313.69477
-2
24
25
2483.13462
-1
2440.51546
-3
1894.25933
13
1851.64006
0
25
26
2483.91956
5
2439.63162
-3
1270.89558
2
1895.03549
-7
1871.91903
-0
26
27
2484.70199
-0
2438.74573
2
1895.80925
5
1849.85292
0
1871.81587
2
27
28
2485.48206
4
2437.85762
-1
1316.65749
4
1269.03310
4
1896.58015
7
1848.95569
0
1871.70855
5
28
29
2486.25959
2
2436.96744
6
1317.38888
-10
1268.09675
-5
1897.34821
5
1848.05598
0
1871.59697
5
29
30
2487.03463
5
2436.07491
-2
1318.11680
-6
1267.15722
1
1898.11342
2
1847.15377
2
1871.48119
9
30
31
2487.80703
2
2435.18026
3
1318.84099
-8
1266.21426
-4
1898.87575
0
1846.24901
4
31
32
2488.57688
6
2434.28332
6
1319.56171
8
1265.26798
-9
32
33
2489.34404
8
2433.38403
5
1264.31855
1
1900.39152
-9
1871.10783
8
33
34
2490.10843
5
2432.48243
8
1320.99175
0
1263.36575
3
1843.51900
0
1870.97468
14
34
35
2490.87011
7
2431.57840
7
1321.70123
-8
1870.83705
16
35
36
2491.62895
7
2430.67195
6
1322.40721
1
1261.45030
9
1902.64272
9
1841.68575
11
1870.69486
11
36
37
2492.38492
5
2429.76308
9
1260.48758
4
1840.76493
10
1870.54823
14
37
38
2493.13800
5
2428.85162
4
1323.80805
7
1259.52158
-3
1904.12768
8
1870.39703
17
38
39
2493.88814
7
2427.93769
7
1324.50288
2
1258.55235
-7
1904.86538
15
1838.91487
8
39
40
2494.63526
8
2427.02116
7
1325.19406
-1
1257.57985
-13
1905.59947
-9
1870.08069
16
40
41
2495.37922
-2
2426.10199
6
1906.33066
11
1837.05332
8
1869.91542
7
41
42
2496.12026
7
2425.18020
9
1326.56555
10
1255.62535
-2
1869.74563
19
42
43
2496.85810
10
2424.25567
9
1327.24571
9
1869.57082
7
43
44
2497.59259
0
2423.32835
4
1327.92218
7
1253.65792
9
44
45
2498.32396
3
2422.39831
5
1328.59496
5
45
46
2499.05199
1
2421.46546
9
1832.34713
8
46
47
2499.77670
3
2420.52963
1
1868.8236
18
47
48
2500.49798
1
2419.59096
-0
1330.59128
9
1868.6242
-4
48
49
2501.21576
-6
2418.64934
-2
1331.24930
7
1829.48599
6
49
50
2501.93013
-5
2417.70487
11
1331.90367
10
50
51
2502.64099
-1
2416.75712
-3
1332.55433
12
1246.67027
-9
1827.56237
7
51
52
2503.34821
-3
2415.80641
-5
1333.20120
5
1245.65940
3
1826.59550
-2
52
53
2504.05187
3
2414.85265
-2
1333.84444
6
53
54
2504.75172
-5
2413.89574
-1
1334.48395
6
54
55
2505.44792
-7
2412.93559
-5
1335.11972
4
55
56
2506.14042
-2
1335.75180
5
1822.69443
3
56
57
2506.82919
9
2411.00571
-5
57
58
2507.51397
6
2410.03589
-2
1337.00468
-2
1239.52670
-0
1820.7232
21
58
59
2508.19484
-1
59
60
2508.87187
1
2408.08619
-6
1237.45724
15
60
61
2509.54504
11
2407.10639
2
1338.85635
30
1236.41759
9
61
62
2510.21403
2
2406.12314
6
62
63
2510.87899
-8
2405.13649
13
63
64
2511.54004
-4
2404.14615
-4
64
66
2512.84999
16
66
67
2513.49844
-9
2401.15476
7
67
68
2514.14332
26
68
69
2514.78331
-12
2399.14275
7
69
70
2515.41969
9
70
72
2516.6793
1
2396.0979
7
72
74
2517.9219
-15
2394.04992
-0
74
75
2518.5370
-6
2393.02022
-34
75
76
2519.1477
-12
76
77
2519.7545
17
77
78
2520.3566
1
78
O - C are the observed minus the computed frequencies in cm-1 × 105.
Table V
Observed Line Positions (cm-1) of the 2000–0000 and 2000–1000 Bands of 14N216Oa
J
2000–0000 Band
2000–1000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
2564.17068
3
1279.26726
-2
0
1
2564.99506
1
2562.50144
2
1277.60155
-4
1
2
2568.51260
-3
2561.65662
3
1280.91989
7
2
3
2566.62341
3
2560.80500
4
1275.92272
3
3
4
2567.42731
0
2559.94654
1
1282.55908
-0
4
5
2568.22446
5
2559.08135
4
1274.23075
11
5
6
2569.01466
-3
2558.20935
4
6
7
2569.79811
-2
2557.33057
5
1272.52549
-0
7
8
2570.57474
1
2556.44499
3
1285.79776
-3
1271.66812
10
8
9
2571.34450
-0
2555.55264
1
1286.59910
-6
1270.80738
10
9
10
2572.10744
0
2554.65356
3
10
11
2572.86353
-0
2553.74767
-1
1269.07614
9
11
12
2573.61281
2
2552.83509
0
1288.98331
4
1268.20563
7
12
13
2574.35519
-2
2551.91578
3
1289.77135
4
1267.33193
8
13
14
2575.09079
-0
2550.98969
1
1266.45498
8
14
15
2575.81953
-1
2550.05686
-2
1265.57481
7
15
16
2576.54146
2
2549.11736
-2
1292.11538
-5
1264.69138
3
16
17
2577.25649
-3
2548.17114
-2
1292.89024
11
17
18
2577.96474
-2
2547.21824
-0
1293.66153
4
18
19
2578.66617
1
2546.25860
-4
1294.42948
-4
19
20
2579.36070
-3
2545.29233
-3
1295.19424
3
1261.12589
5
20
21
2580.04849
1
2544.31940
-2
1295.95554
-3
1260.22652
1
21
22
2580.72939
-1
2543.33978
-3
1259.32408
7
22
23
2581.40350
-0
2542.35353
-3
1297.46820
-10
1258.41842
7
23
24
2582.07080
1
2541.36069
1
24
25
2582.73124
-2
2540.36111
-6
1298.96769
-1
25
26
2583.38489
-3
2539.35501
-4
1255.68249
-6
26
27
2584.03177
-1
2538.34233
-1
1254.76435
-2
27
28
2584.67186
1
2537.32294
-10
1301.19184
-4
1253.84306
-2
28
29
2585.30507
-5
2536.29712
-6
1301.92667
3
1252.91860
.10
29
30
2585.93164
3
2535.26470
-5
1302.65815
7
1251.99122
-1
30
31
2586.55129
-3
2534.22575
-4
1303.38629
7
1251.06068
-1
31
32
2587.16423
-3
2533.18027
-2
1304.11114
8
1250.12714
5
32
33
2587.77044
0
2532.12825
-4
1304.83277
18
33
34
2588.36986
-1
2531.06974
-5
1248.25080
4
34
35
2588.96261
6
2530.00481
-1
1247.30803
-2
35
36
2589.54848
-2
2528.93336
-2
1246.36248
14
36
37
2590.12772
-1
2527.85552
2
1245.41370
7
37
38
2590.70024
-0
2526.77118
-1
1244.46214
20
38
39
2591.26609
3
2525.68049
1
1309.09299
13
39
40
2591.82523
4
2524.58340
1
40
41
2592.37764
-0
2523.47989
-3
41
42
2592.92348
5
2522.37014
2
1311.17908
8
1240.62570
2
42
43
2593.46263
5
2521.25400
2
1311.86799
7
43
44
2593.99509
-1
2520.13157
2
1238.69019
11
44
45
2594.52102
2
2519.00289
5
1313.23608
-4
1237.71809
13
45
46
2595.04034
4
2517.86792
4
1236.74313
13
46
47
2595.55312
10
2516.72668
2
1314.59154
-1
47
48
2596.05920
1
2515.57936
7
48
49
2596.55885
4
2514.42572
1
1233.80122
0
49
50
2597.05188
-3
2513.26591
-7
1232.81512
7
50
51
2597.53856
6
2512.10018
5
1231.82614
-0
51
52
2598.01866
4
2510.92821
3
1317.92489
-5
52
53
2509.75022
5
53
54
2598.95952
-0
2508.56616
3
1228.84318
5
54
55
2507.37614
5
55
56
2599.87479
-1
2506.18009
2
56
57
2600.32287
-3
2504.97811
-1
1225.83636
15
57
58
2600.7644
-28
2503.77020
-7
1224.82896
25
58
59
2601.20012
-5
2502.55657
1
59
60
2601.62924
-15
2501.33700
-2
60
61
2602.05244
5
61
62
2498.88058
-3
62
63
2602.87989
6
2497.64384
2
63
65
2603.68271
-8
2495.15318
-12
65
66
2604.07515
-3
2493.89952
-13
66
67
2604.46159
3
2492.64052
5
67
68
2604.84196
-3
2491.37592
11
68
70
2605.58512
-1
2488.83028
4
70
71
2605.94779
-15
2487.54941
-3
71
72
2486.26342
6
72
73
2606.65632
2
2484.97219
12
73
74
2607.00199
4
2483.67548
-13
74
77
2608.00548
3
2479.75589
-2
77
81
2609.2679
21
2474.46139
11
81
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table VI
Observed Line Positions (cm-1) of the 1220(e)–0000, 1220(e)–0220(e), and 0220(e)–0110 Bands of N216Oa
J
1220(e)–0000 Band
1220(e)–0220(e) Band
1220(e)–0110 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
2
1299.55557
-6
2
3
1300.38314
3
3
4
1890.20316
1
1882.66968
-1
4
5
1302.02854
9
1292.82089
-5
1891.03369
-3
1881.82625
1
5
6
1891.86297
-3
1880.98152
1
6
7
1892.69100
1
7
8
1290.24285
-11
1893.51771
1
8
9
1289.37739
10
1894.34315
0
1878.43981
-2
9
10
1306.08559
-3
1877.59019
1
10
11
2465.52921
1
1895.99026
1
1876.73935
1
11
12
2464.68124
6
1896.81195
1
1875.88732
-1
12
13
2486.4308
22
1285.88284
-18
1897.63247
4
1875.03418
2
13
14
2487.25452
5
1874.17988
2
14
15
2488.07746
-4
1284.11702
7
1873.32449
4
15
16
2488.89975
7
2461.28116
11
1872.46798
3
16
17
2489.72112
10
1885.59587
8
17
18
2490.54149
-4
1281.44421
-4
18
19
2458.72315
1
1869.89222
6
1855.49219
0
19
20
2457.86904
-10
1279.64683
8
1903.34270
9
1869.03161
5
20
21
2492.99839
2
1278.74345
15
1904.15386
0
1885.37811
2
21
22
2493.81574
-7
1904.96407
2
1867.30756
5
1885.31717
0
22
23
2455.30349
4
1905.77325
4
1866.44420
8
1885.25369
-2
23
24
1906.58137
2
1865.57995
8
1885.18774
0
24
25
2496.26399
5
2453.59024
3
1907.38850
-2
1885.11933
6
25
26
2497.07860
-6
2452.73294
10
1274.17926
8
1908.19470
-1
1863.84897
8
1885.04838
2
26
27
2497.89264
-13
1273.25696
-5
1908.99997
-1
1862.98224
1
27
28
2498.70620
-8
2451.01686
8
1272.33175
2
1909.80430
-4
1884.89924
-5
28
29
2499.51912
-10
2450.15804
-12
1910.60783
1
1861.24677
1
29
30
1911.41047
1
1860.37805
4
30
31
1269.53736
10
1912.21222
-5
1884.65799
-7
31
32
1913.01326
-4
1884.57278
-31
32
33
2502.76590
-2
2446.72051
1
1913.81355
-1
1857.76812
-4
1884.48582
-7
33
34
1914.61308
-1
1856.89714
1
1884.39635
-16
34
35
2504.38654
-3
2445.00018
-10
1265.76812
10
1856.02558
-5
1884.30490
-6
35
36
2505.19634
1
2444.13999
4
1916.21003
-5
1855.15368
-2
1884.21117
-13
36
37
2506.00576
1
2443.27956
4
1263.86496
2
1917.00758
-2
1854.28135
-2
1884.11542
-13
37
38
2506.81497
11
1884.01761
-15
38
39
2441.55844
-7
1918.60087
2
1883.91779
-16
39
40
2508.43231
6
1260.98731
-5
1919.39669
6
1883.81604
-12
40
41
2439.83744
-11
1920.19181
-9
1883.71235
-8
41
42
2438.97713
-4
1883.60664
-16
42
43
2510.85664
-5
2438.11684
-9
1849.04122
-2
1883.49920
-10
43
44
2511.66445
-5
2437.25672
-12
1922.57490
2
1848.16719
-3
1883.38977
-19
44
45
2436.39694
-1
1883.27865
-16
45
46
2435.53731
3
1255.15011
-2
1883.16584
-6
46
47
1333.57618
3
1254.16660
-11
1845.54479
-1
47
48
1253.18029
0
1844.67069
3
1882.93482
-8
48
49
2515.70224
-2
1334.93298
-16
1252.19078
-11
1843.79648
-11
1882.81666
-22
49
50
1251.19840
-11
1842.92275
15
1882.69710
-12
50
51
2431.24364
6
1336.27673
-4
1250.20316
-1
1842.04872
-2
1882.57583
-11
51
52
2430.38590
-9
1336.94342
-15
52
53
2518.93218
-6
1882.32860
-7
53
54
2428.76214
-5
1338.26712
-3
1247.19943
-5
54
55
2427.81599
-4
1338.92400
7
1246.19237
-2
55
56
2521.3554
2
2426.96036
-5
1339.57731
-6
56
57
2522.1630
-29
1340.22753
6
1244.16943
-9
1836.8100
-4
57
58
2522.97134
2
2425.25077
-8
1340.87419
-5
1243.15384
7
1835.9378
-12
58
59
2424.3968
-14
1242.13520
5
59
60
2423.5437
5
1342.15784
6
1241.11374
6
60
61
2525.39622
6
1342.79472
16
1240.08935
-4
61
62
2526.2045
-20
1343.42798
-5
1239.06240
11
62
63
2420.98751
-8
1344.05828
11
63
64
2420.1373
42
1344.68500
-1
64
65
2528.63119
13
1345.30855
0
65
66
1345.92868
-11
66
67
2530.2485
-65
2417.5880
-74
1346.54564
-11
67
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table VII
Observed Line Positions (cm-1) of the 2110–0110 and 2110–0000 Bands of N216Oa
J
2110(e)–0110(e) Band
2110(f)–0110(f)Band
2110–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
3166.68528
-3
0
1
2578.7423
-5
2578.7432
0
3167.5103
-37
1
2
2579.5607
-11
2575.4024
2
2579.5690
6
2575.3996
-17
2
3
2580.37252
4
2574.5506
-11
2580.38444
-1
2574.5475
-14
3169.14224
-12
3163.3203
-28
3165.8281
-37
3
4
2581.17748
0
2573.6923
-8
2581.19379
-6
2573.6894
-3
3169.9485
-19
3162.46362
3
3165.81184
10
4
5
2581.97582
3
2581.99706
-8
3170.7485
-17
3165.79095
12
5
6
2582.76744
2
2571.95574
-7
2582.79427
-4
2571.95472
-4
3171.54211
-19
3160.73064
-5
3165.76582
8
6
7
2583.55233
-3
2583.58531
-5
3172.3294
-17
3159.8544
-38
3165.7362
-28
7
8
2584.33060
-1
2570.1925
-19
2584.37029
-0
2570.1957
-13
3173.11043
-5
3158.97257
0
3165.70313
8
8
9
2585.10215
-1
2569.30114
-5
2585.14909
-2
2569.30714
-13
3173.88492
-12
3165.6653
-15
9
10
2585.86702
-1
2568.40312
4
2585.92179
-2
2568.41267
-1
3174.65326
3
3157.18924
-4
3165.62375
7
10
11
2586.62520
0
2567.49831
-4
2586.68832
-7
2567.51204
-1
3175.4152
14
3156.28827
5
3165.57774
-2
11
12
2587.37670
3
2566.58705
3
2587.44884
-2
2566.60539
0
3176.17062
9
3155.38083
-5
3165.52774
6
12
13
2588.12154
9
2565.66912
2
2588.20317
-5
2565.69262
-10
3176.91962
-0
3154.46724
-4
3165.47345
0
13
14
2588.85951
-2
2564.74460
1
2588.95148
1
2564.77399
-5
3177.66228
-7
3153.5472
-21
3165.41509
2
14
15
2589.59089
-2
2563.81349
-0
2589.69361
3
2563.84930
-6
3178.39872
1
3165.35259
3
15
16
2590.31563
4
2562.87582
-0
2590.42959
-8
2562.91862
-8
3179.12871
1
3151.68894
1
3165.28599
8
16
17
2591.03359
1
2561.93158
-1
2591.15961
-1
2561.98206
-1
3179.85232
0
3150.75030
-3
3165.21521
7
17
18
2591.74485
-2
2560.98085
5
2591.88342
-6
2561.03947
-2
3180.56959
3
3149.80555
5
3165.14024
-2
18
19
2592.44944
-2
2560.02349
3
2592.60131
6
2560.09083
-12
3181.28041
-3
3148.85434
-10
3165.06129
3
19
20
2593.14737
2
2559.05964
5
2593.31295
0
2559.13645
-4
3181.98490
-4
3147.8968
-37
3164.97814
-3
20
21
2593.8386
4
2558.08919
1
2558.17606
-5
3182.68309
2
3146.93361
-9
3164.89115
17
21
22
2557.11223
-3
2594.71815
2
2557.20979
-3
3183.37481
-2
3164.79973
2
22
23
2595.20092
3
2556.12881
-1
2595.41162
-1
2556.23762
-3
3184.06014
-8
3144.9878
-35
3164.7041
-27
23
24
2595.87202
-0
2555.13892
4
2596.09908
-0
2555.25962
1
3184.7394
16
3144.0065
39
3164.60499
3
24
25
2596.53649
2
2554.14244
-2
2596.78051
1
2554.27562
-9
3185.41181
-9
3164.50156
5
25
26
2597.19423
-0
2553.1394
-16
2597.45584
-5
2553.28594
-3
3186.07824
6
3164.39407
5
26
27
2597.84536
4
2552.13024
5
2598.12526
1
2552.29042
-0
3186.7382
9
3164.28261
11
27
28
2551.11432
-4
2598.78857
-5
2551.28900
-7
3187.39172
5
28
29
2599.12750
4
2550.09209
-0
2599.44599
1
2550.28190
-3
3188.03881
-6
3164.0472
-24
29
30
2599.75856
3
2549.06344
5
2600.09735
-2
2549.26892
-12
3188.67969
-2
3163.92387
-6
30
31
2600.38298
4
2548.02826
-1
2600.74272
-7
2548.25042
2
3189.31420
-0
3163.79648
4
31
32
2601.00069
0
2547.98678
4
2601.38219
-6
3189.9424
6
3163.66509
9
32
33
2601.61178
-0
2545.93878
-4
2602.01578
0
2546.19596
-3
3190.56414
1
3163.52969
7
33
34
2602.21620
-3
2544.88451
-1
2602.64329
-9
2545.16022
-5
3191.17951
-7
3163.39024
-8
34
35
2602.81406
2
2543.82388
2
2603.26507
-0
2544.11889
0
3191.78874
5
3163.2469
-21
35
36
2603.50419
-2
2542.75687
3
2603.88089
1
2543.07181
-8
3192.39146
-0
3163.09994
-7
36
37
2603.98972
-4
2541.68351
3
2604.49074
-7
2542.01925
-3
3192.98787
-4
3162.94914
9
37
38
2604.56772
4
2540.60384
3
2605.09489
0
2540.96109
-1
3193.5778
-23
3162.79414
-9
38
39
2605.13894
-6
2539.51779
-4
2605.69309
-4
2539.89739
2
3194.16174
-10
3162.63574
15
39
40
2605.70379
8
2538.42558
1
2606.28552
-5
2538.82812
0
3194.73927
-6
3162.47324
10
40
41
2606.26181
-1
2606.87222
1
2537.75340
3
3195.31053
2
3162.30692
1
41
42
2606.81336
1
2536.22210
-11
2607.45310
2
2536.67317
0
3195.87535
-5
3162.13704
13
42
43
2607.35840
10
2535.11114
-2
2608.02821
0
2535.58755
3
3196.43403
3
3161.96324
7
43
44
2607.89672
3
2533.99387
-3
2608.59763
1
2534.49650
2
3196.98634
2
3161.78564
-7
44
45
2608.42847
-5
2532.87047
4
2609.16127
-6
2533.40000
-7
3197.53239
3
3161.4199
14
45
46
2608.95379
-2
2531.74070
-8
2609.71937
0
2532.29830
-1
3198.07214
1
46
47
2609.47267
10
2530.60499
3
2610.27173
-4
2531.19130
4
3198.6055
-15
3161.23144
13
47
48
2529.46297
-3
2610.81850
-5
2530.07888
-5
3199.13291
-1
48
49
2610.49055
2
2611.35966
-9
2528.96137
-0
3160.8431
-51
49
50
2610.98979
2
2527.16064
-8
2611.89544
4
2527.8389
28
3200.16888
11
50
51
2611.48257
4
2526.00044
-0
2612.42564
12
2526.71067
-3
3200.67743
6
51
52
2611.96894
11
2524.83408
-3
2612.95012
-3
2525.57764
-3
52
53
2612.44873
6
2523.66165
-9
2613.46930
-3
2524.43949
-7
3201.6761
12
53
54
2612.92204
-5
2523.29636
-5
3202.1661
8
54
55
2613.38906
-4
2521.29889
-9
2614.49128
-17
2522.14824
-2
55
56
2613.84960
-10
2520.1090
36
2614.99448
0
2520.99529
12
3203.1280
37
56
57
2614.30384
-10
2518.91244
7
2615.49215
-4
2519.83715
-2
57
58
2614.75197
16
2517.71014
-4
2615.98454
-10
2518.67431
1
58
59
2615.19335
0
2616.4716
-26
2517.5069
27
59
60
2615.6289
33
2515.28811
-8
2616.95380
-10
2516.33424
5
60
61
2616.05744
-6
2514.06862
19
2617.4309
10
2515.1567
-34
61
62
2617.90269
8
2513.97514
-9
62
63
2616.8968
22
2511.61180
23
2618.36941
4
2512.78876
-5
63
64
2617.3070
22
2510.3748
27
2618.83094
-19
64
65
2617.71084
6
2619.2878
-15
2510.40241
5
65
66
2618.1083
-33
2507.8838
43
66
67
2618.50051
18
2620.18697
1
2507.99809
-7
67
68
2618.88617
24
2505.36981
12
2620.62940
14
2506.78964
10
68
69
2619.26548
2
2504.10444
-6
2621.06684
0
2505.5768
13
69
70
2619.63904
9
2502.8341
31
2621.49963
-11
2504.3592
-41
70
71
2621.92807
3
2503.1382
-21
71
72
2500.2762
22
72
73
2622.7708
-27
73
74
2499.4505
-25
74
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table VIII
Observed Line Positions (cm-1) of the 1310–0110 and 1310–0000 Bands of N216Oa
J
1310(e)–0110(e) Band
1310(f)–0110(f)Band
1310–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
3047.0482
-24
0
1
2459.11314
-5
2459.12126
-5
3047.8810
-44
1
2459.94284
-17
2459.95744
-24
3048.71209
15
2
3
2460.77001
3
2460.79269
-14
3043.6911
-26
3
4
2461.59403
-5
2461.62677
0
4
5
2462.41534
3
2453.22489
-2
2462.45946
-3
2453.23351
1
3051.18826
1
3041.9972
-64
5
6
2463.23366
-1
2452.37224
-17
2452.38759
-9
3052.00857
-3
3041.1471
-24
6
7
2464.04914
1
2451.51704
-5
2464.12117
-6
2451.54059
-8
3052.82643
3
3040.29429
-6
7
8
2464.86170
0
2450.65881
-13
2464.95019
-3
2450.69248
-2
3053.64154
-9
3039.4387
-17
8
9
2465.67133
-2
2449.79794
-3
2465.77794
-1
2449.84309
-5
3054.45428
-0
3038.58086
-4
9
10
2466.47810
1
2448.93411
-6
2466.60437
-4
2448.99260
-1
3055.26422
-13
3037.72042
-1
10
11
2467.28182
-7
2448.06749
-5
2467.42959
1
2448.14090
1
3056.07183
3
3036.85738
-8
11
12
2468.08273
-1
2447.19807
-1
2468.25346
2
2447.28792
-5
3056.87654
-11
3035.99187
-12
3046.26894
3
12
13
2468.88063
0
2446.32581
2
2469.07599
1
2446.43387
-3
3057.67884
-2
3035.12392
-10
3046.27813
5
13
14
2469.67555
1
2445.45063
-2
2469.89716
-2
2445.57859
-2
3058.47830
-12
3046.28795
7
14
15
2470.46753
6
2444.57269
2
2470.71699
-5
2444.72213
1
3059.27519
-14
3033.38051
-2
3046.29839
7
15
16
2471.25641
2
2443.69177
-7
2471.53546
-6
2443.86438
-3
3060.06951
-4
3032.5050
0
3046.30946
8
16
17
2472.04232
3
2442.80826
11
2472.35251
-10
2443.00540
-9
3060.86102
-6
3046.32114
10
17
18
2472.82515
0
2441.92169
9
2473.16826
-3
2442.14526
-7
3061.64985
-5
3046.33340
10
18
19
2473.60501
6
2473.98253
-1
2441.28389
-5
3062.43592
-7
3029.8630
-21
3046.34624
12
19
20
2474.38175
7
2474.79532
-3
3063.21928
-4
3028.97755
4
3046.35954
3
20
21
2439.24462
-6
2475.60661
-7
2439.55732
-7
3063.99988
-1
3028.08924
0
3046.3735
7
21
22
2475.92589
5
2438.34659
1
2476.41655
4
2438.69209
-13
3064.77765
-1
3027.19844
4
3046.3879
4
22
23
2476.69319
-5
2437.44554
-4
2477.22482
-1
2437.82561
-14
3065.5523
-32
3026.3047
-27
3046.4028
0
23
24
2477.45752
4
2436.54162
-4
2478.03154
-6
2436.95799
0
3066.32464
-11
3025.4092
27
3046.4183
9
24
25
2478.21856
1
2435.63479
-2
2436.08896
6
3024.51024
-5
3046.43404
-3
25
26
2478.97646
4
2434.72499
-2
2479.64056
16
2435.2183
-19
3067.86035
-8
3023.6088
-22
3046.45034
-3
26
27
2479.73105
-3
2433.81231
4
2480.44240
2
2434.34669
-3
3068.62382
-11
3022.7049
-21
3046.46704
-3
27
28
2480.48253
3
2481.24270
-1
2433.47352
-6
3069.38445
-5
3021.7987
15
3046.48415
-2
28
29
2431.97789
3
2482.04137
1
2432.59904
-2
3070.14210
-2
3046.50163
4
29
30
2481.97556
2
2431.05622
5
2482.83833
3
2431.72302
-11
3070.89673
-5
3046.5194
5
30
31
2482.71696
-16
2430.13149
2
2483.63344
-6
2430.84566
-12
3071.64839
-4
3019.0630
21
3046.5374
-2
31
32
2483.45546
10
2429.20379
3
2484.42697
5
2429.96689
-8
3072.39697
-10
3046.5557
-6
32
33
2484.19017
-8
2428.27296
-4
2485.21848
-6
2429.08662
-8
3073.14268
3
3046.5743
-4
33
34
2484.92179
3
2427.33931
11
2486.00837
4
2428.20501
7
3073.8850
-16
3046.5931
-3
34
35
2485.64990
3
2426.40226
-6
2486.79628
4
2427.3218
14
3074.62450
-7
3046.61214
3
35
36
2486.37456
2
2425.46242
5
2487.58228
4
2426.43684
1
3075.36089
4
3046.6311
-13
36
37
2487.09572
-5
2424.51926
-5
2488.36624
-6
2425.55042
-2
3076.09399
2
3046.6504
-6
37
38
2423.57314
-0
2489.14842
4
2424.66251
5
3076.82384
-8
3046.6697
-8
38
39
2488.52772
-4
2422.62386
2
2489.92848
3
2423.77288
2
3077.55061
-4
3046.6890
-14
39
40
2489.23842
-5
2421.67132
-7
2490.70641
-5
2422.88159
-2
3078.27411
-3
3046.7084
-11
40
41
2489.94564
1
2420.71565
-12
2491.48242
4
2421.98859
-10
3078.9943
-7
3046.7278
-5
41
42
2490.64915
-5
2419.75709
12
2492.25609
-7
2421.09412
6
42
43
2491.34909
-8
2418.79499
2
2493.02781
4
2420.19769
-0
3080.4250
8
43
44
2492.04549
-1
2493.79711
-6
2419.29959
3
3081.13517
0
44
45
2492.73826
9
2416.86134
5
2494.56426
-5
2418.39966
3
45
46
2493.42707
-8
2415.88959
1
2495.32908
-7
2417.49792
6
46
47
2494.11232
-10
2414.91457
-4
2496.09155
-9
2416.5940
-24
3083.2454
-15
47
48
2494.79404
10
2413.93619
-15
48
49
2495.47162
-8
2497.60929
-14
2414.78127
2
3084.6353
12
49
50
2496.14566
-0
2498.36451
-12
50
51
2496.81602
21
2499.11737
6
2412.9605
12
51
52
2409.99001
1
2499.86737
-5
2412.04697
7
52
53
2498.1447
18
2408.99496
-5
2500.61499
9
2411.13134
-1
53
54
2407.99680
17
2501.35986
13
2410.21364
-3
54
55
2499.45776
12
2406.99506
23
2502.10179
-5
2409.29378
-6
55
56
2405.98956
-4
2502.84136
17
2408.37186
4
56
57
2500.75504
9
2404.98081
-10
2407.44759
3
57
58
2501.39751
-10
2406.5207
-32
58
59
2502.03637
14
2402.95332
20
2505.0416
-58
2405.59221
4
59
60
2404.66090
-6
60
61
2503.3010
-30
2506.49462
-16
2403.72739
3
61
62
2503.92778
9
2402.79125
-6
62
63
2507.93505
-7
63
64
2505.16801
-3
2397.8244
35
2508.65076
19
64
65
2399.96827
15
65
66
2399.02171
-18
66
67
2506.9976
45
2510.77729
-13
67
68
2507.59844
6
68
69
2512.17854
-2
69
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table IX
Observed Line Positions (cm-1) of the 0201–0000, 0201–0200, and 0201–0110 Bands of N216Oa
J
0201–0000 Band
0201–0200 Band
0201–0110 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
3364.81108
1
0
1
3365.63927
4
3363.13999
3
2197.50510
-1
2776.87104
2
2775.20329
3
1
2
3366.46248
4
3362.29705
4
2194.15924
-2
2777.69353
-4
2773.52822
8
2775.1897
13
2
3
3367.28071
1
3361.44918
4
2199.13750
1
2193.30591
-2
2778.51083
1
2772.67922
-5
2775.16901
-1
3
4
3368.09404
5
3360.59643
8
2199.94351
-1
2192.4456
-28
2779.3229
12
2771.82508
-6
2775.14165
4
4
5
3368.90234
3
3359.73867
4
2191.57912
2
2770.9655
-25
2775.10730
-4
5
6
3369.70565
2
3358.87602
3
2201.53516
-8
2190.70560
0
2780.93080
5
2775.06618
-1
6
7
3370.50394
-1
3358.00846
4
2202.32086
-6
2189.82536
-3
2781.72676
3
2769.2314
20
2775.01816
-0
7
8
3371.29726
2
3357.13591
0
2203.09976
-4
2188.93845
-2
2782.51742
6
2768.35602
-1
2774.96328
4
8
9
3372.08546
-2
3356.25845
-0
2203.87188
1
2188.04480
-4
2783.30254
-6
2767.47562
5
2774.90144
3
9
10
3372.86867
1
3355.37607
3
2187.14453
1
10
11
3373.64672
-2
3354.48863
-3
2205.39558
-1
2186.23753
2
2784.85678
-9
2765.69889
10
2774.7568
-17
11
12
3374.41965
-6
2206.14720
-2
2185.32383
1
2785.62589
4
2764.8025
5
2774.67435
3
12
13
3375.18751
-3
3352.69891
-5
2206.89202
-1
2184.40339
-6
2786.38934
-2
2763.90074
-4
2774.58472
5
13
14
3375.95021
1
3351.79658
-2
2183.47638
-2
2787.14732
-5
2774.48807
-1
14
15
3376.70767
1
3350.88922
1
2208.36114
0
2787.89979
-6
2762.08138
-2
2774.3845
7
15
16
3377.45987
-2
3349.97676
-2
2209.08545
2
2181.60233
1
2788.6466
-17
2761.16360
-7
2774.2738
5
16
17
3378.20677
-9
3349.05926
-2
2209.80286
-1
2180.65534
5
2789.3880
-11
2760.24052
-1
2774.15592
-8
17
18
3378.94853
0
3348.13663
-6
2210.51348
3
2179.70164
3
2759.31199
1
2774.03108
-7
18
19
3379.68481
-6
3347.20895
-3
2211.21722
4
2178.74132
3
2758.37796
-4
2773.89913
-4
19
20
3380.41585
0
3346.27605
-9
2211.91407
3
2177.77437
4
2791.57830
4
2757.43857
2
2773.76007
2
20
21
3381.14132
-10
3345.33805
-8
2212.60406
3
2176.80077
3
2756.49356
-5
2773.6135
-24
21
22
3381.86150
-5
3344.39486
-7
2213.28717
3
2793.00992
14
2755.54317
1
2773.46026
5
22
23
3382.57617
-3
3343.44644
-6
2213.96341
4
2174.83372
4
2793.71684
-2
2754.58715
-2
2773.29940
-4
23
24
3383.28531
-1
3342.49284
2
2214.63274
2
2173.84027
5
2773.13136
-2
24
25
3383.98884
-3
3341.53380
-6
2215.29524
7
2172.84014
-2
2795.11346
2
2752.65819
-24
25
26
3384.68679
-3
3340.56960
2
2215.95076
4
2171.83351
2
2795.80282
-4
2751.68559
-4
2772.77332
4
26
27
3385.37910
-1
3339.59992
-3
2216.59942
4
2170.82024
2
2796.48641
10
2750.70722
6
2772.58321
5
27
28
3386.06571
1
3338.62493
-1
2217.24116
4
2169.80040
4
2797.16394
19
2749.72299
-0
28
29
3386.74657
3
3337.64448
-2
2217.87602
6
2168.77392
1
2797.83524
11
2748.73304
-5
2772.18064
4
29
30
3387.42164
4
3336.65861
1
2218.50395
8
2167.74091
3
2798.50051
10
2747.73744
2
30
31
3388.09082
1
3335.66725
4
2219.12496
9
2166.70129
2
2799.15964
10
2746.73599
5
2771.74810
8
31
32
3388.75417
3
3334.67030
2
2219.73898
4
2165.65517
8
2745.72862
-1
2771.52046
10
32
33
3389.41157
5
3333.66781
3
2220.34614
5
2164.60235
1
2800.45924
7
2744.71546
3
33
34
3390.06298
5
3332.65968
1
2220.94635
5
2163.54308
5
2801.09970
12
2771.04226
14
34
35
3390.70834
4
3331.64597
7
2221.53963
6
2162.47718
1
2801.7336
-4
2742.6713
5
2770.79154
9
35
36
3391.34773
15
3330.62650
6
2222.12595
5
2161.40482
6
2802.36146
14
2741.64028
10
36
37
3391.98076
4
3329.60132
8
2222.70538
10
2160.32580
-0
2802.98270
13
2740.60312
3
2770.26699
20
37
38
3392.60776
8
3328.57029
2
2223.27779
7
2159.24045
15
2803.59742
9
2739.55998
6
38
39
3393.22845
4
3327.53349
1
2223.84325
5
2804.20565
8
2738.51075
11
2769.71092
15
39
40
3393.84291
7
2224.40178
5
2157.04975
4
2804.80727
5
2737.45543
2
40
41
3394.45096
2
3325.44247
20
2224.95330
0
2155.94465
2
2805.40253
28
2736.39371
13
41
42
3395.05270
5
3324.38781
4
2225.4978
-11
2154.83315
12
2805.99067
7
2735.3257
-2
2768.8169
-25
42
43
3395.64790
-2
3323.32733
4
2226.0357
15
2806.57229
7
2734.25170
11
2768.50334
12
43
44
3396.23668
-3
3322.26078
1
2226.56636
14
2807.1469
-18
2733.17109
-6
2768.18132
13
44
45
3396.81892
-4
3321.18815
-4
2227.0898
-13
2151.45921
5
2807.71526
14
2732.08409
-26
2767.8509
-11
45
46
3397.39454
-8
3320.10955
6
2808.2762
-9
2730.9912
3
2767.51273
8
46
47
3397.96356
-8
3319.02468
4
2228.1166
17
2149.17760
18
2808.83041
-15
2729.89172
16
47
48
3398.52593
-6
3317.93350
-10
2228.61918
-3
2809.3775
-37
2728.78534
-14
2766.8113
9
48
49
3316.83630
-3
2229.11520
18
2146.8696
-14
2809.9180
-18
2727.67276
-14
49
50
3399.63031
-15
3315.73278
-6
2810.45157
12
2726.55392
14
2766.07669
13
50
51
3400.17243
-6
3314.62280
-19
2230.08575
5
2144.5362
5
2810.97776
12
51
52
3400.70752
-14
3313.50663
-16
2230.56069
12
2143.35963
-2
2811.4966
-11
2724.2958
1
2765.30859
20
52
53
3401.23587
-6
2231.02849
3
2142.17680
11
2812.0081
-51
2723.1566
-17
53
54
3401.75722
-3
3311.25512
-10
2812.51326
-6
54
55
3402.2716
0
3310.11968
-10
2231.9437
41
2139.79141
-1
2813.0109
11
2764.09254
-12
55
56
3402.77895
3
3308.9776
-20
2813.50091
-9
2719.6999
3
56
57
3403.27928
8
3307.8291
-27
2232.83030
10
2137.38038
2
2813.9838
-10
2763.2400
50
57
58
3403.77255
16
3306.67442
-2
2136.16519
1
2717.3615
3
58
59
3404.25874
28
3305.51270
-19
2134.94366
8
2814.9275
-18
59
60
3304.34486
10
2234.10822
1
2133.71569
14
2815.3886
9
60
62
2131.24033
9
2816.2877
-46
62
63
3406.13078
-26
3300.80085
26
2129.99300
2
63
64
2128.73940
9
64
65
3407.0235
-54
2127.47928
3
65
66
3297.19660
18
2126.21290
10
66
67
3407.8880
13
3295.98143
-21
67
68
3408.3082
-70
3294.7605
30
2123.66084
8
68
69
2122.37497
-22
69
70
3292.2975
35
70
71
3409.5285
23
2119.7847
-24
71
73
2117.1694
11
73
74
3287.2904
-40
74
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table X
Observed Line Positions (cm-1) of the 1200–0000, 2000–0000, and 0201–0000 Bands of 14N15N16Oa
J
1200–0000 Band
2000–0000 Band
0201–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
2553.23890
8
3296.2947
-69
0
1
2432.9931
4
2554.0618
-25
2551.57030
4
3297.1235
-60
3294.6243
21
1
2
2429.6450
22
2554.87788
-1
2550.72454
-40
3293.7815
-1
2
3
2428.8029
-36
2549.87229
4
3292.9347
39
3
4
2435.4856
20
2427.96014
17
2556.48748
3
2549.0119
-31
3299.5830
67
3292.0832
71
4
5
2436.3128
28
2427.11484
-6
2557.28122
8
2548.14493
11
3300.39268
28
3291.2263
25
5
6
2437.13785
6
2426.26811
7
2558.06754
9
2547.27013
4
3290.3645
-47
6
7
2437.96124
6
2558.84634
-2
2546.38804
3
3301.9980
-39
7
8
2438.7828
13
2424.56892
-2
2559.61787
-0
3302.7943
3
3288.6292
30
8
9
2439.6020
-24
2423.71684
17
2560.38193
-6
2544.60189
4
3303.5853
-7
3287.75409
21
9
10
2561.13872
3
2543.69776
-2
3286.8743
12
10
11
2422.0066
-4
2561.88792
-7
2542.78643
4
3305.1530
-12
3285.9895
-28
11
12
2442.0495
41
2421.14892
8
2562.62994
7
2541.86773
5
3305.9297
-0
3285.1007
4
12
13
2563.36437
2
2540.94174
7
3306.7013
-7
13
14
2564.09130
-10
2540.00830
-4
3283.3082
3
14
15
2418.56412
9
2564.81105
2
2539.06771
-1
3308.2297
-12
3282.40485
11
15
16
2445.2827
-2
2565.5231
-14
2538.11981
1
3281.49654
5
16
17
2446.0855
-23
2416.83118
11
2566.22805
2
2537.16457
-2
3309.73805
-9
3280.58325
-13
17
18
2415.9614
-18
2566.92544
6
2536.20210
0
3310.4843
-33
3279.66518
-19
18
19
2415.09019
17
2567.61540
9
2535.23239
7
3311.2257
-25
3278.7423
-13
19
20
2414.2163
-9
2568.2978
0
2534.25528
-0
3311.9622
15
3277.8144
-13
20
21
2413.34065
3
2568.97281
-5
2533.27099
2
3276.8815
-12
21
22
2450.0660
-13
2412.46278
9
2569.64044
-3
2532.27943
2
3313.4186
22
3275.94370
4
22
23
2450.8551
15
2411.58271
16
2570.30072
7
2531.28049
-10
23
24
2451.6413
7
2410.70033
16
2570.95335
-4
2530.27454
2
3314.8532
3
3274.0523
-12
24
25
2452.4250
10
2409.81568
18
2571.59872
4
2529.26119
-2
3315.5623
-6
25
26
2408.92870
20
2572.2365
-3
2528.24060
-6
3316.2654
-60
3272.1404
-5
26
27
2453.9847
45
2408.03919
8
2527.21281
-8
3316.9640
-2
27
28
2454.7595
-30
2407.1473
0
2573.48982
-7
2526.17779
-11
3317.6567
32
3270.20721
-15
28
29
2406.25309
8
2574.10548
8
2525.13566
-3
3318.3436
59
3269.2329
12
29
30
2405.35626
7
2574.71344
-1
2524.08626
-2
3268.2525
-28
30
31
2404.4569
11
2575.31404
-2
2523.02971
4
3319.6993
45
31
32
2403.5551
33
2575.90722
1
2521.96586
-1
3266.2769
63
32
33
2458.59409
15
2402.65013
6
2520.89481
-7
3265.2795
-18
33
34
2401.7425
-13
2519.81667
-5
3321.6881
-5
3264.27761
16
34
35
2460.1058
-30
2577.64199
3
2518.73137
-2
35
36
2399.9194
6
2578.20532
2
2517.63889
-0
36
37
2399.0035
12
2516.53932
7
3323.6219
-76
3261.2367
26
37
38
2398.0845
2
2579.30966
3
2515.43245
-1
3260.2116
44
38
39
2463.0912
37
2397.1622
-37
2579.85064
2
2514.31855
2
39
40
2396.23771
11
2513.19751
3
3325.50052
-28
3258.1432
31
40
41
2580.91027
3
2512.0691
-22
3257.1000
20
41
42
2465.2931
29
2394.3783
1
2581.4286
-28
2510.9341
6
42
43
2393.4440
16
2581.94007
1
2509.79156
-10
3254.9959
41
43
44
2466.7431
62
2392.5058
-33
2508.64228
8
44
45
2467.4616
-5
2391.5651
-0
2582.94012
2
2507.4854
-25
3252.8672
49
45
46
2468.1769
-6
2390.62085
14
2583.42892
-4
2506.32211
7
3329.0817
-57
3251.7933
26
46
47
2389.6724
-51
2583.9104
3
2505.15136
-0
3329.6560
2
47
48
2469.5959
5
2388.7212
-45
2584.3843
-5
2503.97366
2
3249.6268
-16
48
49
2584.85099
10
2502.78889
1
3248.5349
42
49
50
2386.8089
31
50
51
2471.6941
2
51
52
2586.20593
0
2499.19257
10
52
53
2497.97967
-0
53
54
2587.07217
-1
2496.75980
-9
54
55
2587.49421
3
2495.5330
-13
55
56
2494.2994
-2
56
59
2589.1082
5
2490.5567
1
59
60
2589.49319
2
2489.2954
12
60
61
2488.0268
-19
61
62
2486.7518
-3
62
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XI
Observed Line Positions (cm-1) of the 1200–0000, 2000–0000, and 0201–0000 Bands of 15N14N16Oa
J
1200–0000 Band
2000–0000 Band
0201–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O - C
P Branch
O – C
0
0
1
2438.8148
-12
2533.72235
1
3335.3445
48
1
2
2438.0034
-21
2536.92457
-11
2532.90666
12
3332.1152
28
2
3
2442.84754
6
2437.1909
19
2537.71009
6
2532.08470
3
3
4
2443.6488
-36
2436.3761
-13
2538.48925
-5
2531.25674
1
3330.4710
-18
4
5
2444.44926
6
2539.26245
-1
2530.42264
-8
3338.4952
18
5
6
2445.2473
-29
2434.74247
-4
2540.02948
-4
2529.58254
-10
3339.2703
-19
3328.80832
33
6
7
2446.04450
17
2433.92322
-4
2540.79048
0
2528.73629
-23
3340.0407
-34
3327.96925
15
7
8
2446.83944
5
2541.54540
6
2527.88439
5
3340.8065
-13
3327.1252
-14
8
9
2447.63274
-3
2432.27994
-3
2542.29409
-0
2527.02612
-0
3341.5673
1
3326.27661
-9
9
10
2448.4244
-4
2431.45591
-2
2543.03667
-8
2526.16189
2
10
11
2449.2142
-19
2543.77332
2
2525.29159
0
3343.0736
7
11
12
2450.00264
4
2429.80299
1
2544.50372
-3
2524.41519
-10
3343.8190
-14
3323.70142
-4
12
13
2450.78907
3
2428.9740
-7
2545.22810
0
2523.53311
13
3344.5595
-21
13
14
2451.57370
-1
2428.14345
-6
2522.64449
-17
3345.2954
18
3321.9602
12
14
15
2546.65856
5
15
16
2453.1374
-20
2426.4774
-2
2547.36459
2
2520.85011
5
3320.1986
-35
16
17
2548.06454
-0
2519.94376
-4
3319.3110
6
17
18
2454.69419
12
2424.80449
-11
2548.75846
3
2519.03176
19
3318.41802
8
18
19
2455.46956
10
2423.96549
-13
2549.44618
-6
2518.11338
-1
3348.8957
-13
3317.51995
1
19
20
2456.24309
17
2550.12802
5
2517.18926
-1
3349.6001
-28
20
21
2550.80359
-3
2516.25919
-3
3350.2996
-7
3315.7092
37
21
22
2421.43804
-16
2551.47322
1
2515.32328
3
3350.9936
-7
22
23
2458.55149
11
2420.59202
-15
2514.38139
1
23
24
2459.31680
-0
2552.79430
10
2513.43360
-2
3352.3655
-15
3312.9539
-20
24
25
2460.08024
11
2418.89464
1
2553.44566
3
2512.48000
1
3353.0436
3
3312.0254
-21
25
26
2418.04292
-16
2554.09102
1
2511.52049
0
3353.7160
-5
26
27
2417.18943
-21
2554.73041
5
2510.55522
8
3354.3834
33
3310.1530
-10
27
28
2462.3573
6
2416.33414
-15
2555.36366
-3
2509.58379
-17
3355.0444
-18
3309.2094
38
28
29
2463.11182
-5
2415.4771
11
2555.99102
2
2508.60686
-10
3308.25966
-4
29
30
2463.86429
6
2414.61780
7
2556.61237
6
3307.3054
31
30
31
2464.61430
1
2413.7564
-6
2557.2273
-32
2506.63562
3
3356.9961
37
3306.3454
24
31
32
2465.3624
39
2412.8930
-17
2557.83702
7
2505.64129
4
3357.6351
27
3305.3798
-10
32
33
2412.02792
9
2558.44029
-2
2504.64116
1
3358.2679
-33
3304.4093
4
33
34
2466.8500
-26
2411.16044
5
2559.03782
11
2503.63533
-1
3358.8958
-8
3303.4332
-1
34
35
2467.59087
15
2410.29093
9
2559.62909
-8
2502.62379
-2
3302.4519
18
35
36
2468.3285
-17
2409.4189
-24
2560.21476
7
3301.4646
-16
36
37
2408.54526
0
3360.7442
26
3300.4720
-29
37
38
2469.79702
11
2407.66919
3
2561.36802
2
2499.55514
-4
3361.3480
-18
3299.4747
43
38
39
2470.5271
-1
2406.79096
15
2561.9355
-32
2498.52099
-4
3361.9463
-17
3298.4707
3
39
40
2405.9105
32
40
41
2471.97950
4
2405.02733
10
2563.0536
-26
2496.4357
-24
3363.1250
3
3296.4465
-8
41
42
2472.70159
6
2563.60417
6
3363.7050
-11
42
43
2473.42080
-1
2403.25413
-11
2564.14869
11
2494.2856
-7
3364.2795
39
43
44
2474.1369
-34
2402.36419
6
2564.6874
20
2493.26680
9
3293.3676
-11
44
45
2401.4718
24
2492.1992
-11
3365.4081
-42
45
46
2475.5619
49
2400.5763
-20
2491.1265
4
3365.9635
-34
3291.28598
-21
46
47
2399.6788
-12
2566.26852
-5
2490.0483
10
3366.5133
45
47
48
2476.97389
18
2398.7791
33
2488.96459
5
3367.0551
-41
3289.1809
-30
48
49
2477.67529
-1
2397.87619
18
2567.2940
-23
2487.8753
-21
3288.1202
40
49
50
2396.9706
-3
2567.7985
-6
3368.1214
-17
3287.0529
48
50
51
2396.0622
-37
2485.68166
16
3285.9792
17
51
52
2395.1516
-21
2484.5766
2
52
53
2394.2380
-31
2569.27795
11
2483.4665
8
53
54
2481.13608
17
2393.3218
-23
2569.7600
20
54
55
2392.4028
-14
2570.2363
6
55
56
2482.4976
30
2391.4812
19
2570.70711
-8
2480.1051
20
56
57
2483.1728
-14
57
58
2483.8453
16
2571.6327
-4
58
59
2572.0874
-2
59
60
2572.53685
11
60
61
2474.4013
21
61
62
2573.4194
-9
2473.2457
19
62
63
2573.8528
-18
63
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XII
Observed Line Positions (cm-1) of the 1200–0000, 2000–0000, and 0201–0000 Bands of 14N218Oa
J
1200–0000 Band
2000–0000 Band
0201–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
2412.29589
-4
2491.9727
-15
3345.1896
-11
0
1
2413.08329
9
2410.71559
3
2492.75344
4
2490.39584
-1
3343.6125
17
1
2
2409.92254
7
2493.52864
1
2489.5995
11
3342.8162
-4
2
3
2414.65206
17
2409.12739
-6
2494.29854
-1
2488.7974
-25
3347.5189
22
3342.0150
-22
3
4
2415.43324
-5
2408.3302
-29
2495.06320
4
2487.99065
5
3348.2854
31
4
5
2416.21274
2
2407.5313
-31
2495.82234
-12
2487.17829
2
5
6
2416.99014
-2
2406.73078
-1
2496.57637
-8
2486.36075
8
3349.8027
-27
6
7
2417.76566
5
2405.92809
4
2497.32521
8
3350.5540
-42
3338.76184
-1
7
8
2418.5392
16
2405.12331
-5
2498.06851
2
3351.3010
13
3337.93607
-10
8
9
2419.31044
-1
2404.31664
-10
2498.80654
-2
2483.87626
-0
3337.10564
8
9
10
2420.07989
6
2403.50808
-9
2499.53924
-8
2483.0374
-23
3352.77895
28
10
11
2420.8468
-35
2402.69762
-4
2500.26674
-5
2482.19380
4
3353.5104
40
11
12
2421.61249
8
2401.88512
-6
2500.98909
13
2481.34471
4
3354.2363
4
3334.58400
-3
12
13
2401.07064
-10
2501.70594
9
2480.49039
1
3354.9575
8
3333.73361
2
13
14
2423.13659
-5
2400.2542
-13
2502.41754
8
3355.67333
-15
3332.87820
2
14
15
2423.89566
8
2399.43591
-2
2503.12385
6
2478.7663
10
3356.3842
-20
3332.01769
-9
15
16
2398.61550
-4
2503.82492
5
2477.89646
10
3357.0903
12
16
17
2397.79308
-6
2504.52059
-10
2477.02143
7
3357.79066
-12
3330.28185
-12
17
18
2426.15949
7
2396.96868
-4
2505.21124
-3
2476.14119
-3
3358.48632
14
18
19
2426.90976
12
2396.14222
-4
2505.89661
-0
2475.25606
10
3359.17619
-17
19
20
2395.31377
1
2506.57671
-3
3359.8615
21
3327.64047
-4
20
21
2428.40334
1
2394.48313
-5
2507.25154
-12
2473.47019
3
21
22
2393.65051
-2
2507.92139
1
2472.5698
15
3361.21514
-16
3325.85422
2
22
23
2392.81581
4
2508.58584
-9
2471.66422
12
3361.8844
8
3324.95330
-8
23
24
2391.97889
-0
2470.75354
1
3362.54797
-2
3324.0474
-4
24
25
2431.36307
8
2391.13984
-3
2509.89962
6
2469.83792
-3
3363.20619
-7
3323.13625
-9
25
26
2390.29870
1
2468.91754
14
3363.85908
-4
3322.2202
13
26
27
2432.82844
-6
2389.45532
-1
2511.19266
-1
2467.99194
4
3364.50639
-13
3321.29854
-6
27
28
2433.55748
-9
2388.60976
-1
2511.83164
6
2467.06146
-1
28
29
2387.76194
-3
2466.12606
-8
3365.7850
16
3319.4401
11
29
30
2435.00820
4
2386.91187
-5
2513.09415
-6
2465.18592
-2
3366.41557
-12
30
31
2435.72964
1
2386.05953
-7
2513.71804
4
2464.24092
3
3367.0408
-16
3317.5603
-1
31
32
2385.20496
-1
2514.33686
8
32
33
2437.1645
-21
2384.34801
-1
2514.95055
-3
2462.3362
-19
33
34
2437.8779
-35
2383.48863
-7
2515.5596
16
2461.37706
7
3368.8828
-9
3314.7011
28
34
35
2438.5889
-19
2382.62694
-7
2516.16344
7
2460.41281
-7
3369.48543
-3
3313.7370
11
35
36
2439.29739
22
2381.76284
-6
3370.08230
4
36
37
2440.0026
13
2380.89642
7
2517.35666
4
2458.47066
2
3370.6731
-15
3311.7925
-22
37
38
2380.02728
-4
2517.94599
1
3371.2588
40
3310.8126
19
38
39
2379.15584
4
2518.5306
5
39
40
2442.10128
2
2378.28177
3
2519.11042
5
2455.5228
2
3308.8352
-1
40
41
2377.40527
15
2454.5309
-23
3372.9787
28
41
42
2443.48586
5
2376.5256
-30
2520.25592
5
42
43
2444.17354
0
2375.6437
-41
2520.8214
-23
2452.5346
10
3374.09518
2
3305.8274
-6
43
44
2444.8581
-12
3374.6441
-33
3304.8137
13
44
45
2445.53954
-26
2521.93934
-5
2450.52054
10
45
46
2372.98234
-7
2449.50697
-1
3375.72462
4
46
47
3301.7370
-51
47
48
2447.56564
19
2371.19414
-9
2523.58236
11
2447.4672
-27
3376.7804
48
48
49
2448.23424
7
2524.1213
24
2446.44169
17
3299.6576
-22
49
50
2524.6559
36
2445.4115
-2
50
51
2449.56159
-1
2525.18598
24
2444.37744
-8
51
52
2450.22030
8
2525.71173
-1
2443.33959
2
52
53
2450.87536
-4
2526.23368
11
53
54
2526.75134
4
54
55
2527.26520
22
2440.20280
10
55
56
2452.8202
41
56
57
2438.0932
29
57
58
2454.0980
-2
2528.78256
13
2437.0328
15
58
59
2454.7315
-8
2529.2804
-19
59
60
2529.7750
-5
2434.9019
12
60
61
2433.8314
8
61
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XIII
Observed Line Positions (cm-1) of the 1200–0000, 2000–0000, and 0201–0000 Bands of 14N217Oa
J
1200–0000 Band
2000–0000 Band
0201–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
2525.4796
-19
0
1
2434.9140
13
2526.2812
30
1
2
2438.15652
-5
2434.09892
16
2527.0760
9
2
3
2438.9633
53
2522.2140
-21
3357.2107
-16
3351.5520
6
3
4
2439.76734
17
2432.4635
28
2528.64759
4
3357.9988
-75
4
5
2440.5698
5
2431.64281
1
2529.4240
-18
5
6
2441.37013
-37
2430.8202
-41
2530.1944
-30
2519.7011
11
6
7
2442.1696
19
2530.95914
6
2518.85127
19
3360.3358
-12
3348.2103
10
7
8
2429.1707
-21
2531.71734
-1
2517.99514
4
3361.1055
74
8
9
2443.76139
-25
2532.4692
-29
2517.1329
-16
9
10
2533.21554
4
3345.6519
-47
10
11
2426.6830
4
2533.95534
-6
2515.39074
-7
3363.3809
-42
3344.7900
6
11
12
2446.13542
-33
2425.8502
15
2534.6890
-18
2514.5107
8
3343.9223
-29
12
13
2446.92304
-21
2425.01522
-9
2535.41688
4
2513.6244
-0
13
14
2447.70849
-28
2424.1787
-5
2512.73227
10
3365.6122
-37
14
15
2536.85387
5
3366.3461
-7
3341.2913
33
15
16
2537.56315
-1
3367.0747
3
16
17
2450.0530
-24
2421.65788
-5
2538.26653
14
2510.0193
-16
17
18
2450.8303
-34
2420.8136
-30
2538.96330
-23
2509.10324
-2
3368.5160
-23
3338.6148
3
18
19
2451.6055
-42
2539.65461
3
2508.1812
10
19
20
2507.25309
10
3369.9374
37
3336.8057
1
20
21
2418.2700
-29
3370.6398
24
3335.8943
69
21
22
2417.4181
-42
2505.3791
10
3371.3364
-41
3334.9769
43
22
23
2504.4331
-4
3372.0289
18
3334.0540
-26
23
24
2455.44969
-9
2415.70894
-4
2543.0185
-28
3372.7153
4
24
25
2543.67351
4
2502.5235
-29
3373.3965
13
3332.1947
25
25
26
2413.9915
18
2501.5602
-12
26
27
2413.12946
8
2544.96487
9
2500.5912
18
27
28
2458.4839
-4
2412.2651
-23
2499.61592
1
28
29
2459.2365
-2
2411.3996
44
2546.23231
24
2498.63497
-3
29
30
2459.9864
-21
2546.85675
1
30
31
2460.7343
0
2409.66059
27
2547.47542
-4
2496.65581
-6
31
32
2461.4793
-13
32
33
2462.2220
0
2407.91277
12
2548.6952
16
2494.6536
-30
3378.6423
-63
33
34
2407.03574
30
2493.6442
-3
3379.2720
-36
34
35
2463.6998
45
2406.1557
-24
35
36
2464.4345
44
2405.2742
7
2550.4798
-30
2491.6081
-0
36
37
2465.1665
42
2404.3905
51
2551.06334
-3
2490.5815
-6
37
38
2465.8948
-58
2551.64084
4
2489.5493
-21
38
39
2402.6147
12
2552.21229
-12
2488.5123
44
39
40
2467.3453
-39
2552.7784
18
2487.46872
4
40
41
2553.3384
15
2486.41992
-7
41
42
2399.9336
30
2553.8927
17
2485.36574
-9
42
43
2469.5003
35
2399.0343
-30
2554.4410
-8
2484.3060
-22
43
44
2470.2124
13
2554.98386
-7
2483.2410
-19
44
45
2482.17074
-5
45
46
2471.6283
21
2556.05254
-8
2481.09504
1
46
47
2472.3319
36
47
48
2473.0321
11
2557.0989
6
2478.92764
1
48
49
49
50
2558.1229
8
2476.7390
-26
50
51
2558.62654
-2
51
O - C are the observed minus the computed frequencies in cm-1 × 105.
Table XIV
Observed Line Positions (cm-1) of the 0441–0440, 0441–0330, 1530–0330, 2330–0330, 0531–0330, and 1331–0330 Bands of 14N216Oa
Line
Band
Position
O – C
Line
Band
Position
O – C
Line
Band
Position
O – C
R 6
0441–0440
2173.1653
-5
R22
2330–0330
2615.3896
-8
P13
0531–0330
3290.8065
7
R 8
0441–0440
2174.4379
-10
R23
2330–0330
2616.0861
77
P15
0531–0330
3288.9790
-10
R18
0441–0440
2182.2026
29
R24
2330–0330
2616.7748
-4
P18
0531–0330
3286.1979
-26
P11
0441–0440
2157.82565
18
R26
2330–0330
2618.1361
23
P19
0531–0330
3285.2605
-4
P12
0441–0440
2156.9108
-15
R27
2330–0330
2618.8072
-5
P20
0531–0330
3284.3169
-72
P13
0441–0440
2155.9899
2
R28
2330–0330
2619.4723
-27
P21
0531–0330
3283.3689
-50
P15
0441–0440
2154.1278
-27
R29
2330–0330
2620.1318
-2
P22
0531–0330
3282.4157
-17
P16
0441–0440
2153.1871
-23
R31
2330–0330
2621.4323
13
P23
0531–0330
3281.4569
-16
P17
0441–0440
2152.23999
-7
R32
2330–0330
2622.0732
-6
P24
0531–0330
3280.4929
-6
P20
0441–0440
2149.3592
13
R34
2330–0330
2623.3373
-1
P25
0531–0330
3279.5237
11
P21
0441–0440
2148.3856
-14
R35
2330–0330
2623.9603
4
P26
0531–0330
3278.5486
-36
P23
0441–0440
2146.4198
17
R37
2330–0330
2625.1881
3
P27
0531–0330
3277.5694
32
P27
0441–0440
2142.4100
2
R38
2330–0330
2625.7928
-12
P28
0531–0330
3276.5844
43
P29
0441–0440
2140.3662
-16
R40
2330–0330
2626.9845
-5
P30
0531–0330
3274.5986
49
P31
0441–0440
2138.2965
5
R41
2330–0330
2627.5713
-3
P31
0531–0330
3273.5981
69
R 8
0441–0330
2765.4281
93
R43
2330–0330
2628.7266
-25
P32
0531–0330
3272.5921
52
P17
0441–0330
2741.7422
-49
R44
2330–0330
2629.2955
-10
P34
0531–0330
3270.5652
58
P19
0441–0330
2739.869
149
R46
2330–0330
2630.4154
30
P35
0531–0330
3269.5425
-109
P22
0441–0330
2737.012
-132
R48
2330–0330
2631.5105
-12
P36
0531–0330
3268.5158
-180
P24
0441–0330
2735.0836
47
R50
2330–0330
2632.5821
-11
R 6
1331–0330
3461.1737
57
P25
0441–0330
2734.1100
14
P 4
2330–0330
2594.3115
-12
R 7
1331–0330
3461.9366
51
Q12
0441–0330
2756.363
4
P 7
2330–0330
2591.6969
-19
R11
1331–0330
3464.8897
-8
Q16
0441–0330
2756.0415
6
P10
2330–0330
2589.0284
-0
R12
1331–0330
3465.6036
-6
Q17
0441–0330
2755.9467
-44
P12
2330–0330
2587.2191
-18
R14
1331–0330
3467.00206
11
Q18
0441–0330
2755.84786
54
P14
2330–0330
2585.3865
28
R18
1331–0330
3469.68061
-1
Q20
0441–0330
2755.6310
-20
P15
2330–0330
2584.4606
-13
R21
1331–0330
3471.58636
-4
Q24
0441–0330
2755.134
14
P18
2330–0330
2581.6484
-10
R22
1331–0330
3472.2021
10
Q25
0441–0330
2754.9959
-9
P26
2330–0330
2573.8884
-9
R24
1331–0330
3473.4036
-8
R 5
1530–0330
2455.7065
-1
P29
2330–0330
2570.8812
-22
R25
1331–0330
3473.9898
3
R 8
1530–0330
2458.1744
-11
P31
2330–0330
2568.8474
-11
R27
1331–0330
3475.13265
21
R 9
1530–0330
2458.99248
0
Q 3
2330–0330
2597.6771
23
R28
1331–0330
3475.6892
18
R10
1530–0330
2459.8086
50
Q 4
2330–0330
2597.6523
-34
R29
1331–0330
3476.2359
14
R12
1530–0330
2461.43219
-11
Q 5
2330–0330
2597.6222
-16
R30
1331–0330
3476.77295
29
R14
1530–0330
2463.0472
12
Q 6
2330–0330
2597.5862
17
R31
1331–0330
3477.2999
17
R18
1530–0330
2466.2479
-42
Q 8
2330–0330
2597.4946
-63
R32
1331–0330
3477.8173
35
R28
1530–0330
2474.0850
-33
Q11
2330–0330
2597.3143
59
R33
1331–0330
3478.3240
-33
R32
1530–0330
2477.1524
-56
Q12
2330–0330
2597.2415
36
R35
1331–0330
3479.30972
14
P 5
1530–0330
2446.4771
-48
Q18
2330–0330
2596.6799
67
R36
1331–0330
3479.7878
36
P 7
1530–0330
2444.7690
-52
R 3
0531–0330
3305.4741
18
R37
1331–0330
3480.2553
-16
P 8
1530–0330
2443.9121
4
R 4
0531–0330
3306.2879
-39
R38
1331–0330
3480.7138
16
P 9
1530–0330
2443.0525
19
R 5
0531–0330
3307.098
76
R40
1331–0330
3481.6017
122
P10
1530–0330
2442.1904
12
R 6
0531–0330
3307.9012
41
P 5
1331–0330
3451.2531
-45
P11
1530–0330
2441.3262
23
R 8
0531–0330
3309.4917
7
P 6
1331–0330
3450.36311
-24
P12
1530–0330
2440.4594
0
R10
0531–0330
3311.0609
10
P 7
1331–0330
3449.4633
-9
P20
1530–0330
2433.446
0
R11
0531–0330
3311.8370
-24
P 8
1331–0330
3448.5535
-18
P21
1530–0330
2432.5591
-14
R12
0531–0330
3312.6080
-25
P 9
1331–0330
3447.63432
11
P26
1530–0330
2428.0924
-31
R16
0531–0330
3315.637
-88
P12
1331–0330
3444.8172
-18
P27
1530–0330
2427.1928
-4
R17
0531–0330
3316.381
-147
P17
1331–0330
3439.92835
17
P33
1530–0330
2421.7481
22
R18
0531–0330
3317.1192
-80
P19
1331–0330
3437.90449
-8
P35
1530–0330
2419.9154
-9
R19
0531–0330
3317.8526
-28
P21
1331–0330
3435.8419
-33
R 3
2330–0330
2601.0177
-32
R20
0531–0330
3318.5810
70
P22
1331–0330
3434.79652
-3
R 4
2330–0330
2601.8291
3
R21
0531–0330
3319.3027
44
P24
1331–0330
3432.67642
22
R 6
2330–0330
2603.4330
1
R24
0531–0330
3321.4352
-19
P25
1331–0330
3431.6016
5
R 8
2330–0330
2605.0126
-3
R25
0531–0330
3322.1349
-62
P26
1331–0330
3430.5177
44
R 9
2330–0330
2605.7930
-35
R27
0531–0330
3323.5205
103
P29
1331–0330
3427.2056
-101
R10
2330–0330
2606.5679
-9
R28
0531–0330
3324.2037
40
P30
1331–0330
3426.0837
-13
R12
2330–0330
2608.0995
-46
R35
0531–0330
3328.8403
-6
P31
1331–0330
3424.9512
-25
R14
2330–0330
2609.6055
-28
R37
0531–0330
3330.1192
84
P38
1331–0330
3416.7560
-56
R15
2330–0330
2610.3499
-14
P 6
0531–0330
3297.0345
67
P39
1331–0330
3415.54721
-43
R16
2330–0330
2611.0882
-2
P 7
0531–0330
3296.1603
4
P42
1331–0330
3411.8632
-56
R17
2330–0330
2611.8202
-12
P10
0531–0330
3293.5080
59
P45
1331–0330
3408.0941
-24
R19
2330–0330
2613.2660
-29
P11
0531–0330
3292.6127
28
R21
2330–0330
2614.6879
-6
P12
0531–0330
3291.7122
10
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XV
Observed Line Positions (cm-1) of the 1001–0000, 1001–1000 and 1001–0110 Bands of N216Oa
J
1001–0000 Band
1001–1000 Band
1001–0110 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q–Branch
O – C
0
3481.64677
-0
2196.74345
2
0
1
3479.98123
5
2195.08145
10
2893.6958
11
1
2
3483.27055
1
3479.13275
4
2198.37777
3
2194.23990
-1
2894.50181
14
2892.01404
-23
2
3
3484.06677
3
3478.27385
5
2199.18445
-2
2193.39157
4
2895.29704
17
3
4
3484.85249
2
3477.40451
6
2199.98423
-1
2192.53624
1
2896.08125
-1
2891.92763
-2
4
5
3485.62771
-2
3476.52471
4
2200.77705
-1
2191.67395
-5
2896.85472
-13
2887.75173
-7
2891.86597
16
5
6
3486.39251
0
3475.63450
4
2201.56288
-3
2190.80488
2
2897.61762
-1
2886.8598
21
2891.79159
-2
6
7
3487.14682
1
3474.73388
5
2202.34183
4
2189.92877
-4
2898.36964
4
2885.95676
14
2891.70524
20
7
8
3473.82282
4
2203.11367
-3
2189.04585
1
2899.11074
-2
2885.04298
8
2891.60608
-3
8
9
3488.62396
-2
3472.90135
4
2203.87867
4
2188.15594
-3
2899.84104
-7
2884.11839
-5
2891.49481
-1
9
10
3489.34681
-3
3471.96944
-0
2187.25919
-1
2900.56061
-2
2883.18322
-2
2891.37118
2
10
11
3490.05920
0
3471.02715
-1
2205.38756
-0
2186.35551
-2
2882.23721
-9
2891.23509
-6
11
12
3490.76105
-2
3470.07447
-1
2206.13152
-3
2185.44495
-1
2901.96722
1
2881.28057
-5
12
13
3491.45242
-2
3469.11138
-3
2206.86852
-2
2184.52750
-1
2902.65416
-10
2880.31324
0
2890.9257
-36
13
14
3492.13329
-2
3468.13796
1
2207.59852
-1
2183.60316
-2
2903.33042
-6
2879.33512
-1
2890.75304
6
14
15
3492.80364
-4
3467.15407
-4
2208.32155
2
2903.99572
-16
2890.5674
-15
15
16
3493.46351
-3
3466.15983
-6
2209.03751
-1
2181.73376
-11
2904.65034
-9
2877.3467
-8
2890.36981
3
16
17
3494.11294
4
3465.15526
-4
2209.74650
-1
2180.78870
-4
2905.29412
-4
2876.3365
-6
2890.1595
-16
17
18
3464.14028
-6
2210.44850
2
2179.83704
-4
2905.92692
-13
2875.31557
-7
2889.93716
-3
18
19
3495.38005
-2
3463.11500
-2
2211.14343
-1
2178.87833
-5
2906.54896
-14
2874.28413
9
19
20
3495.99785
-5
3462.07928
-7
2211.83133
-5
2177.91274
-9
2907.16022
-9
2873.24167
-10
2889.45515
-11
20
21
3496.60521
1
3461.03329
-4
2212.51225
-4
2176.94035
-8
2907.76071
3
2872.18872
-10
2889.19571
-8
21
22
3459.97691
-6
2213.18620
2
2175.96111
-6
2908.35015
-7
2871.12501
-20
2888.92399
-0
22
23
3497.78823
-1
3458.91025
-3
2213.85307
3
2174.97512
5
2908.9288
-11
2870.05089
-6
2888.63978
-10
23
24
3498.36400
2
3457.83322
-4
2214.51290
4
2173.98219
6
2909.49674
-2
2868.96586
-17
2888.34337
-6
24
25
*3498.92928
8
3456.74590
-1
*2215.16560
-5
2172.98240
5
*2910.05380
3
2867.8703
-18
2888.03460
-8
25
26
*3499.48408
19
3455.64825
0
*2215.81162
23
2171.97585
11
*2910.60019
25
2866.76440
10
*2887.71369
7
26
27
*3500.02968
162
*3454.54036
8
*2216.45175
166
*2170.96235
4
*2911.13693
166
*2865.64729
-20
*2887.38026
1
27
28
*3500.56140
-30
*3453.42219
18
*2217.08147
-26
*2169.9423
25
*2911.65942
-34
*2887.03619
161
28
29
*3501.08469
-12
*3452.29511
166
*2217.70636
3
*2168.91666
169
*2912.17335
-3
*2886.6763
-31
29
30
3501.59735
-4
*3451.15429
-31
2218.32383
-4
*2167.88090
-18
2912.67622
1
*2886.3060
-35
30
31
3502.09948
4
*3450.00540
-7
2218.93440
6
*2166.84033
-5
2913.1681
2
2885.92365
-16
31
32
3502.59098
2
3448.84602
-5
2219.53784
8
2165.79285
-2
2913.64937
6
2859.90427
-15
2885.52895
-5
32
33
3503.07208
13
3447.67642
1
2220.13422
12
2164.73862
6
2914.11972
11
2858.72399
-7
2885.12194
3
33
34
*3503.54265
24
3446.49658
9
*2220.72346
8
2163.67756
10
*2914.57914
7
2857.53322
7
2884.7026
5
34
35
*3504.00265
30
3445.30645
12
*2221.30575
17
2162.60972
15
2856.33172
4
*2884.27100
6
35
36
*3504.45213
38
*3444.10613
20
*2221.88088
17
*2161.53515
26
*2915.46606
56
*2855.12000
32
*2883.82741
33
36
37
*3504.89110
48
*3442.89555
26
*2222.44922
47
*2160.45361
18
*2915.8925
3
*2853.89730
16
*2883.37137
40
37
38
*3505.31960
63
*3441.67485
41
*2223.01037
66
*2159.36545
26
*2916.3091
48
*2852.66451
41
*2882.9035
87
38
39
*3505.73759
81
*3440.44388
50
*2223.5640
41
*2158.27072
54
*2916.7150
105
*2851.4211
56
*2882.4231
105
39
40
*3506.14516
109
*3439.20274
63
*2224.11145
108
*2157.1690
60
*2917.1095
104
*2850.1670
51
40
41
*3506.54224
140
*3437.95142
77
*2224.65150
144
*2156.06066
79
*2917.4932
105
*2848.9026
64
41
42
*3506.92911
203
*3436.69022
122
*2225.18466
201
*2154.94570
113
*2917.8664
137
*2847.6275
55
*2880.90851
146
42
43
*3507.30598
318
*3435.41868
150
*2225.71158
344
*2153.82399
147
*2918.2300
289
*2846.3429
141
*2880.3793
164
43
44
*3507.67522
721
*3434.13726
206
*2226.23378
725
*2152.69580
207
*2918.5851
671
*2879.8393
323
44
45
*3507.99683
-2586
*3432.84628
321
*2226.71210
-2572
*2151.56147
328
*2918.8926
-2612
*2843.7425
326
*2879.2902
788
45
46
*3508.36177
-510
*3431.54803
724
*2150.42309
717
*2919.2425
-595
*2842.4303
783
46
47
*3508.69782
-271
*3430.20249
-2589
*2149.24121
-2570
47
48
*3509.02178
-190
*3428.90075
-510
*2228.22690
-211
*2148.10636
-482
*2839.7527
-504
48
49
*3509.33503
-130
*3427.57060
-261
*2146.94583
-289
49
50
*3509.63750
-98
*3426.22864
-184
*2145.77773
-182
50
51
*3509.92929
-84
*2144.60210
-157
*2835.6815
-132
51
52
*3510.21067
-62
*3423.51372
-104
*2230.11758
-3
52
53
*3510.48142
-55
*3422.14100
-81
*2142.23139
-40
53
54
*3510.74175
-41
*3420.75817
-63
*2231.0192
4
*2141.03545
-36
54
55
*3510.99156
-32
*2231.45900
-24
*2139.83280
-33
55
56
*3511.23095
-17
*3417.96247
-24
*2231.89214
-4
56
57
*3511.45972
-18
*3416.54946
-19
*2232.31787
-12
*2137.40750
-24
57
58
3511.67817
-5
*3415.12642
-17
2232.73674
8
58
59
3511.88606
-3
*3413.69339
-16
*2134.95547
-18
59
60
3412.25050
-6
2233.55268
11
2133.71965
4
60
61
3512.27058
7
3410.79759
-2
61
62
3512.44703
-4
3409.33485
11
2234.33998
7
62
63
3512.6134
19
3407.86192
-2
63
64
3512.6898
4
3406.37924
-1
2128.70891
-5
64
65
3512.91438
11
3404.88670
2
2127.43985
15
654
66
3513.04927
6
66
67
3513.17377
1
3401.87195
-0
67
68
3513.28797
2
68
69
3513.39182
4
3398.81787
-5
2122.29670
23
69
70
3513.48520
-5
3397.27612
-8
2120.99420
6
70
71
3513.56850
10
2119.68526
4
71
72.
3513.64120
-5
3394.16342
-6
72
73
3513.7034
-33
73
74
3513.7554
-54
3391.01159
-25
74
75
3513.7973
-67
75
76
3513.8290
-54
3387.8211
-38
76
77
3513.8511
15
77
78
3384.5922
-31
78
82
3513.8050
14
82
83
3376.3531
55
83
84
3513.7149
-37
84
O – C are the observed minus the computed frequencies in cm-1 × 105. The transitions denoted with asterisks are perturbed and were not included in the frequency analysis.
Table XVI
Observed Line Positions (cm-1) of the 1001–0000 Bands of 14N15N16O and 15N14N16Oa
J
14N15N16O
15N14N16O
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
3433.0205
-17
3444.4494
-34
0
1
3433.8383
43
1
2
3442.0202
-40
2
3
3446.78929
4
3
4
3436.22717
3
3447.5491
-5
3440.3515
7
4
5
3437.00287
10
3427.89945
-12
3448.29925
18
3439.50184
-9
5
6
3427.0100
22
3449.0390
-2
3438.64237
-12
6
7
3438.52270
-11
3426.10968
4
3449.76908
9
7
8
3439.26714
-8
3450.48905
7
3436.89394
10
8
9
3440.00132
11
3424.2781
-25
3451.19910
12
3436.00472
9
9
10
3440.7248
1
3423.3471
-3
3451.89923
23
3435.10555
4
10
11
3441.43785
-9
3422.40566
4
*3452.5894
37
11
12
3442.14070
4
3421.45377
-1
*3453.26940
33
3433.27766
12
12
13
3442.83280
-15
*3453.93962
51
*3432.34895
24
13
14
3443.5146
-21
3419.5197
57
*3454.59975
59
*3431.41045
47
14
15
3444.18626
3
3418.53637
5
*3455.24995
73
*3430.46190
53
15
16
3444.84715
-7
3417.54322
1
*3455.89032
104
*3429.50377
89
16
17
3445.4976
-15
3416.53977
-2
*3428.53541
90
17
18
3446.13796
13
3415.52605
-2
*3457.14078
138
18
19
3446.76750
3
3414.50200
-5
*3457.75141
195
*3426.56955
136
19
20
3447.38676
11
3413.46765
-8
*3458.35175
223
*3425.57186
162
20
21
3447.9955
13
3412.42316
3
*3458.94277
319
*3424.5642
176
21
22
3448.59352
-10
3411.3684
15
*3459.5245
486
*3423.54726
245
22
23
3410.30308
-2
*3460.10231
1262
*3422.52052
318
23
24
3449.7586
-14
3409.22762
-5
*3460.63377
-1597
*3421.48506
501
24
25
3450.3252
-39
3408.14192
-5
*3461.1949
-489
*3420.44553
1259
25
26
3450.8820
4
*3461.73736
-248
26
27
3451.42775
-11
3405.9399
11
*3462.2682
-169
*3418.30445
-486
27
28
3451.96324
-3
3404.82330
-3
*3462.7885
-143
*3417.23015
-264
28
29
3452.48803
-17
3403.69644
-17
*3463.29931
-67
*3416.1444
-209
29
30
3453.00274
10
3402.5596
-6
*3463.79938
-64
*3415.04890
-152
30
31
3453.5068
23
3401.41235
-12
*3464.28975
-32
*3413.9436
-97
31
32
3453.99990
-15
3400.25505
-1
*3464.76984
-28
*3412.82853
-43
32
33
3454.48308
7
3465.24012
-5
*3411.70311
-49
33
34
3454.95556
8
3397.90935
-21
34
35
3455.4178
36
3396.72139
-10
3409.42331
-36
35
36
3395.52310
-11
3466.59040
4
36
37
3456.30985
-1
3394.31473
-0
3467.02052
8
3407.10480
-3
37
38
3393.0960
-6
3467.44072
19
38
39
3391.86735
15
3467.8509
27
3404.7472
4
39
40
3390.62803
-12
3468.25081
6
3403.55377
-3
40
41
3457.96875
18
3389.37881
-12
3402.3508
5
41
42
3388.11958
4
3401.13805
1
42
43
3386.85012
13
3469.39125
2
3399.91576
9
43
44
3459.10225
7
3385.57035
7
3469.7514
-4
3398.68385
20
44
45
3384.28052
10
3470.1015
-17
3397.44207
8
45
46
3382.98065
24
46
47
*3460.1412
11
3470.7720
-24
3394.9295
-30
47
48
*3460.4675
115
3380.35033
33
3471.0926
2
48
49
*3460.78215
108
3392.3792
1
49
50
*3461.0865
123
*3377.6794
31
3471.7029
-48
3391.0894
-10
50
51
*3461.3766
-234
*3376.3294
93
3389.79026
3
51
52
*3461.6617
-37
*3374.9687
95
3388.4814
-0
52
53
*3373.5943
-263
3387.16296
-6
53
54
3462.1968
5
*3372.2151
-93
3385.8350
-9
54
55
3473.0562
-6
3384.4978
16
55
56
3369.4242
20
3383.1510
34
56
57
3368.0124
-48
3381.7945
32
57
58
3473.7489
15
58
59
3463.3491
0
59
60
3463.5478
-17
3363.7199
67
3474.1611
31
3377.6682
40
60
61
3474.3518
-14
61
62
3360.8058
-83
3374.8696
5
62
63
3464.0822
82
3359.3354
9
63
64
3357.8541
12
64
65
3356.3622
-46
3370.6013
-11
65
O – C are the observed minus the computed frequencies in cm-1 × 105. Transitions denoted with asterisks are perturbed and were not included in the analysis.
Table XVII
Observed Line Positions (cm-1) of the 1001–0000 Bands of 14N218O and 14N217Oa
J
14N218O
14N217O
J
R Branch
O –C
P Branch
O –C
R Branch
O –C
P Branch
O –C
2
3437.29316
6
3433.38455
5
3459.01650
-15
2
3
3432.57432
-17
3459.7904
22
3
4
3438.79049
1
3453.3231
-20
4
5
3439.52498
-2
3430.92620
-3
3461.3072
-14
3452.4701
-11
5
6
3451.6068
-38
6
7
3440.96566
-3
3450.7337
-54
7
8
3428.38320
-7
3463.5084
9
8
9
3442.36845
-12
3427.51679
-3
3464.2224
38
3448.9588
20
9
10
3443.05598
15
3426.64100
1
3464.92565
-10
3448.0567
78
10
11
3443.7339
27
3425.75580
3
3447.14330
-4
11
12
3444.40195
-2
3424.86110
-8
3446.22095
8
12
13
3445.06095
9
3423.95713
-9
3466.9770
-5
13
14
3445.71035
7
3423.04403
14
3467.6409
5
3444.3464
14
14
15
3422.12120
-2
3468.2947
4
15
16
3421.18923
4
3468.9385
2
3442.4323
15
16
17
3447.60184
2
3420.24794
12
3441.4602
-9
17
18
3448.21359
18
3419.29712
0
3470.1965
33
3440.4787
12
18
19
3448.81575
19
3418.33715
6
3470.81005
3
3439.4875
47
19
20
3449.40827
3
3417.36774
-1
3438.4858
17
20
21
3416.38905
-5
3437.47453
14
21
22
3450.5653
3
3436.45330
-4
22
23
3414.4037
-22
3473.1652
-35
23
24
3451.68428
-22
3413.39730
-11
3473.7295
5
3434.3819
13
24
25
3412.3815
-12
3474.2835
13
25
26
3452.7659
-6
3474.82715
-15
3432.2705
-49
26
27
3453.2922
-33
3410.32220
-9
3475.3613
7
27
28
3453.80982
15
3409.27885
9
3475.88504
-14
3430.1205
-57
28
29
3454.31735
-4
3408.22588
-12
3476.3992
5
3429.0313
-15
29
30
3454.81563
-5
3407.16399
-4
3476.9032
8
3427.9323
23
30
31
3455.30492
36
3406.09290
4
31
32
3405.01260
11
32
33
3478.3552
5
3424.5750
-46
33
34
3456.7149
17
3402.82415
-9
3423.4370
-14
34
35
3479.2733
4
3422.2891
1
35
36
3457.6075
-37
3400.59931
-7
3479.7176
25
3421.13115
-19
36
37
3458.0404
4
37
38
3458.46340
-9
3398.33781
-21
3480.5753
-31
38
39
3397.1938
10
3480.9899
12
3417.6000
4
39
40
3459.2815
-15
3396.04023
-6
*3481.3943
32
40
41
3459.67666
-5
3394.8776
-22
3415.1975
14
41
42
3460.0624
-3
3393.7068
52
*3482.1730
52
42
43
3460.4390
18
3392.5260
25
*3482.5495
271
43
44
*3482.9165
536
*3411.5222
106
44
45
3390.1384
78
45
46
*3483.6066
-336
*3409.0285
626
46
47
*3461.8613
997
*3387.7146
102
*3407.7532
-519
47
48
*3462.1758
-545
*3386.49003
189
*3484.2687
-27
48
49
*3385.26385
1007
*3405.2012
-76
49
50
*3384.0055
-502
50
51
*3382.75633
-204
3485.1834
51
51
52
*3381.4960
-137
3485.4671
-55
52
53
*3380.2266
-92
53
54
3398.6438
9
54
56
3376.3647
-49
56
57
3375.0603
8
57
58
3373.7468
27
58
60
3371.0940
92
60
62
3465.8356
55
62
O – C are the observed minus the computed frequencies in cm-1 × 105. Transitions denoted with asterisks are perturbed and were not included in the analysis.
Table XVIII
Observed Line Positions (cm-1) of the 1111–0110 and 1111–0000 Bands of N216Oa
J
1111(e)–0110(e) Band
1111(f)–0110(f)Band
1111–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
4062.0763
-12
0
1
3474.8575
-17
3474.8614
5
4063.62589
-4
1
2
3475.6650
-25
3471.525
23
3475.6710
-7
3471.522
26
2
3
3476.4620
5
3470.666
8
3476.471
30
3470.6619
22
4065.23243
-5
4059.43584
-0
3
4
3477.2497
11
3469.797
18
3477.2604
16
3469.7916
5
4
5
3478.0264
5
3468.917
-49
3478.03965
-5
3468.9115
12
4066.79921
-7
5
6
3468.0277
-22
3478.80900
-7
3468.0212
5
4067.56778
1
6
7
3479.54913
10
3467.1282
8
3479.56840
6
3467.1211
21
4068.32621
-9
7
8
3480.29503
8
3466.2184
29
3480.31752
1
3466.2106
1
4069.07470
-18
8
9
3481.03058
1
3465.2976
-27
3481.05662
4
3465.2905
25
4069.81345
-5
4054.08068
-12
9
10
3481.75589
-2
3464.3674
-2
3481.78554
-1
3464.3594
-50
4070.54213
-3
10
11
3463.4269
14
3482.50449
7
3463.4196
8
4071.26087
1
4061.44152
-3
11
12
3483.17570
2
3462.4758
-10
3483.21322
4
3462.4692
7
4071.96961
2
4061.34357
-18
12
13
3483.87012
0
3461.5149
5
3483.91177
-6
3461.5089
16
4050.31284
-24
13
14
3484.55423
-2
3460.5438
20
3484.60037
-0
3460.539
65
4073.35706
-7
4049.34642
-6
4061.12372
-0
14
15
3485.22803
-5
3459.5623
14
3485.27869
-11
3459.558
3
4074.03591
-3
4048.3697
-32
15
16
3485.89155
-4
3458.570
-55
3485.94717
5
3458.568
40
4074.70470
-5
4047.3834
-31
16
17
3486.54476
-4
3457.5688
4
3486.60537
4
3457.567
-26
4075.36354
-5
4046.38750
-6
4060.73260
-5
17
18
3487.18768
-1
3456.5569
10
3487.25345
2
3456.5569
-4
4076.01246
2
4045.38149
-7
4060.58601
-1
18
19
3487.82027
0
3455.5347
2
3455.537
33
4076.65127
-3
4044.36558
-14
19
20
3488.44246
-7
3454.5022
-21
3488.51932
3
3454.506
-44
4077.28012
-4
4043.34002
-3
4060.2682
-17
20
21
3489.05441
-5
3453.4600
1
3489.13704
-1
3453.466
-27
4077.89898
-5
4042.30454
-2
4060.09745
9
21
22
3489.65611
3
3452.4074
-3
3489.74467
-2
3452.416
-16
4078.50787
-3
4041.25930
6
4059.91840
17
22
23
3490.24736
-2
3451.3447
-3
3490.34222
-1
3451.3562
8
4079.10673
-3
4040.20403
-8
4059.73090
-8
23
24
3490.82830
-5
3450.2719
0
3490.92963
-2
3450.2863
13
4079.69554
-8
4039.13916
-1
4059.53572
11
24
25
3491.39895
-4
3449.1889
-5
3491.50696
-1
3449.2064
10
4080.27448
1
4038.06429
-14
25
26
3491.95930
-1
3448.0963
42
3492.07412
-5
3448.11666
12
4080.84329
-3
4036.97898
0
4059.12052
-1
26
27
3492.50930
-0
3446.9933
59
3492.63127
-0
3447.01677
-12
4081.40211
-4
4035.88549
-7
4058.90095
11
27
28
3493.04901
4
3445.87947
3
3493.17826
-1
3445.90736
1
4034.78145
1
4058.67302
-2
28
29
3493.57836
6
3444.75613
5
3493.71518
2
3444.78792
-3
4033.66766
12
4058.43714
0
29
30
3494.0976
29
3443.62259
-4
3494.24195
-1
3443.65877
8
4032.54376
-11
4058.19318
3
30
31
3494.60603
4
3442.47913
2
3442.51944
-14
4031.41018
-25
4057.94112
5
31
32
*3495.10450
17
3441.32558
6
3495.26524
-1
3441.37066
3
*4084.04618
14
4030.26729
6
32
33
*3495.59263
28
3440.1620
13
3495.76183
7
3440.21183
-3
*4084.54504
28
4029.11441
14
4057.41277
10
33
34
*3496.07228
224
*3438.98828
11
*3496.24836
18
3439.0433
3
*4085.03574
229
*4027.95168
11
4057.13647
12
34
35
*3496.53710
-31
*3437.80472
29
*3496.72491
39
3437.86495
8
*4085.51186
-25
4026.77933
20
*4056.8526
64
35
36
*3496.99428
-16
*3436.61295
230
*3497.192
123
*4085.98064
-11
*4025.59914
218
*4056.55996
45
36
37
3497.44113
-2
*3435.4068
-8
*3497.64602
-93
*3435.47912
39
4086.43943
7
*4024.40474
-32
*4056.26105
206
37
38
3497.87750
-3
*3434.1927
-34
*3498.09258
-48
*3434.27300
200
4086.88798
4
*4023.20311
-33
38
39
3498.30354
-5
3432.96915
-7
*3498.52873
-37
*3433.05254
-98
4087.32654
5
4021.99196
-15
*4055.63305
-76
39
40
3498.71935
2
3431.73516
-24
*3498.9545
-58
*3431.82555
-74
4087.75504
3
4020.77093
-15
*4055.30902
-14
40
41
3499.12474
-1
3430.4914
-20
*3499.37077
-23
*3430.58932
-2
4019.54040
5
41
42
3499.51988
3
*3499.7767
-17
*3429.3425
-18
4088.58192
-4
4018.29995
1
*4054.63572
-3
42
43
3499.90465
2
3427.97426
17
3500.17265
-5
*3428.08612
-20
4017.04958
-26
*4054.2867
-31
43
44
3500.27916
6
3426.70042
2
*3426.82013
-14
4015.78996
-11
44
45
3500.64332
5
3425.41687
11
3500.9344
16
3425.54452
-4
4014.52061
-4
45
46
3500.99707
-5
3424.12322
3
*3501.30022
25
3424.25916
-2
4013.2413
-27
46
47
3501.34068
1
3422.81970
-0
*3501.65625
57
3422.96423
6
4011.95266
-18
47
48
3501.67392
-1
3421.50662
31
*3502.0021
71
*3421.65971
18
4010.65442
-6
*4052.0272
75
48
49
3501.99671
-17
3420.18310
9
*3502.33805
97
*3420.34568
39
49
50
3502.30956
1
3418.84972
-12
*3502.66405
126
*3419.02218
73
4008.02884
-6
50
51
3502.61215
23
3417.50686
7
*3502.98002
151
*3417.68892
88
51
52
3502.90398
-4
3416.15381
-7
*3503.2866
235
*3416.34620
114
52
53
3503.18584
-0
3414.79114
1
*3503.58354
352
*3414.99424
169
53
54
3503.45736
-3
3413.41840
-15
*3503.87088
504
*3413.63302
251
54
55
3503.71875
7
3412.03610
-5
*3504.1510
929
*3412.2627
374
55
56
3503.96982
12
*3504.42655
1891
*3410.88304
512
56
57
3504.21065
17
*3504.55976
-10388
57
58
3407.83004
-14
*3504.891
-1873
*3408.10612
1866
58
59
*3504.66168
38
*3505.13539
-1052
*3406.5750
-10308
59
60
*3504.8720
63
3404.97736
-3
*3505.36502
-718
*3405.2402
-1908
60
61
*3505.07245
124
*3403.5364
1
*3505.58310
-551
61
62
*3505.26262
178
62
63
*3505.44401
374
*3505.99184
-343
*3400.94181
-481
63
64
*3505.61777
827
*3399.1588
359
*3399.4860
-438
64
65
*3397.6791
363
*3506.35571
-199
65
66
*3505.8345
-8293
*3396.5474
-260
66
67
*3506.0289
-2724
*3394.70917
2207
3506.6792
-113
*3395.06326
-265
67
68
3506.8283
35
68
69
*3391.629
-3131
3506.9668
99
3392.068
-203
69
70
*3506.3984
-1302
3507.096
207
70
71
*3506.4953
-1430
*3388.5812
-1407
3389.0397
231
71
72
*3506.5849
-1278
*3387.0347
-1375
3387.508
66
72
73
*3506.6611
-1457
3507.4245
457
73
74
3506.7315
-1209
*3383.9134
-1294
3507.5143
509
3384.4244
448
74
75
3506.7820
-1945
3507.5952
637
75
O – C are the observed minus the computed frequencies in cm-1 × 105. Transitions denoted with asterisks are perturbed and were not included in the frequency analysis.
Table XIX
Observed Line Positions (cm-1) of the 0600–0000,0620(e)–0000, 0710–0110, and 0730–0110 Bands of 14N216O and the 0600–0000 Band of 15N14N16Oa
O – C are the observed minus the computed frequencies in cm-1 × 105.
δ is the difference between the observed frequency and the observed position of the transition of the perturbing band Values of δ are given in cm-1.
Table XX
Computed Line Positions (cm-1) of the 0002–0000 and 0002–1000 Bands of 14N216Oa
J
0002–0000 Band
0002–1000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
4418.20195
-1
3133.29861
19
0
1
4419.01232
-1
4416.53973
-3
3134.11249
-13
3131.63990
-0
1
2
4419.80887
-4
4415.68789
-2
3134.91606
-4
3130.79508
-8
2
3
4420.59158
-3
4414.82224
-3
3135.70930
-7
3129.93997
-3
3
4
4421.36045
-3
4413.94278
3136.49222
-5
3129.07455
3
4
5
4422.11547
-2
4413.04951
3137.26480
-1
3128.19884
-2
5
6
4422.85665
-4
4412.14244
3138.02705
-8
3127.31284
-1
6
7
4423.58399
-2
4411.22158
3138.77896
-7
3126.41655
-7
7
8
4424.29746
-2
4410.28693
3139.52052
5
3125.50999
-5
8
9
4424.99708
-1
4409.33849
3140.25173
2
3124.59314
-1
9
10
4425.68283
-0
4408.37626
2
3140.97259
0
3123.66602
-3
10
11
4426.35472
-2
4407.40026
3141.68309
-1
3122.72862
2
11
12
4427.01274
-1
4406.41048
3142.38322
-1
3121.78096
-3
12
13
4427.65689
0
4405.40694
3143.07299
0
3120.82304
2
13
14
4428.28715
-0
4404.38963
3143.75238
2
3119.85485
1
14
15
4428.90354
1
4403.35856
3144.42139
1
3118.87641
-7
15
16
4429.50604
0
4402.31373
-1
3145.08002
-8
3117.88771
2
16
17
4430.09465
-1
4401.25516
3
3145.72826
0
3116.88877
1
17
18
4430.66937
1
4400.18284
1
3146.36610
-9
3115.87957
18
19
4431.23019
1
4399.09677
5
3146.99355
0
3114.86013
1
19
20
4431.77711
1
4397.99697
1
3147.61059
-9
3113.83046
0
20
21
4432.31012
3
4396.88344
3148.21722
-6
3112.79054
1
21
22
4432.82923
2
4395.75619
4
3148.81343
2
3111.74039
-2
22
23
4433.33443
2
4394.61521
3
3149.39923
-4
3110.68000
20
23
24
4433.82572
1
4393.46051
3149.97459
5
3109.60939
5
24
25
4434.30308
3
4392.29210
4
3150.53953
2
3108.52854
0
25
26
4434.76653
2
4391.10998
3
3151.09402
3
3107.43748
-16
26
27
4435.21605
3
4389.91416
7
3151.63808
3
3106.33619
-1
27
28
4435.65164
2
4388.70465
3152.17168
2
3105.22468
28
29
4436.07330
2
4387.48144
3152.69482
10
3104.10296
8
29
30
4436.48103
0
4386.24454
5
3153.20750
11
3102.97102
30
31
4436.87481
-0
4384.99397
3153.70972
6
3101.82887
4
31
32
4437.25466
2
4383.72971
3154.20145
9
3100.67651
-11
32
33
4437.62056
1
4382.45178
2
3154.68271
11
3099.51394
33
34
4437.97251
1
4381.16019
3155.15348
9
3098.34116
-9
34
35
4438.31051
1
4379.85494
3155.61375
5
3097.15817
7
35
36
4438.63456
1
4378.53602
2
3156.06352
-16
3095.96498
36
37
4438.94465
0
4377.20346
3156.50278
3094.76158
-15
37
38
4439.24078
-3
4375.85725
3156.93152
6
3093.54800
0
38
39
4439.52294
0
4374.49740
3157.34974
10
3092.32421
9
39
40
4439.79114
-4
4373.12392
3
3157.75743
6
3091.09021
10
40
41
4440.04536
-4
4371.73680
3158.15458
-11
3089.84602
18
41
42
4440.28562
0
4370.33607
-7
3158.54118
-15
3088.59163
17
42
43
4440.51189
-8
4368.92171
-4
3158.91723
3087.32705
15
43
44
4440.72419
-0
4367.49374
-6
3159.28272
3086.05226
44
45
4440.92251
-5
4366.05216
0
3159.63763
3084.76728
45
46
4441.10681
-10
4364.59697
3159.98196
3083.47210
46
47
4441.27718
7
4363.12819
3160.31571
3082.16672
47
48
4441.43353
4361.64582
-1
3160.63886
3080.85115
48
49
4441.57589
4360.14987
3160.95140
3079.52537
49
50
4441.70425
-21
4358.64033
3161.25333
3078.18940
50
51
4441.81862
4357.11722
0
3161.54463
3076.84323
51
52
4441.91898
4355.58053
3161.82529
3075.48685
52
53
4442.00533
4354.03029
3162.09531
3074.12027
53
54
4442.07768
4352.46649
-4
3162.35468
3072.74349
54
55
4442.13602
4350.88913
-3
3162.60338
3071.35649
55
56
4442.18034
4349.29823
17
3162.84140
3069.95929
56
57
4442.21065
4347.69379
3163.06874
3068.55188
57
58
4442.22694
4346.07581
3163.28538
58
59
4442.22921
4344.44430
59
60
4442.21745
4342.79927
-10
60
61
4442.19167
4341.14073
61
62
4442.15186
4339.46867
33
62
63
4442.09802
4337.78311
63
64
4442.03015
4336.08404
17
64
65
4441.94824
4334.37149
65
66
4441.85229
4332.64544
66
67
4441.74230
4330.90592
67
68
4441.61826
4329.15292
-23
68
69
4441.48018
4327.38645
69
70
4441.32805
4325.60651
70
71
4441.16187
4323.81312
71
72
4440.98163
4322.00628
72
73
4440.78735
4320.18599
73
74
4440.57900
4318.35226
74
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XXI
Computed Line Positions (cm-1) of the 1201–0000 and 1201–0200 Bands of N216Oa
O – C are the observed minus the computed frequencies in cm−1 × 105. Transitions denoted by asterisks are perturbed and measured frequencies of these were not included in the analysis.
From Ref. 10. Values given within parentheses are their quoted uncertainties (in the last digits) in the computed values.
Tables (21)
Table I
N2O Effective Vibration–Rotation Constants (cm−1)
Mol
State
G
B
D × 107
H × 1013
L × 1018
446
0000
0.0
0.419011001
1.7609193
−0.16529
446
0110(e)
588.76787(1)
0.419177925
1.783245
−0.1714
446
0110(f)
588.76787(1)
0.419969845
1.793030
−0.1766
446
0200
1168.13230(1)
0.419920952
2.491945
29.55393
446
0220(e)
1177.74467(2)
0.420125256
1.196792
−29.50211
−26.334
446
0220(f)
1177.74467(2)
0.420126260
1.18180
0.95
−10.5
446
1000
1284.90334(1)
0.417255210
1.726978
1.4666
1.8527
446
0310(e)
1749.06523(2)
0.419583944
2.110353
12.22476
−21.9783
446
0310(f)
1749.06515(2)
0.421079073
2.177366
−3.59205
19.5374
446
0330(e)
1766.91238(3)
0.420667053
1.617863
−9.91321
446
0330(f)
1766.91224(7)
0.420671366
1.683740
30.15376
446
1110(e)
1880.26574(1)
0.417464677
1.748503
1.07495
446
1110(f)
1880.26574(1)
0.418372995
1.719561
2.17460
446
0001
2223.756765(7)
0.415559510
1.754675
−0.13626
446
0400
2322.57308(3)
0.420618918
3.964712
140.2855
206.3572
446
0420(e)
2331.12151(3)
0.420768064
0.173512
−142.9273
−150.3509
446
0420(f)
2331.12145(3)
0.420772247
2.161040
4.83973
9.7651
446
0440(e/f)
2356.25242(50)
0.42121862
2.7201
1712.2
−85099.
446
1200
2461.99644(2)
0.418147866
2.430198
25.90692
−16.2308
446
1220(e)
2474.79870(2)
0.418530437
1.206247
−26.98080
−5.6483
446
1220(f)
2474.79865(4)
0.418531597
1.755149
2.44107
−7.3245
446
2000
2563.33944(1)
0.415605503
1.637508
5.68544
9.7329
446
0111(e)
2798.29260(2)
0.415770899
1.775781
−0.11162
446
0111(f)
2798.29260(2)
0.416547926
1.787226
−0.15579
446
0510(e)
2897.81356(2)
0.419861132
2.607442
46.2217
−74.25
446
0510(f)
2897.81339(5)
0.422038393
2.743442
−21.9700
85.76
446
0530(e)
2914.04341(30)
0.421221015
1.440529
−111.308
446
0530(f)
2914.04344(30)
0.421234739
1.802792
167.403
446
1310(e)
3046.21287(3)
0.417758699
2.093227
11.87123
−30.0705
446
1310(f)
3046.21287(3)
0.419376209
2.142852
−2.05374
35.1844
446
1330(e)
3068.72060(3)
0.419107121
1.574276
−11.80339
446
1330(f)
3068.72053(3)
0.419111742
1.646400
29.89492
446
2110(e)
3165.85362(3)
0.415845548
1.676687
2.05913
17.9624
446
2110(f)
3165.85362(3)
0.416919208
1.584805
5.97780
5.3656
446
0201
3363.97798(2)
0.416546127
2.492196
30.92032
446
0221(e)
3373.14140(2)
0.416748424
1.176478
−32.62169
−12.1125
446
0221(f)
3373.14126(2)
0.416750079
1.809069
0.56789
−8.1147
446
1001
3480.81920(2)
0.413785728
1.722949
2.16595
446
0600
3466.59975(8)
0.421192628
6.298511
441.0033
319.04
446
0620(e)
3474.44972(14)
0.421309410
−1.521453
−399.1331
−1201.70
446
0620(f)
3474.44996(13)
0.421315010
2.619901
11.57393
69.145
446
1400
3620.94285(5)
0.418782901
3.805227
119.3536
82.9027
446
1420(e)
3631.58972(12)
0.419031158
0.341776
−108.730
−262.815
446
1420(f)
3631.58972(12)
0.419032886
2.118767
3.7046
66.74
446
2200
3748.25177(3)
0.416330169
2.380568
21.69615
−2.265
446
2220(e)
3766.05283(10)
0.417045204
1.213249
−28.3019
446
2220(f)
3766.05247(12)
0.417045031
1.636055
−2.1862
92.01
446
3000
3836.37099(3)
0.414159548
1.435010
15.2776
32.8175
446
0311(e)
3931.24766(2)
0.416262068
2.104143
12.21040
−12.768
446
0311(f)
3931.24747(3)
0.417728648
2.180777
−1.62105
446
0331(e)
3948.28475(3)
0.417331757
1.614372
−9.72991
446
0331(f)
3948.28456(6)
0.417336147
1.677448
33.78897
446
1111(e)
4061.97960(2)
0.414050142
1.739101
2.05788
446
1111(f)
4061.97956(3)
0.414934474
1.707180
1.31120
446
1510(e)
4197.96377(15)
0.417939711
2.579049
39.92334
446
1510(f)
4197.96382(15)
0.420254960
2.705885
−11.27368
446
1530(e/f)
4217.61977(30)
0.41950599
1.51961
−42.6139
446
2310(e)
4335.79996(15)
0.415923894
2.062313
10.07137
446
2310(f)
4335.79968(15)
0.417682034
2.106185
3.8335
446
2330(e/f)
4364.62559(30)
0.417642711
1.513535
−12.0361
446
0002
4417.37775(2)
0.412100081
1.748530
−0.2204
446
3110(e)
4446.38277(25)
0.414362319
1.561361
7.98418
−45.7646
446
3110(f)
4446.38265(25)
0.415670544
1.359849
5.9370
151.0653
446
0401
4491.54191(5)
0.417321527
3.982509
151.8160
108.169
446
0421(e)
4499.69405(13)
0.417471152
0.159866
−149.2159
−114.647
446
0421(f)
4499.69374(20)
0.417475225
2.156380
6.4716
−47.019
446
0441(e/f)
4523.70508(75)
0.41793556
3.2723
2739.89
−144003.
446
1201
4630.16112(5)
0.414761914
2.413621
28.0426
−72.0795
446
1221(e)
4642.46220(15)
0.415150953
1.208066
−26.145
17.326
446
1221(f)
4642.46222(15)
0.415150379
1.739224
2.257
446
2001
4730.82501(5)
0.412118918
1.623663
6.505
446
0511(e)
5053.58511(40)
0.416646447
2.99581
261.16
446
0511(f)
5053.58555(25)
0.418763750
2.89060
49.10
446
0531(e/f)
5069.07488(40)
0.417973678
1.60502
−42.718
4268.1
446
1311(e)
5200.78125(20)
0.414435123
2.070148
14.714
−27.05
446
1311(f)
5200.78090(25)
0.416011604
2.157292
6.80616
93.35
446
1331(e/f)
5222.47037(40)
0.415774377
1.55047
−13.265
446
2111(e)
5319.17364(25)
0.412431142
1.645910
−1.179
446
2111(f)
5319.17329(30)
0.413473519
1.581333
11.766
446
1002
5646.73800(30)
0.410314084
1.74136
−5.262
456
0000
0.0
0.418981810
1.763264
456
0110(e)
575.43365(20)
0.419108916
1.785826
456
0110(f)
575.43365(20)
0.419918641
1.794459
456
0200
1144.33338(12)
0.419921722
2.84542
66.796
456
0220(e)
1151.03090(40)
0.4200323
0.954
456
0220(f)
1151.03090(40)
0.4200348
1.813
456
1000
1280.35412(4)
0.417127307
1.754555
0.472
456
1110(e)
1860.19121(10)
0.417273136
1.773906
456
1110(f)
1860.19121(10)
0.418165235
1.760323
456
0001
2177.65681(3)
0.415654098
1.756773
0.1254
456
0400
2278.19266(90)
0.42068431
5.02913
300.086
456
1200
2431.32249(24)
0.418090902
2.744112
42.985
121.8
456
1220(e)
2439.59910(70)
0.4182829
1.0475
24.25
456
1220(f)
2439.59880(70)
0.4182861
1.8747
31.77
456
2000
2552.40823(8)
0.415298035
1.727937
1.98891
456
0111(e)
2739.59805(10)
0.415824755
1.776541
456
0111(f)
2739.59805(10)
0.416619104
1.787460
456
1310(e)
3003.31793(80)
0.41766611
2.07424
−24.48
456
1310(f)
3003.31779(80)
0.41934322
2.13157
−70.12
456
2110(e)
3136.97810(20)
0.415466013
1.744618
0.2191
456
2110(f)
3136.97794(20)
0.416466099
1.688420
−0.060
456
0201
3295.46206(20)
0.416670011
2.857513
70.977
456
0221(e)
3301.80085(50)
0.4167793
0.94
456
0221(f)
3301.80058(50)
0.4167808
1.805
456
1001
3432.19309(7)
0.413792520
1.749252
0.932
456
0311(e)
3852.16539(40)
0.416356997
2.068917
−51.648
456
0311(f)
3852.16535(40)
0.417898113
2.339417
41.404
456
1111(e)
3998.57148(30)
0.413992363
1.785911
6.258
456
1111(f)
3998.57154(30)
0.414860130
1.773694
8.473
546
0000
0.0
0.404857965
1.642938
1.8666
546
0110(e)
585.31212(10)
0.405037265
1.656798
546
0110(f)
585.31212(10)
0.405781109
1.667421
546
0200
1159.97171(8)
0.405712750
2.227530
22.07
546
0220(e)
1170.8430(20)
0.4059512
1.218
546
0220(f)
1170.8430(20)
0.4059504
1.691
546
1000
1269.89198(7)
0.403263601
1.597707
3.63434
546
0310(e)
1736.64780(40)
0.405410775
1.914464
546
0310(f)
1736.64792(40)
0.406798997
1.995707
546
1110(e)
1862.76708(20)
0.403489655
1.609708
546
1110(f)
1862.76708(20)
0.404358647
1.57529
546
0001
2201.60529(3)
0.401497172
1.640337
2.33799
546
0400
2305.16257(15)
0.406363987
3.3830
98.35
546
1200
2439.62463(15)
0.404060515
2.177559
18.634
546
1220(e)
2454.6058(8)
0.4045293
1.221
−21.
546
1220(f)
2454.6061(12)
0.4045285
1.6128
546
2000
2534.53206(10)
0.401815575
1.479775
8.0003
546
0111(e)
2772.70270(8)
0.401718382
1.650934
546
0111(f)
2772.70270(8)
0.402447853
1.663171
546
1310(e)
3020.09714(40)
0.40372666
1.96261
25.52
546
1310(f)
3020.09798(60)
0.40522933
1.958737
−2.325
546
2110(e)
3135.58222(15)
0.402061184
1.533367
2.6693
546
2110(f)
3135.58222(15)
0.403110961
1.417340
−0.97
546
0201
3333.73920(20)
0.402423892
2.225370
22.463
546
0221(e)
3344.11945(60)
0.4026622
1.213
546
0221(e)
3344.11945(60)
0.4026614
1.6804
546
1001
3443.64998(15)
0.399879921
1.575051
1.167
456
0311(e)
3896.77589(40)
0.402174114
1.963593
21.022
456
0311(f)
3896.77671(60)
0.403527991
1.918935
−36.350
456
1111(e)
4022.29004(20)
0.400160176
1.568285
−9.261
456
1111(f)
4022.28988(20)
0.401006266
1.547679
−6.365
448
0000
0.0
0.395577895
1.583456
448
0110(e)
584.22466(5)
0.395759697
1.60023
448
0110(f)
584.22466(5)
0.396471172
1.610773
448
0200
1155.13993(8)
0.396278138
2.055029
11.6701
448
0220(e)
1168.6979(50)
0.3966426
1.315
−14.
448
0220(f)
1168.6979(50)
0.3966437
1.640
1.0
448
1000
1246.88456(4)
0.394111338
1.49503
3.46236
448
0310(e)
1729.34728(30)
0.395988998
1.836498
448
0310(f)
1729.34712(20)
0.397277403
1.933747
448
1110(e)
1839.93604(10)
0.394349042
1.529218
2.8186
448
1110(f)
1839.93604(10)
0.395219127
1.472371
448
0001
2216.71118(4)
0.392350601
1.579205
0.12198
448
0400
2294.01729(11)
0.396795947
2.91198
57.2652
448
1200
2411.50672(10)
0.394608454
2.039123
10.3773
448
1220(e)
2431.4902(20)
0.3953809
1.336
448
1220(f)
2431.4902(20)
0.3953793
1.525
448
2000
2491.18700(7)
0.392925728
1.278238
12.060
448
0111(e)
2787.01684(15)
0.392572124
1.591979
448
0111(f)
2787.01684(15)
0.393272984
1.606549
448
1310(e)
2990.17682(40)
0.39434654
1.79927
−5.317
448
1310(f)
2990.17608(60)
0.395759349
1.95229
24.512
448
2110(e)
3093.35503(20)
0.393125755
1.392304
−0.13
448
2110(f)
3093.35486(20)
0.394228830
1.244958
−0.89
448
0201
3344.40349(10)
0.393109315
2.064257
14.240
448
0221(e)
3357.6760(20)
0.3934866
1.317
−15.3
448
0221(f)
3357.6760(20)
0.3934877
1.635
1.4
448
1001
3434.97624(20)
0.390862300
1.481533
3.350
448
0311(e)
3905.18230(40)
0.392862292
1.84656
0.792
448
0311(f)
3905.18305(40)
0.394123435
1.812007
−74.837
448
1111(e)
4014.33138(25)
0.391150488
1.493454
−4.972
448
1111(f)
4014.33171(25)
0.392003962
1.453930
2.007
447
0000
0.0
0.406672154
1.663972
447
0110(e)
586.36197(15)
0.406847
1.683
447
0110(f)
586.36197(15)
0.407599
1.713
447
0200
1161.54509(20)
0.40748554
2.22292
13.828
447
1000
1264.70426(7)
0.405053992
1.610001
3.371
447
1110(e)
1858.76380(20)
0.40528320
1.63744
447
1110(f)
1858.76380(20)
0.40617111
1.61142
447
0001
2220.07346(4)
0.403340066
1.663531
1.28501
447
1200
2435.72722(25)
0.405784433
2.24712
36.832
447
2000
2524.67255(10)
0.403616714
1.454285
7.2668
447
0111(e)
2792.36829(20)
0.40355779
1.68863
3.2887
447
0111(f)
2792.36829(20)
0.40429589
1.70866
447
0201
3354.00671(50)
0.404213155
1.961216
−136.674
447
1001
3456.63632(20)
0.401697793
1.585780
−1.816
556
0000
0.0
0.4048602
1.6356
556
1000
1265.33383(42)
0.40315372
1.62799
556
0001
2154.72590(20)
0.40161709
1.62797
−0.87
556
1001
3394.16294(70)
0.399900309
1.618442
−0.205
458
0000
0.0
0.3954676
1.584
458
0001
2171.04419(21)
0.39236091
1.58215
1.41
548
0000
0.0
0.3819194
1.467
548
0001
2194.04555(17)
0.37877905
1.46226
−0.40
Values given within parentheses are estimated uncertainties in the last digit(s).
Table II
Corrections (cm−1) to Computed 14N216O Frequencies Obtained in This Research
J
State
Correction × 103
70
0200
−0.2
71
0200
−1.10
72
0200
−1.92
73
0200
−2.62
74
0200
−3.01
75
0200
−3.3
76
0200
−3.5
53
0400
−0.40
54
0400
−0.90
55
0400
−1.53
56
0400
−2.60
57
0400
−4.00
58
0400
−5.39
59
0400
−7.72
60
0400
−10.56
61
0400
−14.15
62
0400
−18.71
63
0400
−24.13
64
0400
−31.26
65
0400
−39.85
66
0400
−48.77
67
0400
−60.72
53
0420 (e)
0.3
54
0420 (e)
0.9
55
0420 (e)
1.2
56
0420 (e)
2.2
57
0420(e)
3.8
58
0420 (e)
5.2
59
0420 (e)
6.9
60
0420 (e)
9.2
61
0420 (e)
12.6
62
0420 (e)
17.1
63
0420 (e)
22.0
64
0420 (e)
29.1
65
0420 (e)
40.6
50
0510 (e)
−0.3
51
0510 (e)
−0.59
52
0510 (e)
−0.92
53
0510 (e)
−1.2
54
0510 (e)
−1.6
55
0510 (e)
−2.52
56
0510 (e)
−3.0
57
0510 (e)
−3.91
58
0510 (e)
−5.5
59
0510 (e)
−6.0
60
0510 (e)
−7.2
51
0510 (f)
0.49
52
0510 (f)
0.6
53
0510 (f)
0.92
54
0510 (f)
1.4
55
0510 (f)
2.0
56
0510 (f)
2.74
57
0510 (f)
3.25
58
0510 (f)
3.87
59
0510 (f)
4.43
60
0510(f)
5.19
61
0510 (f)
5.77
Table III
Estimated Uncertainty, σCD, of Differences between Observed and Computed Combination Differences of Lower States for J ≤ 22 of 14N214O Bandsa
Values in cm−1 × 105.
Line finder frequency measurements only.
Table IV
Observed Line Positions (cm−1) of the 1200–0000, 1200–0200, and 1200–0110 Bands of N216Oa
J
1200–0000 Band
1200–0200 Band
1200–0110 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
2462.83276
2
0
1
2463.66728
-2
2461.15839
-3
1293.02435
-3
1872.39019
-3
1873.22486
-6
1
2
2464.50018
6
2460.31872
4
1296.36243
7
1875.73119
-6
1873.21760
-3
2
3
2465.33120
0
2459.47724
2
1876.56132
0
1873.20671
2
3
4
2466.16054
3
2458.63408
5
1298.01010
6
1290.48366
10
1877.38929
-1
1873.19212
2
4
5
2466.98806
0
2457.78914
1
1298.82857
5
1289.62966
6
1881.49732
-1
1873.17388
3
5
6
2467.81382
1
2456.94251
-0
1288.77220
8
1873.15198
5
6
7
2468.63779
2
2456.09420
4
1287.91125
12
7
8
2469.45987
-4
2455.24410
2
1287.04667
3
1866.46429
9
1873.09705
-0
8
9
2470.28019
-2
2454.39227
0
1286.17864
-2
1873.06408
1
9
10
2471.09869
3
2453.53866
-5
1882.31248
3
1864.75253
3
1873.02739
1
10
11
2471.91520
-2
2452.68333
-6
1284.43221
-3
1883.12535
-1
1863.89355
3
1872.98694
-2
11
12
2472.72989
-0
2451.82627
-3
1283.55373
-9
1863.03244
-1
1872.94280
0
12
13
2473.54259
-5
2450.96744
0
1305.24710
-2
1282.67194
1
1862.16926
0
1872.89487
0
13
14
2474.35341
-2
2450.10678
0
1306.03322
-1
1281.78650
-8
1861.30394
-1
1872.84314
-2
14
15
2475.16230
6
2449.24423
-8
1306.81570
-2
1280.89785
6
1886.35441
-2
1860.43648
-2
1872.78762
-4
15
16
2475.96902
-3
2448.38000
-1
1307.59463
4
1280.00564
9
1887.15585
-9
1859.56690
0
1872.72831
-2
16
17
2476.77379
-3
2447.51378
-8
1308.36969
-14
1887.95506
-1
1858.69517
5
1872.66515
0
17
18
2477.57659
7
2446.64577
-8
1309.14139
-5
1278.21085
8
1888.75185
3
1857.82112
-3
1872.59808
-2
18
19
2478.37706
-6
2445.77588
-6
1309.90951
8
1277.30825
0
1889.54602
-12
1856.94493
-3
1872.52714
-2
19
20
2479.17554
-5
2444.90404
-9
1310.67377
-1
1276.40235
3
1890.33802
2
1856.06651
-3
1872.45224
-5
20
21
2479.97188
-0
2444.03035
-3
1311.43460
11
1891.12734
-3
1855.18583
-3
1872.37343
-4
21
22
2480.96597
-0
2443.15460
-6
1274.58023
-3
1891.91421
0
1854.30289
-1
1872.29066
-0
22
23
2481.55781
-1
2442.27692
-4
1273.66405
-9
1872.20381
-5
23
24
2482.34739
0
2441.39722
-3
1313.69477
-2
24
25
2483.13462
-1
2440.51546
-3
1894.25933
13
1851.64006
0
25
26
2483.91956
5
2439.63162
-3
1270.89558
2
1895.03549
-7
1871.91903
-0
26
27
2484.70199
-0
2438.74573
2
1895.80925
5
1849.85292
0
1871.81587
2
27
28
2485.48206
4
2437.85762
-1
1316.65749
4
1269.03310
4
1896.58015
7
1848.95569
0
1871.70855
5
28
29
2486.25959
2
2436.96744
6
1317.38888
-10
1268.09675
-5
1897.34821
5
1848.05598
0
1871.59697
5
29
30
2487.03463
5
2436.07491
-2
1318.11680
-6
1267.15722
1
1898.11342
2
1847.15377
2
1871.48119
9
30
31
2487.80703
2
2435.18026
3
1318.84099
-8
1266.21426
-4
1898.87575
0
1846.24901
4
31
32
2488.57688
6
2434.28332
6
1319.56171
8
1265.26798
-9
32
33
2489.34404
8
2433.38403
5
1264.31855
1
1900.39152
-9
1871.10783
8
33
34
2490.10843
5
2432.48243
8
1320.99175
0
1263.36575
3
1843.51900
0
1870.97468
14
34
35
2490.87011
7
2431.57840
7
1321.70123
-8
1870.83705
16
35
36
2491.62895
7
2430.67195
6
1322.40721
1
1261.45030
9
1902.64272
9
1841.68575
11
1870.69486
11
36
37
2492.38492
5
2429.76308
9
1260.48758
4
1840.76493
10
1870.54823
14
37
38
2493.13800
5
2428.85162
4
1323.80805
7
1259.52158
-3
1904.12768
8
1870.39703
17
38
39
2493.88814
7
2427.93769
7
1324.50288
2
1258.55235
-7
1904.86538
15
1838.91487
8
39
40
2494.63526
8
2427.02116
7
1325.19406
-1
1257.57985
-13
1905.59947
-9
1870.08069
16
40
41
2495.37922
-2
2426.10199
6
1906.33066
11
1837.05332
8
1869.91542
7
41
42
2496.12026
7
2425.18020
9
1326.56555
10
1255.62535
-2
1869.74563
19
42
43
2496.85810
10
2424.25567
9
1327.24571
9
1869.57082
7
43
44
2497.59259
0
2423.32835
4
1327.92218
7
1253.65792
9
44
45
2498.32396
3
2422.39831
5
1328.59496
5
45
46
2499.05199
1
2421.46546
9
1832.34713
8
46
47
2499.77670
3
2420.52963
1
1868.8236
18
47
48
2500.49798
1
2419.59096
-0
1330.59128
9
1868.6242
-4
48
49
2501.21576
-6
2418.64934
-2
1331.24930
7
1829.48599
6
49
50
2501.93013
-5
2417.70487
11
1331.90367
10
50
51
2502.64099
-1
2416.75712
-3
1332.55433
12
1246.67027
-9
1827.56237
7
51
52
2503.34821
-3
2415.80641
-5
1333.20120
5
1245.65940
3
1826.59550
-2
52
53
2504.05187
3
2414.85265
-2
1333.84444
6
53
54
2504.75172
-5
2413.89574
-1
1334.48395
6
54
55
2505.44792
-7
2412.93559
-5
1335.11972
4
55
56
2506.14042
-2
1335.75180
5
1822.69443
3
56
57
2506.82919
9
2411.00571
-5
57
58
2507.51397
6
2410.03589
-2
1337.00468
-2
1239.52670
-0
1820.7232
21
58
59
2508.19484
-1
59
60
2508.87187
1
2408.08619
-6
1237.45724
15
60
61
2509.54504
11
2407.10639
2
1338.85635
30
1236.41759
9
61
62
2510.21403
2
2406.12314
6
62
63
2510.87899
-8
2405.13649
13
63
64
2511.54004
-4
2404.14615
-4
64
66
2512.84999
16
66
67
2513.49844
-9
2401.15476
7
67
68
2514.14332
26
68
69
2514.78331
-12
2399.14275
7
69
70
2515.41969
9
70
72
2516.6793
1
2396.0979
7
72
74
2517.9219
-15
2394.04992
-0
74
75
2518.5370
-6
2393.02022
-34
75
76
2519.1477
-12
76
77
2519.7545
17
77
78
2520.3566
1
78
O - C are the observed minus the computed frequencies in cm-1 × 105.
Table V
Observed Line Positions (cm-1) of the 2000–0000 and 2000–1000 Bands of 14N216Oa
J
2000–0000 Band
2000–1000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
2564.17068
3
1279.26726
-2
0
1
2564.99506
1
2562.50144
2
1277.60155
-4
1
2
2568.51260
-3
2561.65662
3
1280.91989
7
2
3
2566.62341
3
2560.80500
4
1275.92272
3
3
4
2567.42731
0
2559.94654
1
1282.55908
-0
4
5
2568.22446
5
2559.08135
4
1274.23075
11
5
6
2569.01466
-3
2558.20935
4
6
7
2569.79811
-2
2557.33057
5
1272.52549
-0
7
8
2570.57474
1
2556.44499
3
1285.79776
-3
1271.66812
10
8
9
2571.34450
-0
2555.55264
1
1286.59910
-6
1270.80738
10
9
10
2572.10744
0
2554.65356
3
10
11
2572.86353
-0
2553.74767
-1
1269.07614
9
11
12
2573.61281
2
2552.83509
0
1288.98331
4
1268.20563
7
12
13
2574.35519
-2
2551.91578
3
1289.77135
4
1267.33193
8
13
14
2575.09079
-0
2550.98969
1
1266.45498
8
14
15
2575.81953
-1
2550.05686
-2
1265.57481
7
15
16
2576.54146
2
2549.11736
-2
1292.11538
-5
1264.69138
3
16
17
2577.25649
-3
2548.17114
-2
1292.89024
11
17
18
2577.96474
-2
2547.21824
-0
1293.66153
4
18
19
2578.66617
1
2546.25860
-4
1294.42948
-4
19
20
2579.36070
-3
2545.29233
-3
1295.19424
3
1261.12589
5
20
21
2580.04849
1
2544.31940
-2
1295.95554
-3
1260.22652
1
21
22
2580.72939
-1
2543.33978
-3
1259.32408
7
22
23
2581.40350
-0
2542.35353
-3
1297.46820
-10
1258.41842
7
23
24
2582.07080
1
2541.36069
1
24
25
2582.73124
-2
2540.36111
-6
1298.96769
-1
25
26
2583.38489
-3
2539.35501
-4
1255.68249
-6
26
27
2584.03177
-1
2538.34233
-1
1254.76435
-2
27
28
2584.67186
1
2537.32294
-10
1301.19184
-4
1253.84306
-2
28
29
2585.30507
-5
2536.29712
-6
1301.92667
3
1252.91860
.10
29
30
2585.93164
3
2535.26470
-5
1302.65815
7
1251.99122
-1
30
31
2586.55129
-3
2534.22575
-4
1303.38629
7
1251.06068
-1
31
32
2587.16423
-3
2533.18027
-2
1304.11114
8
1250.12714
5
32
33
2587.77044
0
2532.12825
-4
1304.83277
18
33
34
2588.36986
-1
2531.06974
-5
1248.25080
4
34
35
2588.96261
6
2530.00481
-1
1247.30803
-2
35
36
2589.54848
-2
2528.93336
-2
1246.36248
14
36
37
2590.12772
-1
2527.85552
2
1245.41370
7
37
38
2590.70024
-0
2526.77118
-1
1244.46214
20
38
39
2591.26609
3
2525.68049
1
1309.09299
13
39
40
2591.82523
4
2524.58340
1
40
41
2592.37764
-0
2523.47989
-3
41
42
2592.92348
5
2522.37014
2
1311.17908
8
1240.62570
2
42
43
2593.46263
5
2521.25400
2
1311.86799
7
43
44
2593.99509
-1
2520.13157
2
1238.69019
11
44
45
2594.52102
2
2519.00289
5
1313.23608
-4
1237.71809
13
45
46
2595.04034
4
2517.86792
4
1236.74313
13
46
47
2595.55312
10
2516.72668
2
1314.59154
-1
47
48
2596.05920
1
2515.57936
7
48
49
2596.55885
4
2514.42572
1
1233.80122
0
49
50
2597.05188
-3
2513.26591
-7
1232.81512
7
50
51
2597.53856
6
2512.10018
5
1231.82614
-0
51
52
2598.01866
4
2510.92821
3
1317.92489
-5
52
53
2509.75022
5
53
54
2598.95952
-0
2508.56616
3
1228.84318
5
54
55
2507.37614
5
55
56
2599.87479
-1
2506.18009
2
56
57
2600.32287
-3
2504.97811
-1
1225.83636
15
57
58
2600.7644
-28
2503.77020
-7
1224.82896
25
58
59
2601.20012
-5
2502.55657
1
59
60
2601.62924
-15
2501.33700
-2
60
61
2602.05244
5
61
62
2498.88058
-3
62
63
2602.87989
6
2497.64384
2
63
65
2603.68271
-8
2495.15318
-12
65
66
2604.07515
-3
2493.89952
-13
66
67
2604.46159
3
2492.64052
5
67
68
2604.84196
-3
2491.37592
11
68
70
2605.58512
-1
2488.83028
4
70
71
2605.94779
-15
2487.54941
-3
71
72
2486.26342
6
72
73
2606.65632
2
2484.97219
12
73
74
2607.00199
4
2483.67548
-13
74
77
2608.00548
3
2479.75589
-2
77
81
2609.2679
21
2474.46139
11
81
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table VI
Observed Line Positions (cm-1) of the 1220(e)–0000, 1220(e)–0220(e), and 0220(e)–0110 Bands of N216Oa
J
1220(e)–0000 Band
1220(e)–0220(e) Band
1220(e)–0110 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
2
1299.55557
-6
2
3
1300.38314
3
3
4
1890.20316
1
1882.66968
-1
4
5
1302.02854
9
1292.82089
-5
1891.03369
-3
1881.82625
1
5
6
1891.86297
-3
1880.98152
1
6
7
1892.69100
1
7
8
1290.24285
-11
1893.51771
1
8
9
1289.37739
10
1894.34315
0
1878.43981
-2
9
10
1306.08559
-3
1877.59019
1
10
11
2465.52921
1
1895.99026
1
1876.73935
1
11
12
2464.68124
6
1896.81195
1
1875.88732
-1
12
13
2486.4308
22
1285.88284
-18
1897.63247
4
1875.03418
2
13
14
2487.25452
5
1874.17988
2
14
15
2488.07746
-4
1284.11702
7
1873.32449
4
15
16
2488.89975
7
2461.28116
11
1872.46798
3
16
17
2489.72112
10
1885.59587
8
17
18
2490.54149
-4
1281.44421
-4
18
19
2458.72315
1
1869.89222
6
1855.49219
0
19
20
2457.86904
-10
1279.64683
8
1903.34270
9
1869.03161
5
20
21
2492.99839
2
1278.74345
15
1904.15386
0
1885.37811
2
21
22
2493.81574
-7
1904.96407
2
1867.30756
5
1885.31717
0
22
23
2455.30349
4
1905.77325
4
1866.44420
8
1885.25369
-2
23
24
1906.58137
2
1865.57995
8
1885.18774
0
24
25
2496.26399
5
2453.59024
3
1907.38850
-2
1885.11933
6
25
26
2497.07860
-6
2452.73294
10
1274.17926
8
1908.19470
-1
1863.84897
8
1885.04838
2
26
27
2497.89264
-13
1273.25696
-5
1908.99997
-1
1862.98224
1
27
28
2498.70620
-8
2451.01686
8
1272.33175
2
1909.80430
-4
1884.89924
-5
28
29
2499.51912
-10
2450.15804
-12
1910.60783
1
1861.24677
1
29
30
1911.41047
1
1860.37805
4
30
31
1269.53736
10
1912.21222
-5
1884.65799
-7
31
32
1913.01326
-4
1884.57278
-31
32
33
2502.76590
-2
2446.72051
1
1913.81355
-1
1857.76812
-4
1884.48582
-7
33
34
1914.61308
-1
1856.89714
1
1884.39635
-16
34
35
2504.38654
-3
2445.00018
-10
1265.76812
10
1856.02558
-5
1884.30490
-6
35
36
2505.19634
1
2444.13999
4
1916.21003
-5
1855.15368
-2
1884.21117
-13
36
37
2506.00576
1
2443.27956
4
1263.86496
2
1917.00758
-2
1854.28135
-2
1884.11542
-13
37
38
2506.81497
11
1884.01761
-15
38
39
2441.55844
-7
1918.60087
2
1883.91779
-16
39
40
2508.43231
6
1260.98731
-5
1919.39669
6
1883.81604
-12
40
41
2439.83744
-11
1920.19181
-9
1883.71235
-8
41
42
2438.97713
-4
1883.60664
-16
42
43
2510.85664
-5
2438.11684
-9
1849.04122
-2
1883.49920
-10
43
44
2511.66445
-5
2437.25672
-12
1922.57490
2
1848.16719
-3
1883.38977
-19
44
45
2436.39694
-1
1883.27865
-16
45
46
2435.53731
3
1255.15011
-2
1883.16584
-6
46
47
1333.57618
3
1254.16660
-11
1845.54479
-1
47
48
1253.18029
0
1844.67069
3
1882.93482
-8
48
49
2515.70224
-2
1334.93298
-16
1252.19078
-11
1843.79648
-11
1882.81666
-22
49
50
1251.19840
-11
1842.92275
15
1882.69710
-12
50
51
2431.24364
6
1336.27673
-4
1250.20316
-1
1842.04872
-2
1882.57583
-11
51
52
2430.38590
-9
1336.94342
-15
52
53
2518.93218
-6
1882.32860
-7
53
54
2428.76214
-5
1338.26712
-3
1247.19943
-5
54
55
2427.81599
-4
1338.92400
7
1246.19237
-2
55
56
2521.3554
2
2426.96036
-5
1339.57731
-6
56
57
2522.1630
-29
1340.22753
6
1244.16943
-9
1836.8100
-4
57
58
2522.97134
2
2425.25077
-8
1340.87419
-5
1243.15384
7
1835.9378
-12
58
59
2424.3968
-14
1242.13520
5
59
60
2423.5437
5
1342.15784
6
1241.11374
6
60
61
2525.39622
6
1342.79472
16
1240.08935
-4
61
62
2526.2045
-20
1343.42798
-5
1239.06240
11
62
63
2420.98751
-8
1344.05828
11
63
64
2420.1373
42
1344.68500
-1
64
65
2528.63119
13
1345.30855
0
65
66
1345.92868
-11
66
67
2530.2485
-65
2417.5880
-74
1346.54564
-11
67
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table VII
Observed Line Positions (cm-1) of the 2110–0110 and 2110–0000 Bands of N216Oa
J
2110(e)–0110(e) Band
2110(f)–0110(f)Band
2110–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
3166.68528
-3
0
1
2578.7423
-5
2578.7432
0
3167.5103
-37
1
2
2579.5607
-11
2575.4024
2
2579.5690
6
2575.3996
-17
2
3
2580.37252
4
2574.5506
-11
2580.38444
-1
2574.5475
-14
3169.14224
-12
3163.3203
-28
3165.8281
-37
3
4
2581.17748
0
2573.6923
-8
2581.19379
-6
2573.6894
-3
3169.9485
-19
3162.46362
3
3165.81184
10
4
5
2581.97582
3
2581.99706
-8
3170.7485
-17
3165.79095
12
5
6
2582.76744
2
2571.95574
-7
2582.79427
-4
2571.95472
-4
3171.54211
-19
3160.73064
-5
3165.76582
8
6
7
2583.55233
-3
2583.58531
-5
3172.3294
-17
3159.8544
-38
3165.7362
-28
7
8
2584.33060
-1
2570.1925
-19
2584.37029
-0
2570.1957
-13
3173.11043
-5
3158.97257
0
3165.70313
8
8
9
2585.10215
-1
2569.30114
-5
2585.14909
-2
2569.30714
-13
3173.88492
-12
3165.6653
-15
9
10
2585.86702
-1
2568.40312
4
2585.92179
-2
2568.41267
-1
3174.65326
3
3157.18924
-4
3165.62375
7
10
11
2586.62520
0
2567.49831
-4
2586.68832
-7
2567.51204
-1
3175.4152
14
3156.28827
5
3165.57774
-2
11
12
2587.37670
3
2566.58705
3
2587.44884
-2
2566.60539
0
3176.17062
9
3155.38083
-5
3165.52774
6
12
13
2588.12154
9
2565.66912
2
2588.20317
-5
2565.69262
-10
3176.91962
-0
3154.46724
-4
3165.47345
0
13
14
2588.85951
-2
2564.74460
1
2588.95148
1
2564.77399
-5
3177.66228
-7
3153.5472
-21
3165.41509
2
14
15
2589.59089
-2
2563.81349
-0
2589.69361
3
2563.84930
-6
3178.39872
1
3165.35259
3
15
16
2590.31563
4
2562.87582
-0
2590.42959
-8
2562.91862
-8
3179.12871
1
3151.68894
1
3165.28599
8
16
17
2591.03359
1
2561.93158
-1
2591.15961
-1
2561.98206
-1
3179.85232
0
3150.75030
-3
3165.21521
7
17
18
2591.74485
-2
2560.98085
5
2591.88342
-6
2561.03947
-2
3180.56959
3
3149.80555
5
3165.14024
-2
18
19
2592.44944
-2
2560.02349
3
2592.60131
6
2560.09083
-12
3181.28041
-3
3148.85434
-10
3165.06129
3
19
20
2593.14737
2
2559.05964
5
2593.31295
0
2559.13645
-4
3181.98490
-4
3147.8968
-37
3164.97814
-3
20
21
2593.8386
4
2558.08919
1
2558.17606
-5
3182.68309
2
3146.93361
-9
3164.89115
17
21
22
2557.11223
-3
2594.71815
2
2557.20979
-3
3183.37481
-2
3164.79973
2
22
23
2595.20092
3
2556.12881
-1
2595.41162
-1
2556.23762
-3
3184.06014
-8
3144.9878
-35
3164.7041
-27
23
24
2595.87202
-0
2555.13892
4
2596.09908
-0
2555.25962
1
3184.7394
16
3144.0065
39
3164.60499
3
24
25
2596.53649
2
2554.14244
-2
2596.78051
1
2554.27562
-9
3185.41181
-9
3164.50156
5
25
26
2597.19423
-0
2553.1394
-16
2597.45584
-5
2553.28594
-3
3186.07824
6
3164.39407
5
26
27
2597.84536
4
2552.13024
5
2598.12526
1
2552.29042
-0
3186.7382
9
3164.28261
11
27
28
2551.11432
-4
2598.78857
-5
2551.28900
-7
3187.39172
5
28
29
2599.12750
4
2550.09209
-0
2599.44599
1
2550.28190
-3
3188.03881
-6
3164.0472
-24
29
30
2599.75856
3
2549.06344
5
2600.09735
-2
2549.26892
-12
3188.67969
-2
3163.92387
-6
30
31
2600.38298
4
2548.02826
-1
2600.74272
-7
2548.25042
2
3189.31420
-0
3163.79648
4
31
32
2601.00069
0
2547.98678
4
2601.38219
-6
3189.9424
6
3163.66509
9
32
33
2601.61178
-0
2545.93878
-4
2602.01578
0
2546.19596
-3
3190.56414
1
3163.52969
7
33
34
2602.21620
-3
2544.88451
-1
2602.64329
-9
2545.16022
-5
3191.17951
-7
3163.39024
-8
34
35
2602.81406
2
2543.82388
2
2603.26507
-0
2544.11889
0
3191.78874
5
3163.2469
-21
35
36
2603.50419
-2
2542.75687
3
2603.88089
1
2543.07181
-8
3192.39146
-0
3163.09994
-7
36
37
2603.98972
-4
2541.68351
3
2604.49074
-7
2542.01925
-3
3192.98787
-4
3162.94914
9
37
38
2604.56772
4
2540.60384
3
2605.09489
0
2540.96109
-1
3193.5778
-23
3162.79414
-9
38
39
2605.13894
-6
2539.51779
-4
2605.69309
-4
2539.89739
2
3194.16174
-10
3162.63574
15
39
40
2605.70379
8
2538.42558
1
2606.28552
-5
2538.82812
0
3194.73927
-6
3162.47324
10
40
41
2606.26181
-1
2606.87222
1
2537.75340
3
3195.31053
2
3162.30692
1
41
42
2606.81336
1
2536.22210
-11
2607.45310
2
2536.67317
0
3195.87535
-5
3162.13704
13
42
43
2607.35840
10
2535.11114
-2
2608.02821
0
2535.58755
3
3196.43403
3
3161.96324
7
43
44
2607.89672
3
2533.99387
-3
2608.59763
1
2534.49650
2
3196.98634
2
3161.78564
-7
44
45
2608.42847
-5
2532.87047
4
2609.16127
-6
2533.40000
-7
3197.53239
3
3161.4199
14
45
46
2608.95379
-2
2531.74070
-8
2609.71937
0
2532.29830
-1
3198.07214
1
46
47
2609.47267
10
2530.60499
3
2610.27173
-4
2531.19130
4
3198.6055
-15
3161.23144
13
47
48
2529.46297
-3
2610.81850
-5
2530.07888
-5
3199.13291
-1
48
49
2610.49055
2
2611.35966
-9
2528.96137
-0
3160.8431
-51
49
50
2610.98979
2
2527.16064
-8
2611.89544
4
2527.8389
28
3200.16888
11
50
51
2611.48257
4
2526.00044
-0
2612.42564
12
2526.71067
-3
3200.67743
6
51
52
2611.96894
11
2524.83408
-3
2612.95012
-3
2525.57764
-3
52
53
2612.44873
6
2523.66165
-9
2613.46930
-3
2524.43949
-7
3201.6761
12
53
54
2612.92204
-5
2523.29636
-5
3202.1661
8
54
55
2613.38906
-4
2521.29889
-9
2614.49128
-17
2522.14824
-2
55
56
2613.84960
-10
2520.1090
36
2614.99448
0
2520.99529
12
3203.1280
37
56
57
2614.30384
-10
2518.91244
7
2615.49215
-4
2519.83715
-2
57
58
2614.75197
16
2517.71014
-4
2615.98454
-10
2518.67431
1
58
59
2615.19335
0
2616.4716
-26
2517.5069
27
59
60
2615.6289
33
2515.28811
-8
2616.95380
-10
2516.33424
5
60
61
2616.05744
-6
2514.06862
19
2617.4309
10
2515.1567
-34
61
62
2617.90269
8
2513.97514
-9
62
63
2616.8968
22
2511.61180
23
2618.36941
4
2512.78876
-5
63
64
2617.3070
22
2510.3748
27
2618.83094
-19
64
65
2617.71084
6
2619.2878
-15
2510.40241
5
65
66
2618.1083
-33
2507.8838
43
66
67
2618.50051
18
2620.18697
1
2507.99809
-7
67
68
2618.88617
24
2505.36981
12
2620.62940
14
2506.78964
10
68
69
2619.26548
2
2504.10444
-6
2621.06684
0
2505.5768
13
69
70
2619.63904
9
2502.8341
31
2621.49963
-11
2504.3592
-41
70
71
2621.92807
3
2503.1382
-21
71
72
2500.2762
22
72
73
2622.7708
-27
73
74
2499.4505
-25
74
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table VIII
Observed Line Positions (cm-1) of the 1310–0110 and 1310–0000 Bands of N216Oa
J
1310(e)–0110(e) Band
1310(f)–0110(f)Band
1310–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
3047.0482
-24
0
1
2459.11314
-5
2459.12126
-5
3047.8810
-44
1
2459.94284
-17
2459.95744
-24
3048.71209
15
2
3
2460.77001
3
2460.79269
-14
3043.6911
-26
3
4
2461.59403
-5
2461.62677
0
4
5
2462.41534
3
2453.22489
-2
2462.45946
-3
2453.23351
1
3051.18826
1
3041.9972
-64
5
6
2463.23366
-1
2452.37224
-17
2452.38759
-9
3052.00857
-3
3041.1471
-24
6
7
2464.04914
1
2451.51704
-5
2464.12117
-6
2451.54059
-8
3052.82643
3
3040.29429
-6
7
8
2464.86170
0
2450.65881
-13
2464.95019
-3
2450.69248
-2
3053.64154
-9
3039.4387
-17
8
9
2465.67133
-2
2449.79794
-3
2465.77794
-1
2449.84309
-5
3054.45428
-0
3038.58086
-4
9
10
2466.47810
1
2448.93411
-6
2466.60437
-4
2448.99260
-1
3055.26422
-13
3037.72042
-1
10
11
2467.28182
-7
2448.06749
-5
2467.42959
1
2448.14090
1
3056.07183
3
3036.85738
-8
11
12
2468.08273
-1
2447.19807
-1
2468.25346
2
2447.28792
-5
3056.87654
-11
3035.99187
-12
3046.26894
3
12
13
2468.88063
0
2446.32581
2
2469.07599
1
2446.43387
-3
3057.67884
-2
3035.12392
-10
3046.27813
5
13
14
2469.67555
1
2445.45063
-2
2469.89716
-2
2445.57859
-2
3058.47830
-12
3046.28795
7
14
15
2470.46753
6
2444.57269
2
2470.71699
-5
2444.72213
1
3059.27519
-14
3033.38051
-2
3046.29839
7
15
16
2471.25641
2
2443.69177
-7
2471.53546
-6
2443.86438
-3
3060.06951
-4
3032.5050
0
3046.30946
8
16
17
2472.04232
3
2442.80826
11
2472.35251
-10
2443.00540
-9
3060.86102
-6
3046.32114
10
17
18
2472.82515
0
2441.92169
9
2473.16826
-3
2442.14526
-7
3061.64985
-5
3046.33340
10
18
19
2473.60501
6
2473.98253
-1
2441.28389
-5
3062.43592
-7
3029.8630
-21
3046.34624
12
19
20
2474.38175
7
2474.79532
-3
3063.21928
-4
3028.97755
4
3046.35954
3
20
21
2439.24462
-6
2475.60661
-7
2439.55732
-7
3063.99988
-1
3028.08924
0
3046.3735
7
21
22
2475.92589
5
2438.34659
1
2476.41655
4
2438.69209
-13
3064.77765
-1
3027.19844
4
3046.3879
4
22
23
2476.69319
-5
2437.44554
-4
2477.22482
-1
2437.82561
-14
3065.5523
-32
3026.3047
-27
3046.4028
0
23
24
2477.45752
4
2436.54162
-4
2478.03154
-6
2436.95799
0
3066.32464
-11
3025.4092
27
3046.4183
9
24
25
2478.21856
1
2435.63479
-2
2436.08896
6
3024.51024
-5
3046.43404
-3
25
26
2478.97646
4
2434.72499
-2
2479.64056
16
2435.2183
-19
3067.86035
-8
3023.6088
-22
3046.45034
-3
26
27
2479.73105
-3
2433.81231
4
2480.44240
2
2434.34669
-3
3068.62382
-11
3022.7049
-21
3046.46704
-3
27
28
2480.48253
3
2481.24270
-1
2433.47352
-6
3069.38445
-5
3021.7987
15
3046.48415
-2
28
29
2431.97789
3
2482.04137
1
2432.59904
-2
3070.14210
-2
3046.50163
4
29
30
2481.97556
2
2431.05622
5
2482.83833
3
2431.72302
-11
3070.89673
-5
3046.5194
5
30
31
2482.71696
-16
2430.13149
2
2483.63344
-6
2430.84566
-12
3071.64839
-4
3019.0630
21
3046.5374
-2
31
32
2483.45546
10
2429.20379
3
2484.42697
5
2429.96689
-8
3072.39697
-10
3046.5557
-6
32
33
2484.19017
-8
2428.27296
-4
2485.21848
-6
2429.08662
-8
3073.14268
3
3046.5743
-4
33
34
2484.92179
3
2427.33931
11
2486.00837
4
2428.20501
7
3073.8850
-16
3046.5931
-3
34
35
2485.64990
3
2426.40226
-6
2486.79628
4
2427.3218
14
3074.62450
-7
3046.61214
3
35
36
2486.37456
2
2425.46242
5
2487.58228
4
2426.43684
1
3075.36089
4
3046.6311
-13
36
37
2487.09572
-5
2424.51926
-5
2488.36624
-6
2425.55042
-2
3076.09399
2
3046.6504
-6
37
38
2423.57314
-0
2489.14842
4
2424.66251
5
3076.82384
-8
3046.6697
-8
38
39
2488.52772
-4
2422.62386
2
2489.92848
3
2423.77288
2
3077.55061
-4
3046.6890
-14
39
40
2489.23842
-5
2421.67132
-7
2490.70641
-5
2422.88159
-2
3078.27411
-3
3046.7084
-11
40
41
2489.94564
1
2420.71565
-12
2491.48242
4
2421.98859
-10
3078.9943
-7
3046.7278
-5
41
42
2490.64915
-5
2419.75709
12
2492.25609
-7
2421.09412
6
42
43
2491.34909
-8
2418.79499
2
2493.02781
4
2420.19769
-0
3080.4250
8
43
44
2492.04549
-1
2493.79711
-6
2419.29959
3
3081.13517
0
44
45
2492.73826
9
2416.86134
5
2494.56426
-5
2418.39966
3
45
46
2493.42707
-8
2415.88959
1
2495.32908
-7
2417.49792
6
46
47
2494.11232
-10
2414.91457
-4
2496.09155
-9
2416.5940
-24
3083.2454
-15
47
48
2494.79404
10
2413.93619
-15
48
49
2495.47162
-8
2497.60929
-14
2414.78127
2
3084.6353
12
49
50
2496.14566
-0
2498.36451
-12
50
51
2496.81602
21
2499.11737
6
2412.9605
12
51
52
2409.99001
1
2499.86737
-5
2412.04697
7
52
53
2498.1447
18
2408.99496
-5
2500.61499
9
2411.13134
-1
53
54
2407.99680
17
2501.35986
13
2410.21364
-3
54
55
2499.45776
12
2406.99506
23
2502.10179
-5
2409.29378
-6
55
56
2405.98956
-4
2502.84136
17
2408.37186
4
56
57
2500.75504
9
2404.98081
-10
2407.44759
3
57
58
2501.39751
-10
2406.5207
-32
58
59
2502.03637
14
2402.95332
20
2505.0416
-58
2405.59221
4
59
60
2404.66090
-6
60
61
2503.3010
-30
2506.49462
-16
2403.72739
3
61
62
2503.92778
9
2402.79125
-6
62
63
2507.93505
-7
63
64
2505.16801
-3
2397.8244
35
2508.65076
19
64
65
2399.96827
15
65
66
2399.02171
-18
66
67
2506.9976
45
2510.77729
-13
67
68
2507.59844
6
68
69
2512.17854
-2
69
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table IX
Observed Line Positions (cm-1) of the 0201–0000, 0201–0200, and 0201–0110 Bands of N216Oa
J
0201–0000 Band
0201–0200 Band
0201–0110 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
3364.81108
1
0
1
3365.63927
4
3363.13999
3
2197.50510
-1
2776.87104
2
2775.20329
3
1
2
3366.46248
4
3362.29705
4
2194.15924
-2
2777.69353
-4
2773.52822
8
2775.1897
13
2
3
3367.28071
1
3361.44918
4
2199.13750
1
2193.30591
-2
2778.51083
1
2772.67922
-5
2775.16901
-1
3
4
3368.09404
5
3360.59643
8
2199.94351
-1
2192.4456
-28
2779.3229
12
2771.82508
-6
2775.14165
4
4
5
3368.90234
3
3359.73867
4
2191.57912
2
2770.9655
-25
2775.10730
-4
5
6
3369.70565
2
3358.87602
3
2201.53516
-8
2190.70560
0
2780.93080
5
2775.06618
-1
6
7
3370.50394
-1
3358.00846
4
2202.32086
-6
2189.82536
-3
2781.72676
3
2769.2314
20
2775.01816
-0
7
8
3371.29726
2
3357.13591
0
2203.09976
-4
2188.93845
-2
2782.51742
6
2768.35602
-1
2774.96328
4
8
9
3372.08546
-2
3356.25845
-0
2203.87188
1
2188.04480
-4
2783.30254
-6
2767.47562
5
2774.90144
3
9
10
3372.86867
1
3355.37607
3
2187.14453
1
10
11
3373.64672
-2
3354.48863
-3
2205.39558
-1
2186.23753
2
2784.85678
-9
2765.69889
10
2774.7568
-17
11
12
3374.41965
-6
2206.14720
-2
2185.32383
1
2785.62589
4
2764.8025
5
2774.67435
3
12
13
3375.18751
-3
3352.69891
-5
2206.89202
-1
2184.40339
-6
2786.38934
-2
2763.90074
-4
2774.58472
5
13
14
3375.95021
1
3351.79658
-2
2183.47638
-2
2787.14732
-5
2774.48807
-1
14
15
3376.70767
1
3350.88922
1
2208.36114
0
2787.89979
-6
2762.08138
-2
2774.3845
7
15
16
3377.45987
-2
3349.97676
-2
2209.08545
2
2181.60233
1
2788.6466
-17
2761.16360
-7
2774.2738
5
16
17
3378.20677
-9
3349.05926
-2
2209.80286
-1
2180.65534
5
2789.3880
-11
2760.24052
-1
2774.15592
-8
17
18
3378.94853
0
3348.13663
-6
2210.51348
3
2179.70164
3
2759.31199
1
2774.03108
-7
18
19
3379.68481
-6
3347.20895
-3
2211.21722
4
2178.74132
3
2758.37796
-4
2773.89913
-4
19
20
3380.41585
0
3346.27605
-9
2211.91407
3
2177.77437
4
2791.57830
4
2757.43857
2
2773.76007
2
20
21
3381.14132
-10
3345.33805
-8
2212.60406
3
2176.80077
3
2756.49356
-5
2773.6135
-24
21
22
3381.86150
-5
3344.39486
-7
2213.28717
3
2793.00992
14
2755.54317
1
2773.46026
5
22
23
3382.57617
-3
3343.44644
-6
2213.96341
4
2174.83372
4
2793.71684
-2
2754.58715
-2
2773.29940
-4
23
24
3383.28531
-1
3342.49284
2
2214.63274
2
2173.84027
5
2773.13136
-2
24
25
3383.98884
-3
3341.53380
-6
2215.29524
7
2172.84014
-2
2795.11346
2
2752.65819
-24
25
26
3384.68679
-3
3340.56960
2
2215.95076
4
2171.83351
2
2795.80282
-4
2751.68559
-4
2772.77332
4
26
27
3385.37910
-1
3339.59992
-3
2216.59942
4
2170.82024
2
2796.48641
10
2750.70722
6
2772.58321
5
27
28
3386.06571
1
3338.62493
-1
2217.24116
4
2169.80040
4
2797.16394
19
2749.72299
-0
28
29
3386.74657
3
3337.64448
-2
2217.87602
6
2168.77392
1
2797.83524
11
2748.73304
-5
2772.18064
4
29
30
3387.42164
4
3336.65861
1
2218.50395
8
2167.74091
3
2798.50051
10
2747.73744
2
30
31
3388.09082
1
3335.66725
4
2219.12496
9
2166.70129
2
2799.15964
10
2746.73599
5
2771.74810
8
31
32
3388.75417
3
3334.67030
2
2219.73898
4
2165.65517
8
2745.72862
-1
2771.52046
10
32
33
3389.41157
5
3333.66781
3
2220.34614
5
2164.60235
1
2800.45924
7
2744.71546
3
33
34
3390.06298
5
3332.65968
1
2220.94635
5
2163.54308
5
2801.09970
12
2771.04226
14
34
35
3390.70834
4
3331.64597
7
2221.53963
6
2162.47718
1
2801.7336
-4
2742.6713
5
2770.79154
9
35
36
3391.34773
15
3330.62650
6
2222.12595
5
2161.40482
6
2802.36146
14
2741.64028
10
36
37
3391.98076
4
3329.60132
8
2222.70538
10
2160.32580
-0
2802.98270
13
2740.60312
3
2770.26699
20
37
38
3392.60776
8
3328.57029
2
2223.27779
7
2159.24045
15
2803.59742
9
2739.55998
6
38
39
3393.22845
4
3327.53349
1
2223.84325
5
2804.20565
8
2738.51075
11
2769.71092
15
39
40
3393.84291
7
2224.40178
5
2157.04975
4
2804.80727
5
2737.45543
2
40
41
3394.45096
2
3325.44247
20
2224.95330
0
2155.94465
2
2805.40253
28
2736.39371
13
41
42
3395.05270
5
3324.38781
4
2225.4978
-11
2154.83315
12
2805.99067
7
2735.3257
-2
2768.8169
-25
42
43
3395.64790
-2
3323.32733
4
2226.0357
15
2806.57229
7
2734.25170
11
2768.50334
12
43
44
3396.23668
-3
3322.26078
1
2226.56636
14
2807.1469
-18
2733.17109
-6
2768.18132
13
44
45
3396.81892
-4
3321.18815
-4
2227.0898
-13
2151.45921
5
2807.71526
14
2732.08409
-26
2767.8509
-11
45
46
3397.39454
-8
3320.10955
6
2808.2762
-9
2730.9912
3
2767.51273
8
46
47
3397.96356
-8
3319.02468
4
2228.1166
17
2149.17760
18
2808.83041
-15
2729.89172
16
47
48
3398.52593
-6
3317.93350
-10
2228.61918
-3
2809.3775
-37
2728.78534
-14
2766.8113
9
48
49
3316.83630
-3
2229.11520
18
2146.8696
-14
2809.9180
-18
2727.67276
-14
49
50
3399.63031
-15
3315.73278
-6
2810.45157
12
2726.55392
14
2766.07669
13
50
51
3400.17243
-6
3314.62280
-19
2230.08575
5
2144.5362
5
2810.97776
12
51
52
3400.70752
-14
3313.50663
-16
2230.56069
12
2143.35963
-2
2811.4966
-11
2724.2958
1
2765.30859
20
52
53
3401.23587
-6
2231.02849
3
2142.17680
11
2812.0081
-51
2723.1566
-17
53
54
3401.75722
-3
3311.25512
-10
2812.51326
-6
54
55
3402.2716
0
3310.11968
-10
2231.9437
41
2139.79141
-1
2813.0109
11
2764.09254
-12
55
56
3402.77895
3
3308.9776
-20
2813.50091
-9
2719.6999
3
56
57
3403.27928
8
3307.8291
-27
2232.83030
10
2137.38038
2
2813.9838
-10
2763.2400
50
57
58
3403.77255
16
3306.67442
-2
2136.16519
1
2717.3615
3
58
59
3404.25874
28
3305.51270
-19
2134.94366
8
2814.9275
-18
59
60
3304.34486
10
2234.10822
1
2133.71569
14
2815.3886
9
60
62
2131.24033
9
2816.2877
-46
62
63
3406.13078
-26
3300.80085
26
2129.99300
2
63
64
2128.73940
9
64
65
3407.0235
-54
2127.47928
3
65
66
3297.19660
18
2126.21290
10
66
67
3407.8880
13
3295.98143
-21
67
68
3408.3082
-70
3294.7605
30
2123.66084
8
68
69
2122.37497
-22
69
70
3292.2975
35
70
71
3409.5285
23
2119.7847
-24
71
73
2117.1694
11
73
74
3287.2904
-40
74
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table X
Observed Line Positions (cm-1) of the 1200–0000, 2000–0000, and 0201–0000 Bands of 14N15N16Oa
J
1200–0000 Band
2000–0000 Band
0201–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
2553.23890
8
3296.2947
-69
0
1
2432.9931
4
2554.0618
-25
2551.57030
4
3297.1235
-60
3294.6243
21
1
2
2429.6450
22
2554.87788
-1
2550.72454
-40
3293.7815
-1
2
3
2428.8029
-36
2549.87229
4
3292.9347
39
3
4
2435.4856
20
2427.96014
17
2556.48748
3
2549.0119
-31
3299.5830
67
3292.0832
71
4
5
2436.3128
28
2427.11484
-6
2557.28122
8
2548.14493
11
3300.39268
28
3291.2263
25
5
6
2437.13785
6
2426.26811
7
2558.06754
9
2547.27013
4
3290.3645
-47
6
7
2437.96124
6
2558.84634
-2
2546.38804
3
3301.9980
-39
7
8
2438.7828
13
2424.56892
-2
2559.61787
-0
3302.7943
3
3288.6292
30
8
9
2439.6020
-24
2423.71684
17
2560.38193
-6
2544.60189
4
3303.5853
-7
3287.75409
21
9
10
2561.13872
3
2543.69776
-2
3286.8743
12
10
11
2422.0066
-4
2561.88792
-7
2542.78643
4
3305.1530
-12
3285.9895
-28
11
12
2442.0495
41
2421.14892
8
2562.62994
7
2541.86773
5
3305.9297
-0
3285.1007
4
12
13
2563.36437
2
2540.94174
7
3306.7013
-7
13
14
2564.09130
-10
2540.00830
-4
3283.3082
3
14
15
2418.56412
9
2564.81105
2
2539.06771
-1
3308.2297
-12
3282.40485
11
15
16
2445.2827
-2
2565.5231
-14
2538.11981
1
3281.49654
5
16
17
2446.0855
-23
2416.83118
11
2566.22805
2
2537.16457
-2
3309.73805
-9
3280.58325
-13
17
18
2415.9614
-18
2566.92544
6
2536.20210
0
3310.4843
-33
3279.66518
-19
18
19
2415.09019
17
2567.61540
9
2535.23239
7
3311.2257
-25
3278.7423
-13
19
20
2414.2163
-9
2568.2978
0
2534.25528
-0
3311.9622
15
3277.8144
-13
20
21
2413.34065
3
2568.97281
-5
2533.27099
2
3276.8815
-12
21
22
2450.0660
-13
2412.46278
9
2569.64044
-3
2532.27943
2
3313.4186
22
3275.94370
4
22
23
2450.8551
15
2411.58271
16
2570.30072
7
2531.28049
-10
23
24
2451.6413
7
2410.70033
16
2570.95335
-4
2530.27454
2
3314.8532
3
3274.0523
-12
24
25
2452.4250
10
2409.81568
18
2571.59872
4
2529.26119
-2
3315.5623
-6
25
26
2408.92870
20
2572.2365
-3
2528.24060
-6
3316.2654
-60
3272.1404
-5
26
27
2453.9847
45
2408.03919
8
2527.21281
-8
3316.9640
-2
27
28
2454.7595
-30
2407.1473
0
2573.48982
-7
2526.17779
-11
3317.6567
32
3270.20721
-15
28
29
2406.25309
8
2574.10548
8
2525.13566
-3
3318.3436
59
3269.2329
12
29
30
2405.35626
7
2574.71344
-1
2524.08626
-2
3268.2525
-28
30
31
2404.4569
11
2575.31404
-2
2523.02971
4
3319.6993
45
31
32
2403.5551
33
2575.90722
1
2521.96586
-1
3266.2769
63
32
33
2458.59409
15
2402.65013
6
2520.89481
-7
3265.2795
-18
33
34
2401.7425
-13
2519.81667
-5
3321.6881
-5
3264.27761
16
34
35
2460.1058
-30
2577.64199
3
2518.73137
-2
35
36
2399.9194
6
2578.20532
2
2517.63889
-0
36
37
2399.0035
12
2516.53932
7
3323.6219
-76
3261.2367
26
37
38
2398.0845
2
2579.30966
3
2515.43245
-1
3260.2116
44
38
39
2463.0912
37
2397.1622
-37
2579.85064
2
2514.31855
2
39
40
2396.23771
11
2513.19751
3
3325.50052
-28
3258.1432
31
40
41
2580.91027
3
2512.0691
-22
3257.1000
20
41
42
2465.2931
29
2394.3783
1
2581.4286
-28
2510.9341
6
42
43
2393.4440
16
2581.94007
1
2509.79156
-10
3254.9959
41
43
44
2466.7431
62
2392.5058
-33
2508.64228
8
44
45
2467.4616
-5
2391.5651
-0
2582.94012
2
2507.4854
-25
3252.8672
49
45
46
2468.1769
-6
2390.62085
14
2583.42892
-4
2506.32211
7
3329.0817
-57
3251.7933
26
46
47
2389.6724
-51
2583.9104
3
2505.15136
-0
3329.6560
2
47
48
2469.5959
5
2388.7212
-45
2584.3843
-5
2503.97366
2
3249.6268
-16
48
49
2584.85099
10
2502.78889
1
3248.5349
42
49
50
2386.8089
31
50
51
2471.6941
2
51
52
2586.20593
0
2499.19257
10
52
53
2497.97967
-0
53
54
2587.07217
-1
2496.75980
-9
54
55
2587.49421
3
2495.5330
-13
55
56
2494.2994
-2
56
59
2589.1082
5
2490.5567
1
59
60
2589.49319
2
2489.2954
12
60
61
2488.0268
-19
61
62
2486.7518
-3
62
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XI
Observed Line Positions (cm-1) of the 1200–0000, 2000–0000, and 0201–0000 Bands of 15N14N16Oa
J
1200–0000 Band
2000–0000 Band
0201–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O - C
P Branch
O – C
0
0
1
2438.8148
-12
2533.72235
1
3335.3445
48
1
2
2438.0034
-21
2536.92457
-11
2532.90666
12
3332.1152
28
2
3
2442.84754
6
2437.1909
19
2537.71009
6
2532.08470
3
3
4
2443.6488
-36
2436.3761
-13
2538.48925
-5
2531.25674
1
3330.4710
-18
4
5
2444.44926
6
2539.26245
-1
2530.42264
-8
3338.4952
18
5
6
2445.2473
-29
2434.74247
-4
2540.02948
-4
2529.58254
-10
3339.2703
-19
3328.80832
33
6
7
2446.04450
17
2433.92322
-4
2540.79048
0
2528.73629
-23
3340.0407
-34
3327.96925
15
7
8
2446.83944
5
2541.54540
6
2527.88439
5
3340.8065
-13
3327.1252
-14
8
9
2447.63274
-3
2432.27994
-3
2542.29409
-0
2527.02612
-0
3341.5673
1
3326.27661
-9
9
10
2448.4244
-4
2431.45591
-2
2543.03667
-8
2526.16189
2
10
11
2449.2142
-19
2543.77332
2
2525.29159
0
3343.0736
7
11
12
2450.00264
4
2429.80299
1
2544.50372
-3
2524.41519
-10
3343.8190
-14
3323.70142
-4
12
13
2450.78907
3
2428.9740
-7
2545.22810
0
2523.53311
13
3344.5595
-21
13
14
2451.57370
-1
2428.14345
-6
2522.64449
-17
3345.2954
18
3321.9602
12
14
15
2546.65856
5
15
16
2453.1374
-20
2426.4774
-2
2547.36459
2
2520.85011
5
3320.1986
-35
16
17
2548.06454
-0
2519.94376
-4
3319.3110
6
17
18
2454.69419
12
2424.80449
-11
2548.75846
3
2519.03176
19
3318.41802
8
18
19
2455.46956
10
2423.96549
-13
2549.44618
-6
2518.11338
-1
3348.8957
-13
3317.51995
1
19
20
2456.24309
17
2550.12802
5
2517.18926
-1
3349.6001
-28
20
21
2550.80359
-3
2516.25919
-3
3350.2996
-7
3315.7092
37
21
22
2421.43804
-16
2551.47322
1
2515.32328
3
3350.9936
-7
22
23
2458.55149
11
2420.59202
-15
2514.38139
1
23
24
2459.31680
-0
2552.79430
10
2513.43360
-2
3352.3655
-15
3312.9539
-20
24
25
2460.08024
11
2418.89464
1
2553.44566
3
2512.48000
1
3353.0436
3
3312.0254
-21
25
26
2418.04292
-16
2554.09102
1
2511.52049
0
3353.7160
-5
26
27
2417.18943
-21
2554.73041
5
2510.55522
8
3354.3834
33
3310.1530
-10
27
28
2462.3573
6
2416.33414
-15
2555.36366
-3
2509.58379
-17
3355.0444
-18
3309.2094
38
28
29
2463.11182
-5
2415.4771
11
2555.99102
2
2508.60686
-10
3308.25966
-4
29
30
2463.86429
6
2414.61780
7
2556.61237
6
3307.3054
31
30
31
2464.61430
1
2413.7564
-6
2557.2273
-32
2506.63562
3
3356.9961
37
3306.3454
24
31
32
2465.3624
39
2412.8930
-17
2557.83702
7
2505.64129
4
3357.6351
27
3305.3798
-10
32
33
2412.02792
9
2558.44029
-2
2504.64116
1
3358.2679
-33
3304.4093
4
33
34
2466.8500
-26
2411.16044
5
2559.03782
11
2503.63533
-1
3358.8958
-8
3303.4332
-1
34
35
2467.59087
15
2410.29093
9
2559.62909
-8
2502.62379
-2
3302.4519
18
35
36
2468.3285
-17
2409.4189
-24
2560.21476
7
3301.4646
-16
36
37
2408.54526
0
3360.7442
26
3300.4720
-29
37
38
2469.79702
11
2407.66919
3
2561.36802
2
2499.55514
-4
3361.3480
-18
3299.4747
43
38
39
2470.5271
-1
2406.79096
15
2561.9355
-32
2498.52099
-4
3361.9463
-17
3298.4707
3
39
40
2405.9105
32
40
41
2471.97950
4
2405.02733
10
2563.0536
-26
2496.4357
-24
3363.1250
3
3296.4465
-8
41
42
2472.70159
6
2563.60417
6
3363.7050
-11
42
43
2473.42080
-1
2403.25413
-11
2564.14869
11
2494.2856
-7
3364.2795
39
43
44
2474.1369
-34
2402.36419
6
2564.6874
20
2493.26680
9
3293.3676
-11
44
45
2401.4718
24
2492.1992
-11
3365.4081
-42
45
46
2475.5619
49
2400.5763
-20
2491.1265
4
3365.9635
-34
3291.28598
-21
46
47
2399.6788
-12
2566.26852
-5
2490.0483
10
3366.5133
45
47
48
2476.97389
18
2398.7791
33
2488.96459
5
3367.0551
-41
3289.1809
-30
48
49
2477.67529
-1
2397.87619
18
2567.2940
-23
2487.8753
-21
3288.1202
40
49
50
2396.9706
-3
2567.7985
-6
3368.1214
-17
3287.0529
48
50
51
2396.0622
-37
2485.68166
16
3285.9792
17
51
52
2395.1516
-21
2484.5766
2
52
53
2394.2380
-31
2569.27795
11
2483.4665
8
53
54
2481.13608
17
2393.3218
-23
2569.7600
20
54
55
2392.4028
-14
2570.2363
6
55
56
2482.4976
30
2391.4812
19
2570.70711
-8
2480.1051
20
56
57
2483.1728
-14
57
58
2483.8453
16
2571.6327
-4
58
59
2572.0874
-2
59
60
2572.53685
11
60
61
2474.4013
21
61
62
2573.4194
-9
2473.2457
19
62
63
2573.8528
-18
63
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XII
Observed Line Positions (cm-1) of the 1200–0000, 2000–0000, and 0201–0000 Bands of 14N218Oa
J
1200–0000 Band
2000–0000 Band
0201–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
2412.29589
-4
2491.9727
-15
3345.1896
-11
0
1
2413.08329
9
2410.71559
3
2492.75344
4
2490.39584
-1
3343.6125
17
1
2
2409.92254
7
2493.52864
1
2489.5995
11
3342.8162
-4
2
3
2414.65206
17
2409.12739
-6
2494.29854
-1
2488.7974
-25
3347.5189
22
3342.0150
-22
3
4
2415.43324
-5
2408.3302
-29
2495.06320
4
2487.99065
5
3348.2854
31
4
5
2416.21274
2
2407.5313
-31
2495.82234
-12
2487.17829
2
5
6
2416.99014
-2
2406.73078
-1
2496.57637
-8
2486.36075
8
3349.8027
-27
6
7
2417.76566
5
2405.92809
4
2497.32521
8
3350.5540
-42
3338.76184
-1
7
8
2418.5392
16
2405.12331
-5
2498.06851
2
3351.3010
13
3337.93607
-10
8
9
2419.31044
-1
2404.31664
-10
2498.80654
-2
2483.87626
-0
3337.10564
8
9
10
2420.07989
6
2403.50808
-9
2499.53924
-8
2483.0374
-23
3352.77895
28
10
11
2420.8468
-35
2402.69762
-4
2500.26674
-5
2482.19380
4
3353.5104
40
11
12
2421.61249
8
2401.88512
-6
2500.98909
13
2481.34471
4
3354.2363
4
3334.58400
-3
12
13
2401.07064
-10
2501.70594
9
2480.49039
1
3354.9575
8
3333.73361
2
13
14
2423.13659
-5
2400.2542
-13
2502.41754
8
3355.67333
-15
3332.87820
2
14
15
2423.89566
8
2399.43591
-2
2503.12385
6
2478.7663
10
3356.3842
-20
3332.01769
-9
15
16
2398.61550
-4
2503.82492
5
2477.89646
10
3357.0903
12
16
17
2397.79308
-6
2504.52059
-10
2477.02143
7
3357.79066
-12
3330.28185
-12
17
18
2426.15949
7
2396.96868
-4
2505.21124
-3
2476.14119
-3
3358.48632
14
18
19
2426.90976
12
2396.14222
-4
2505.89661
-0
2475.25606
10
3359.17619
-17
19
20
2395.31377
1
2506.57671
-3
3359.8615
21
3327.64047
-4
20
21
2428.40334
1
2394.48313
-5
2507.25154
-12
2473.47019
3
21
22
2393.65051
-2
2507.92139
1
2472.5698
15
3361.21514
-16
3325.85422
2
22
23
2392.81581
4
2508.58584
-9
2471.66422
12
3361.8844
8
3324.95330
-8
23
24
2391.97889
-0
2470.75354
1
3362.54797
-2
3324.0474
-4
24
25
2431.36307
8
2391.13984
-3
2509.89962
6
2469.83792
-3
3363.20619
-7
3323.13625
-9
25
26
2390.29870
1
2468.91754
14
3363.85908
-4
3322.2202
13
26
27
2432.82844
-6
2389.45532
-1
2511.19266
-1
2467.99194
4
3364.50639
-13
3321.29854
-6
27
28
2433.55748
-9
2388.60976
-1
2511.83164
6
2467.06146
-1
28
29
2387.76194
-3
2466.12606
-8
3365.7850
16
3319.4401
11
29
30
2435.00820
4
2386.91187
-5
2513.09415
-6
2465.18592
-2
3366.41557
-12
30
31
2435.72964
1
2386.05953
-7
2513.71804
4
2464.24092
3
3367.0408
-16
3317.5603
-1
31
32
2385.20496
-1
2514.33686
8
32
33
2437.1645
-21
2384.34801
-1
2514.95055
-3
2462.3362
-19
33
34
2437.8779
-35
2383.48863
-7
2515.5596
16
2461.37706
7
3368.8828
-9
3314.7011
28
34
35
2438.5889
-19
2382.62694
-7
2516.16344
7
2460.41281
-7
3369.48543
-3
3313.7370
11
35
36
2439.29739
22
2381.76284
-6
3370.08230
4
36
37
2440.0026
13
2380.89642
7
2517.35666
4
2458.47066
2
3370.6731
-15
3311.7925
-22
37
38
2380.02728
-4
2517.94599
1
3371.2588
40
3310.8126
19
38
39
2379.15584
4
2518.5306
5
39
40
2442.10128
2
2378.28177
3
2519.11042
5
2455.5228
2
3308.8352
-1
40
41
2377.40527
15
2454.5309
-23
3372.9787
28
41
42
2443.48586
5
2376.5256
-30
2520.25592
5
42
43
2444.17354
0
2375.6437
-41
2520.8214
-23
2452.5346
10
3374.09518
2
3305.8274
-6
43
44
2444.8581
-12
3374.6441
-33
3304.8137
13
44
45
2445.53954
-26
2521.93934
-5
2450.52054
10
45
46
2372.98234
-7
2449.50697
-1
3375.72462
4
46
47
3301.7370
-51
47
48
2447.56564
19
2371.19414
-9
2523.58236
11
2447.4672
-27
3376.7804
48
48
49
2448.23424
7
2524.1213
24
2446.44169
17
3299.6576
-22
49
50
2524.6559
36
2445.4115
-2
50
51
2449.56159
-1
2525.18598
24
2444.37744
-8
51
52
2450.22030
8
2525.71173
-1
2443.33959
2
52
53
2450.87536
-4
2526.23368
11
53
54
2526.75134
4
54
55
2527.26520
22
2440.20280
10
55
56
2452.8202
41
56
57
2438.0932
29
57
58
2454.0980
-2
2528.78256
13
2437.0328
15
58
59
2454.7315
-8
2529.2804
-19
59
60
2529.7750
-5
2434.9019
12
60
61
2433.8314
8
61
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XIII
Observed Line Positions (cm-1) of the 1200–0000, 2000–0000, and 0201–0000 Bands of 14N217Oa
J
1200–0000 Band
2000–0000 Band
0201–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
2525.4796
-19
0
1
2434.9140
13
2526.2812
30
1
2
2438.15652
-5
2434.09892
16
2527.0760
9
2
3
2438.9633
53
2522.2140
-21
3357.2107
-16
3351.5520
6
3
4
2439.76734
17
2432.4635
28
2528.64759
4
3357.9988
-75
4
5
2440.5698
5
2431.64281
1
2529.4240
-18
5
6
2441.37013
-37
2430.8202
-41
2530.1944
-30
2519.7011
11
6
7
2442.1696
19
2530.95914
6
2518.85127
19
3360.3358
-12
3348.2103
10
7
8
2429.1707
-21
2531.71734
-1
2517.99514
4
3361.1055
74
8
9
2443.76139
-25
2532.4692
-29
2517.1329
-16
9
10
2533.21554
4
3345.6519
-47
10
11
2426.6830
4
2533.95534
-6
2515.39074
-7
3363.3809
-42
3344.7900
6
11
12
2446.13542
-33
2425.8502
15
2534.6890
-18
2514.5107
8
3343.9223
-29
12
13
2446.92304
-21
2425.01522
-9
2535.41688
4
2513.6244
-0
13
14
2447.70849
-28
2424.1787
-5
2512.73227
10
3365.6122
-37
14
15
2536.85387
5
3366.3461
-7
3341.2913
33
15
16
2537.56315
-1
3367.0747
3
16
17
2450.0530
-24
2421.65788
-5
2538.26653
14
2510.0193
-16
17
18
2450.8303
-34
2420.8136
-30
2538.96330
-23
2509.10324
-2
3368.5160
-23
3338.6148
3
18
19
2451.6055
-42
2539.65461
3
2508.1812
10
19
20
2507.25309
10
3369.9374
37
3336.8057
1
20
21
2418.2700
-29
3370.6398
24
3335.8943
69
21
22
2417.4181
-42
2505.3791
10
3371.3364
-41
3334.9769
43
22
23
2504.4331
-4
3372.0289
18
3334.0540
-26
23
24
2455.44969
-9
2415.70894
-4
2543.0185
-28
3372.7153
4
24
25
2543.67351
4
2502.5235
-29
3373.3965
13
3332.1947
25
25
26
2413.9915
18
2501.5602
-12
26
27
2413.12946
8
2544.96487
9
2500.5912
18
27
28
2458.4839
-4
2412.2651
-23
2499.61592
1
28
29
2459.2365
-2
2411.3996
44
2546.23231
24
2498.63497
-3
29
30
2459.9864
-21
2546.85675
1
30
31
2460.7343
0
2409.66059
27
2547.47542
-4
2496.65581
-6
31
32
2461.4793
-13
32
33
2462.2220
0
2407.91277
12
2548.6952
16
2494.6536
-30
3378.6423
-63
33
34
2407.03574
30
2493.6442
-3
3379.2720
-36
34
35
2463.6998
45
2406.1557
-24
35
36
2464.4345
44
2405.2742
7
2550.4798
-30
2491.6081
-0
36
37
2465.1665
42
2404.3905
51
2551.06334
-3
2490.5815
-6
37
38
2465.8948
-58
2551.64084
4
2489.5493
-21
38
39
2402.6147
12
2552.21229
-12
2488.5123
44
39
40
2467.3453
-39
2552.7784
18
2487.46872
4
40
41
2553.3384
15
2486.41992
-7
41
42
2399.9336
30
2553.8927
17
2485.36574
-9
42
43
2469.5003
35
2399.0343
-30
2554.4410
-8
2484.3060
-22
43
44
2470.2124
13
2554.98386
-7
2483.2410
-19
44
45
2482.17074
-5
45
46
2471.6283
21
2556.05254
-8
2481.09504
1
46
47
2472.3319
36
47
48
2473.0321
11
2557.0989
6
2478.92764
1
48
49
49
50
2558.1229
8
2476.7390
-26
50
51
2558.62654
-2
51
O - C are the observed minus the computed frequencies in cm-1 × 105.
Table XIV
Observed Line Positions (cm-1) of the 0441–0440, 0441–0330, 1530–0330, 2330–0330, 0531–0330, and 1331–0330 Bands of 14N216Oa
Line
Band
Position
O – C
Line
Band
Position
O – C
Line
Band
Position
O – C
R 6
0441–0440
2173.1653
-5
R22
2330–0330
2615.3896
-8
P13
0531–0330
3290.8065
7
R 8
0441–0440
2174.4379
-10
R23
2330–0330
2616.0861
77
P15
0531–0330
3288.9790
-10
R18
0441–0440
2182.2026
29
R24
2330–0330
2616.7748
-4
P18
0531–0330
3286.1979
-26
P11
0441–0440
2157.82565
18
R26
2330–0330
2618.1361
23
P19
0531–0330
3285.2605
-4
P12
0441–0440
2156.9108
-15
R27
2330–0330
2618.8072
-5
P20
0531–0330
3284.3169
-72
P13
0441–0440
2155.9899
2
R28
2330–0330
2619.4723
-27
P21
0531–0330
3283.3689
-50
P15
0441–0440
2154.1278
-27
R29
2330–0330
2620.1318
-2
P22
0531–0330
3282.4157
-17
P16
0441–0440
2153.1871
-23
R31
2330–0330
2621.4323
13
P23
0531–0330
3281.4569
-16
P17
0441–0440
2152.23999
-7
R32
2330–0330
2622.0732
-6
P24
0531–0330
3280.4929
-6
P20
0441–0440
2149.3592
13
R34
2330–0330
2623.3373
-1
P25
0531–0330
3279.5237
11
P21
0441–0440
2148.3856
-14
R35
2330–0330
2623.9603
4
P26
0531–0330
3278.5486
-36
P23
0441–0440
2146.4198
17
R37
2330–0330
2625.1881
3
P27
0531–0330
3277.5694
32
P27
0441–0440
2142.4100
2
R38
2330–0330
2625.7928
-12
P28
0531–0330
3276.5844
43
P29
0441–0440
2140.3662
-16
R40
2330–0330
2626.9845
-5
P30
0531–0330
3274.5986
49
P31
0441–0440
2138.2965
5
R41
2330–0330
2627.5713
-3
P31
0531–0330
3273.5981
69
R 8
0441–0330
2765.4281
93
R43
2330–0330
2628.7266
-25
P32
0531–0330
3272.5921
52
P17
0441–0330
2741.7422
-49
R44
2330–0330
2629.2955
-10
P34
0531–0330
3270.5652
58
P19
0441–0330
2739.869
149
R46
2330–0330
2630.4154
30
P35
0531–0330
3269.5425
-109
P22
0441–0330
2737.012
-132
R48
2330–0330
2631.5105
-12
P36
0531–0330
3268.5158
-180
P24
0441–0330
2735.0836
47
R50
2330–0330
2632.5821
-11
R 6
1331–0330
3461.1737
57
P25
0441–0330
2734.1100
14
P 4
2330–0330
2594.3115
-12
R 7
1331–0330
3461.9366
51
Q12
0441–0330
2756.363
4
P 7
2330–0330
2591.6969
-19
R11
1331–0330
3464.8897
-8
Q16
0441–0330
2756.0415
6
P10
2330–0330
2589.0284
-0
R12
1331–0330
3465.6036
-6
Q17
0441–0330
2755.9467
-44
P12
2330–0330
2587.2191
-18
R14
1331–0330
3467.00206
11
Q18
0441–0330
2755.84786
54
P14
2330–0330
2585.3865
28
R18
1331–0330
3469.68061
-1
Q20
0441–0330
2755.6310
-20
P15
2330–0330
2584.4606
-13
R21
1331–0330
3471.58636
-4
Q24
0441–0330
2755.134
14
P18
2330–0330
2581.6484
-10
R22
1331–0330
3472.2021
10
Q25
0441–0330
2754.9959
-9
P26
2330–0330
2573.8884
-9
R24
1331–0330
3473.4036
-8
R 5
1530–0330
2455.7065
-1
P29
2330–0330
2570.8812
-22
R25
1331–0330
3473.9898
3
R 8
1530–0330
2458.1744
-11
P31
2330–0330
2568.8474
-11
R27
1331–0330
3475.13265
21
R 9
1530–0330
2458.99248
0
Q 3
2330–0330
2597.6771
23
R28
1331–0330
3475.6892
18
R10
1530–0330
2459.8086
50
Q 4
2330–0330
2597.6523
-34
R29
1331–0330
3476.2359
14
R12
1530–0330
2461.43219
-11
Q 5
2330–0330
2597.6222
-16
R30
1331–0330
3476.77295
29
R14
1530–0330
2463.0472
12
Q 6
2330–0330
2597.5862
17
R31
1331–0330
3477.2999
17
R18
1530–0330
2466.2479
-42
Q 8
2330–0330
2597.4946
-63
R32
1331–0330
3477.8173
35
R28
1530–0330
2474.0850
-33
Q11
2330–0330
2597.3143
59
R33
1331–0330
3478.3240
-33
R32
1530–0330
2477.1524
-56
Q12
2330–0330
2597.2415
36
R35
1331–0330
3479.30972
14
P 5
1530–0330
2446.4771
-48
Q18
2330–0330
2596.6799
67
R36
1331–0330
3479.7878
36
P 7
1530–0330
2444.7690
-52
R 3
0531–0330
3305.4741
18
R37
1331–0330
3480.2553
-16
P 8
1530–0330
2443.9121
4
R 4
0531–0330
3306.2879
-39
R38
1331–0330
3480.7138
16
P 9
1530–0330
2443.0525
19
R 5
0531–0330
3307.098
76
R40
1331–0330
3481.6017
122
P10
1530–0330
2442.1904
12
R 6
0531–0330
3307.9012
41
P 5
1331–0330
3451.2531
-45
P11
1530–0330
2441.3262
23
R 8
0531–0330
3309.4917
7
P 6
1331–0330
3450.36311
-24
P12
1530–0330
2440.4594
0
R10
0531–0330
3311.0609
10
P 7
1331–0330
3449.4633
-9
P20
1530–0330
2433.446
0
R11
0531–0330
3311.8370
-24
P 8
1331–0330
3448.5535
-18
P21
1530–0330
2432.5591
-14
R12
0531–0330
3312.6080
-25
P 9
1331–0330
3447.63432
11
P26
1530–0330
2428.0924
-31
R16
0531–0330
3315.637
-88
P12
1331–0330
3444.8172
-18
P27
1530–0330
2427.1928
-4
R17
0531–0330
3316.381
-147
P17
1331–0330
3439.92835
17
P33
1530–0330
2421.7481
22
R18
0531–0330
3317.1192
-80
P19
1331–0330
3437.90449
-8
P35
1530–0330
2419.9154
-9
R19
0531–0330
3317.8526
-28
P21
1331–0330
3435.8419
-33
R 3
2330–0330
2601.0177
-32
R20
0531–0330
3318.5810
70
P22
1331–0330
3434.79652
-3
R 4
2330–0330
2601.8291
3
R21
0531–0330
3319.3027
44
P24
1331–0330
3432.67642
22
R 6
2330–0330
2603.4330
1
R24
0531–0330
3321.4352
-19
P25
1331–0330
3431.6016
5
R 8
2330–0330
2605.0126
-3
R25
0531–0330
3322.1349
-62
P26
1331–0330
3430.5177
44
R 9
2330–0330
2605.7930
-35
R27
0531–0330
3323.5205
103
P29
1331–0330
3427.2056
-101
R10
2330–0330
2606.5679
-9
R28
0531–0330
3324.2037
40
P30
1331–0330
3426.0837
-13
R12
2330–0330
2608.0995
-46
R35
0531–0330
3328.8403
-6
P31
1331–0330
3424.9512
-25
R14
2330–0330
2609.6055
-28
R37
0531–0330
3330.1192
84
P38
1331–0330
3416.7560
-56
R15
2330–0330
2610.3499
-14
P 6
0531–0330
3297.0345
67
P39
1331–0330
3415.54721
-43
R16
2330–0330
2611.0882
-2
P 7
0531–0330
3296.1603
4
P42
1331–0330
3411.8632
-56
R17
2330–0330
2611.8202
-12
P10
0531–0330
3293.5080
59
P45
1331–0330
3408.0941
-24
R19
2330–0330
2613.2660
-29
P11
0531–0330
3292.6127
28
R21
2330–0330
2614.6879
-6
P12
0531–0330
3291.7122
10
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XV
Observed Line Positions (cm-1) of the 1001–0000, 1001–1000 and 1001–0110 Bands of N216Oa
J
1001–0000 Band
1001–1000 Band
1001–0110 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q–Branch
O – C
0
3481.64677
-0
2196.74345
2
0
1
3479.98123
5
2195.08145
10
2893.6958
11
1
2
3483.27055
1
3479.13275
4
2198.37777
3
2194.23990
-1
2894.50181
14
2892.01404
-23
2
3
3484.06677
3
3478.27385
5
2199.18445
-2
2193.39157
4
2895.29704
17
3
4
3484.85249
2
3477.40451
6
2199.98423
-1
2192.53624
1
2896.08125
-1
2891.92763
-2
4
5
3485.62771
-2
3476.52471
4
2200.77705
-1
2191.67395
-5
2896.85472
-13
2887.75173
-7
2891.86597
16
5
6
3486.39251
0
3475.63450
4
2201.56288
-3
2190.80488
2
2897.61762
-1
2886.8598
21
2891.79159
-2
6
7
3487.14682
1
3474.73388
5
2202.34183
4
2189.92877
-4
2898.36964
4
2885.95676
14
2891.70524
20
7
8
3473.82282
4
2203.11367
-3
2189.04585
1
2899.11074
-2
2885.04298
8
2891.60608
-3
8
9
3488.62396
-2
3472.90135
4
2203.87867
4
2188.15594
-3
2899.84104
-7
2884.11839
-5
2891.49481
-1
9
10
3489.34681
-3
3471.96944
-0
2187.25919
-1
2900.56061
-2
2883.18322
-2
2891.37118
2
10
11
3490.05920
0
3471.02715
-1
2205.38756
-0
2186.35551
-2
2882.23721
-9
2891.23509
-6
11
12
3490.76105
-2
3470.07447
-1
2206.13152
-3
2185.44495
-1
2901.96722
1
2881.28057
-5
12
13
3491.45242
-2
3469.11138
-3
2206.86852
-2
2184.52750
-1
2902.65416
-10
2880.31324
0
2890.9257
-36
13
14
3492.13329
-2
3468.13796
1
2207.59852
-1
2183.60316
-2
2903.33042
-6
2879.33512
-1
2890.75304
6
14
15
3492.80364
-4
3467.15407
-4
2208.32155
2
2903.99572
-16
2890.5674
-15
15
16
3493.46351
-3
3466.15983
-6
2209.03751
-1
2181.73376
-11
2904.65034
-9
2877.3467
-8
2890.36981
3
16
17
3494.11294
4
3465.15526
-4
2209.74650
-1
2180.78870
-4
2905.29412
-4
2876.3365
-6
2890.1595
-16
17
18
3464.14028
-6
2210.44850
2
2179.83704
-4
2905.92692
-13
2875.31557
-7
2889.93716
-3
18
19
3495.38005
-2
3463.11500
-2
2211.14343
-1
2178.87833
-5
2906.54896
-14
2874.28413
9
19
20
3495.99785
-5
3462.07928
-7
2211.83133
-5
2177.91274
-9
2907.16022
-9
2873.24167
-10
2889.45515
-11
20
21
3496.60521
1
3461.03329
-4
2212.51225
-4
2176.94035
-8
2907.76071
3
2872.18872
-10
2889.19571
-8
21
22
3459.97691
-6
2213.18620
2
2175.96111
-6
2908.35015
-7
2871.12501
-20
2888.92399
-0
22
23
3497.78823
-1
3458.91025
-3
2213.85307
3
2174.97512
5
2908.9288
-11
2870.05089
-6
2888.63978
-10
23
24
3498.36400
2
3457.83322
-4
2214.51290
4
2173.98219
6
2909.49674
-2
2868.96586
-17
2888.34337
-6
24
25
*3498.92928
8
3456.74590
-1
*2215.16560
-5
2172.98240
5
*2910.05380
3
2867.8703
-18
2888.03460
-8
25
26
*3499.48408
19
3455.64825
0
*2215.81162
23
2171.97585
11
*2910.60019
25
2866.76440
10
*2887.71369
7
26
27
*3500.02968
162
*3454.54036
8
*2216.45175
166
*2170.96235
4
*2911.13693
166
*2865.64729
-20
*2887.38026
1
27
28
*3500.56140
-30
*3453.42219
18
*2217.08147
-26
*2169.9423
25
*2911.65942
-34
*2887.03619
161
28
29
*3501.08469
-12
*3452.29511
166
*2217.70636
3
*2168.91666
169
*2912.17335
-3
*2886.6763
-31
29
30
3501.59735
-4
*3451.15429
-31
2218.32383
-4
*2167.88090
-18
2912.67622
1
*2886.3060
-35
30
31
3502.09948
4
*3450.00540
-7
2218.93440
6
*2166.84033
-5
2913.1681
2
2885.92365
-16
31
32
3502.59098
2
3448.84602
-5
2219.53784
8
2165.79285
-2
2913.64937
6
2859.90427
-15
2885.52895
-5
32
33
3503.07208
13
3447.67642
1
2220.13422
12
2164.73862
6
2914.11972
11
2858.72399
-7
2885.12194
3
33
34
*3503.54265
24
3446.49658
9
*2220.72346
8
2163.67756
10
*2914.57914
7
2857.53322
7
2884.7026
5
34
35
*3504.00265
30
3445.30645
12
*2221.30575
17
2162.60972
15
2856.33172
4
*2884.27100
6
35
36
*3504.45213
38
*3444.10613
20
*2221.88088
17
*2161.53515
26
*2915.46606
56
*2855.12000
32
*2883.82741
33
36
37
*3504.89110
48
*3442.89555
26
*2222.44922
47
*2160.45361
18
*2915.8925
3
*2853.89730
16
*2883.37137
40
37
38
*3505.31960
63
*3441.67485
41
*2223.01037
66
*2159.36545
26
*2916.3091
48
*2852.66451
41
*2882.9035
87
38
39
*3505.73759
81
*3440.44388
50
*2223.5640
41
*2158.27072
54
*2916.7150
105
*2851.4211
56
*2882.4231
105
39
40
*3506.14516
109
*3439.20274
63
*2224.11145
108
*2157.1690
60
*2917.1095
104
*2850.1670
51
40
41
*3506.54224
140
*3437.95142
77
*2224.65150
144
*2156.06066
79
*2917.4932
105
*2848.9026
64
41
42
*3506.92911
203
*3436.69022
122
*2225.18466
201
*2154.94570
113
*2917.8664
137
*2847.6275
55
*2880.90851
146
42
43
*3507.30598
318
*3435.41868
150
*2225.71158
344
*2153.82399
147
*2918.2300
289
*2846.3429
141
*2880.3793
164
43
44
*3507.67522
721
*3434.13726
206
*2226.23378
725
*2152.69580
207
*2918.5851
671
*2879.8393
323
44
45
*3507.99683
-2586
*3432.84628
321
*2226.71210
-2572
*2151.56147
328
*2918.8926
-2612
*2843.7425
326
*2879.2902
788
45
46
*3508.36177
-510
*3431.54803
724
*2150.42309
717
*2919.2425
-595
*2842.4303
783
46
47
*3508.69782
-271
*3430.20249
-2589
*2149.24121
-2570
47
48
*3509.02178
-190
*3428.90075
-510
*2228.22690
-211
*2148.10636
-482
*2839.7527
-504
48
49
*3509.33503
-130
*3427.57060
-261
*2146.94583
-289
49
50
*3509.63750
-98
*3426.22864
-184
*2145.77773
-182
50
51
*3509.92929
-84
*2144.60210
-157
*2835.6815
-132
51
52
*3510.21067
-62
*3423.51372
-104
*2230.11758
-3
52
53
*3510.48142
-55
*3422.14100
-81
*2142.23139
-40
53
54
*3510.74175
-41
*3420.75817
-63
*2231.0192
4
*2141.03545
-36
54
55
*3510.99156
-32
*2231.45900
-24
*2139.83280
-33
55
56
*3511.23095
-17
*3417.96247
-24
*2231.89214
-4
56
57
*3511.45972
-18
*3416.54946
-19
*2232.31787
-12
*2137.40750
-24
57
58
3511.67817
-5
*3415.12642
-17
2232.73674
8
58
59
3511.88606
-3
*3413.69339
-16
*2134.95547
-18
59
60
3412.25050
-6
2233.55268
11
2133.71965
4
60
61
3512.27058
7
3410.79759
-2
61
62
3512.44703
-4
3409.33485
11
2234.33998
7
62
63
3512.6134
19
3407.86192
-2
63
64
3512.6898
4
3406.37924
-1
2128.70891
-5
64
65
3512.91438
11
3404.88670
2
2127.43985
15
654
66
3513.04927
6
66
67
3513.17377
1
3401.87195
-0
67
68
3513.28797
2
68
69
3513.39182
4
3398.81787
-5
2122.29670
23
69
70
3513.48520
-5
3397.27612
-8
2120.99420
6
70
71
3513.56850
10
2119.68526
4
71
72.
3513.64120
-5
3394.16342
-6
72
73
3513.7034
-33
73
74
3513.7554
-54
3391.01159
-25
74
75
3513.7973
-67
75
76
3513.8290
-54
3387.8211
-38
76
77
3513.8511
15
77
78
3384.5922
-31
78
82
3513.8050
14
82
83
3376.3531
55
83
84
3513.7149
-37
84
O – C are the observed minus the computed frequencies in cm-1 × 105. The transitions denoted with asterisks are perturbed and were not included in the frequency analysis.
Table XVI
Observed Line Positions (cm-1) of the 1001–0000 Bands of 14N15N16O and 15N14N16Oa
J
14N15N16O
15N14N16O
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
3433.0205
-17
3444.4494
-34
0
1
3433.8383
43
1
2
3442.0202
-40
2
3
3446.78929
4
3
4
3436.22717
3
3447.5491
-5
3440.3515
7
4
5
3437.00287
10
3427.89945
-12
3448.29925
18
3439.50184
-9
5
6
3427.0100
22
3449.0390
-2
3438.64237
-12
6
7
3438.52270
-11
3426.10968
4
3449.76908
9
7
8
3439.26714
-8
3450.48905
7
3436.89394
10
8
9
3440.00132
11
3424.2781
-25
3451.19910
12
3436.00472
9
9
10
3440.7248
1
3423.3471
-3
3451.89923
23
3435.10555
4
10
11
3441.43785
-9
3422.40566
4
*3452.5894
37
11
12
3442.14070
4
3421.45377
-1
*3453.26940
33
3433.27766
12
12
13
3442.83280
-15
*3453.93962
51
*3432.34895
24
13
14
3443.5146
-21
3419.5197
57
*3454.59975
59
*3431.41045
47
14
15
3444.18626
3
3418.53637
5
*3455.24995
73
*3430.46190
53
15
16
3444.84715
-7
3417.54322
1
*3455.89032
104
*3429.50377
89
16
17
3445.4976
-15
3416.53977
-2
*3428.53541
90
17
18
3446.13796
13
3415.52605
-2
*3457.14078
138
18
19
3446.76750
3
3414.50200
-5
*3457.75141
195
*3426.56955
136
19
20
3447.38676
11
3413.46765
-8
*3458.35175
223
*3425.57186
162
20
21
3447.9955
13
3412.42316
3
*3458.94277
319
*3424.5642
176
21
22
3448.59352
-10
3411.3684
15
*3459.5245
486
*3423.54726
245
22
23
3410.30308
-2
*3460.10231
1262
*3422.52052
318
23
24
3449.7586
-14
3409.22762
-5
*3460.63377
-1597
*3421.48506
501
24
25
3450.3252
-39
3408.14192
-5
*3461.1949
-489
*3420.44553
1259
25
26
3450.8820
4
*3461.73736
-248
26
27
3451.42775
-11
3405.9399
11
*3462.2682
-169
*3418.30445
-486
27
28
3451.96324
-3
3404.82330
-3
*3462.7885
-143
*3417.23015
-264
28
29
3452.48803
-17
3403.69644
-17
*3463.29931
-67
*3416.1444
-209
29
30
3453.00274
10
3402.5596
-6
*3463.79938
-64
*3415.04890
-152
30
31
3453.5068
23
3401.41235
-12
*3464.28975
-32
*3413.9436
-97
31
32
3453.99990
-15
3400.25505
-1
*3464.76984
-28
*3412.82853
-43
32
33
3454.48308
7
3465.24012
-5
*3411.70311
-49
33
34
3454.95556
8
3397.90935
-21
34
35
3455.4178
36
3396.72139
-10
3409.42331
-36
35
36
3395.52310
-11
3466.59040
4
36
37
3456.30985
-1
3394.31473
-0
3467.02052
8
3407.10480
-3
37
38
3393.0960
-6
3467.44072
19
38
39
3391.86735
15
3467.8509
27
3404.7472
4
39
40
3390.62803
-12
3468.25081
6
3403.55377
-3
40
41
3457.96875
18
3389.37881
-12
3402.3508
5
41
42
3388.11958
4
3401.13805
1
42
43
3386.85012
13
3469.39125
2
3399.91576
9
43
44
3459.10225
7
3385.57035
7
3469.7514
-4
3398.68385
20
44
45
3384.28052
10
3470.1015
-17
3397.44207
8
45
46
3382.98065
24
46
47
*3460.1412
11
3470.7720
-24
3394.9295
-30
47
48
*3460.4675
115
3380.35033
33
3471.0926
2
48
49
*3460.78215
108
3392.3792
1
49
50
*3461.0865
123
*3377.6794
31
3471.7029
-48
3391.0894
-10
50
51
*3461.3766
-234
*3376.3294
93
3389.79026
3
51
52
*3461.6617
-37
*3374.9687
95
3388.4814
-0
52
53
*3373.5943
-263
3387.16296
-6
53
54
3462.1968
5
*3372.2151
-93
3385.8350
-9
54
55
3473.0562
-6
3384.4978
16
55
56
3369.4242
20
3383.1510
34
56
57
3368.0124
-48
3381.7945
32
57
58
3473.7489
15
58
59
3463.3491
0
59
60
3463.5478
-17
3363.7199
67
3474.1611
31
3377.6682
40
60
61
3474.3518
-14
61
62
3360.8058
-83
3374.8696
5
62
63
3464.0822
82
3359.3354
9
63
64
3357.8541
12
64
65
3356.3622
-46
3370.6013
-11
65
O – C are the observed minus the computed frequencies in cm-1 × 105. Transitions denoted with asterisks are perturbed and were not included in the analysis.
Table XVII
Observed Line Positions (cm-1) of the 1001–0000 Bands of 14N218O and 14N217Oa
J
14N218O
14N217O
J
R Branch
O –C
P Branch
O –C
R Branch
O –C
P Branch
O –C
2
3437.29316
6
3433.38455
5
3459.01650
-15
2
3
3432.57432
-17
3459.7904
22
3
4
3438.79049
1
3453.3231
-20
4
5
3439.52498
-2
3430.92620
-3
3461.3072
-14
3452.4701
-11
5
6
3451.6068
-38
6
7
3440.96566
-3
3450.7337
-54
7
8
3428.38320
-7
3463.5084
9
8
9
3442.36845
-12
3427.51679
-3
3464.2224
38
3448.9588
20
9
10
3443.05598
15
3426.64100
1
3464.92565
-10
3448.0567
78
10
11
3443.7339
27
3425.75580
3
3447.14330
-4
11
12
3444.40195
-2
3424.86110
-8
3446.22095
8
12
13
3445.06095
9
3423.95713
-9
3466.9770
-5
13
14
3445.71035
7
3423.04403
14
3467.6409
5
3444.3464
14
14
15
3422.12120
-2
3468.2947
4
15
16
3421.18923
4
3468.9385
2
3442.4323
15
16
17
3447.60184
2
3420.24794
12
3441.4602
-9
17
18
3448.21359
18
3419.29712
0
3470.1965
33
3440.4787
12
18
19
3448.81575
19
3418.33715
6
3470.81005
3
3439.4875
47
19
20
3449.40827
3
3417.36774
-1
3438.4858
17
20
21
3416.38905
-5
3437.47453
14
21
22
3450.5653
3
3436.45330
-4
22
23
3414.4037
-22
3473.1652
-35
23
24
3451.68428
-22
3413.39730
-11
3473.7295
5
3434.3819
13
24
25
3412.3815
-12
3474.2835
13
25
26
3452.7659
-6
3474.82715
-15
3432.2705
-49
26
27
3453.2922
-33
3410.32220
-9
3475.3613
7
27
28
3453.80982
15
3409.27885
9
3475.88504
-14
3430.1205
-57
28
29
3454.31735
-4
3408.22588
-12
3476.3992
5
3429.0313
-15
29
30
3454.81563
-5
3407.16399
-4
3476.9032
8
3427.9323
23
30
31
3455.30492
36
3406.09290
4
31
32
3405.01260
11
32
33
3478.3552
5
3424.5750
-46
33
34
3456.7149
17
3402.82415
-9
3423.4370
-14
34
35
3479.2733
4
3422.2891
1
35
36
3457.6075
-37
3400.59931
-7
3479.7176
25
3421.13115
-19
36
37
3458.0404
4
37
38
3458.46340
-9
3398.33781
-21
3480.5753
-31
38
39
3397.1938
10
3480.9899
12
3417.6000
4
39
40
3459.2815
-15
3396.04023
-6
*3481.3943
32
40
41
3459.67666
-5
3394.8776
-22
3415.1975
14
41
42
3460.0624
-3
3393.7068
52
*3482.1730
52
42
43
3460.4390
18
3392.5260
25
*3482.5495
271
43
44
*3482.9165
536
*3411.5222
106
44
45
3390.1384
78
45
46
*3483.6066
-336
*3409.0285
626
46
47
*3461.8613
997
*3387.7146
102
*3407.7532
-519
47
48
*3462.1758
-545
*3386.49003
189
*3484.2687
-27
48
49
*3385.26385
1007
*3405.2012
-76
49
50
*3384.0055
-502
50
51
*3382.75633
-204
3485.1834
51
51
52
*3381.4960
-137
3485.4671
-55
52
53
*3380.2266
-92
53
54
3398.6438
9
54
56
3376.3647
-49
56
57
3375.0603
8
57
58
3373.7468
27
58
60
3371.0940
92
60
62
3465.8356
55
62
O – C are the observed minus the computed frequencies in cm-1 × 105. Transitions denoted with asterisks are perturbed and were not included in the analysis.
Table XVIII
Observed Line Positions (cm-1) of the 1111–0110 and 1111–0000 Bands of N216Oa
J
1111(e)–0110(e) Band
1111(f)–0110(f)Band
1111–0000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
Q Branch
O – C
0
4062.0763
-12
0
1
3474.8575
-17
3474.8614
5
4063.62589
-4
1
2
3475.6650
-25
3471.525
23
3475.6710
-7
3471.522
26
2
3
3476.4620
5
3470.666
8
3476.471
30
3470.6619
22
4065.23243
-5
4059.43584
-0
3
4
3477.2497
11
3469.797
18
3477.2604
16
3469.7916
5
4
5
3478.0264
5
3468.917
-49
3478.03965
-5
3468.9115
12
4066.79921
-7
5
6
3468.0277
-22
3478.80900
-7
3468.0212
5
4067.56778
1
6
7
3479.54913
10
3467.1282
8
3479.56840
6
3467.1211
21
4068.32621
-9
7
8
3480.29503
8
3466.2184
29
3480.31752
1
3466.2106
1
4069.07470
-18
8
9
3481.03058
1
3465.2976
-27
3481.05662
4
3465.2905
25
4069.81345
-5
4054.08068
-12
9
10
3481.75589
-2
3464.3674
-2
3481.78554
-1
3464.3594
-50
4070.54213
-3
10
11
3463.4269
14
3482.50449
7
3463.4196
8
4071.26087
1
4061.44152
-3
11
12
3483.17570
2
3462.4758
-10
3483.21322
4
3462.4692
7
4071.96961
2
4061.34357
-18
12
13
3483.87012
0
3461.5149
5
3483.91177
-6
3461.5089
16
4050.31284
-24
13
14
3484.55423
-2
3460.5438
20
3484.60037
-0
3460.539
65
4073.35706
-7
4049.34642
-6
4061.12372
-0
14
15
3485.22803
-5
3459.5623
14
3485.27869
-11
3459.558
3
4074.03591
-3
4048.3697
-32
15
16
3485.89155
-4
3458.570
-55
3485.94717
5
3458.568
40
4074.70470
-5
4047.3834
-31
16
17
3486.54476
-4
3457.5688
4
3486.60537
4
3457.567
-26
4075.36354
-5
4046.38750
-6
4060.73260
-5
17
18
3487.18768
-1
3456.5569
10
3487.25345
2
3456.5569
-4
4076.01246
2
4045.38149
-7
4060.58601
-1
18
19
3487.82027
0
3455.5347
2
3455.537
33
4076.65127
-3
4044.36558
-14
19
20
3488.44246
-7
3454.5022
-21
3488.51932
3
3454.506
-44
4077.28012
-4
4043.34002
-3
4060.2682
-17
20
21
3489.05441
-5
3453.4600
1
3489.13704
-1
3453.466
-27
4077.89898
-5
4042.30454
-2
4060.09745
9
21
22
3489.65611
3
3452.4074
-3
3489.74467
-2
3452.416
-16
4078.50787
-3
4041.25930
6
4059.91840
17
22
23
3490.24736
-2
3451.3447
-3
3490.34222
-1
3451.3562
8
4079.10673
-3
4040.20403
-8
4059.73090
-8
23
24
3490.82830
-5
3450.2719
0
3490.92963
-2
3450.2863
13
4079.69554
-8
4039.13916
-1
4059.53572
11
24
25
3491.39895
-4
3449.1889
-5
3491.50696
-1
3449.2064
10
4080.27448
1
4038.06429
-14
25
26
3491.95930
-1
3448.0963
42
3492.07412
-5
3448.11666
12
4080.84329
-3
4036.97898
0
4059.12052
-1
26
27
3492.50930
-0
3446.9933
59
3492.63127
-0
3447.01677
-12
4081.40211
-4
4035.88549
-7
4058.90095
11
27
28
3493.04901
4
3445.87947
3
3493.17826
-1
3445.90736
1
4034.78145
1
4058.67302
-2
28
29
3493.57836
6
3444.75613
5
3493.71518
2
3444.78792
-3
4033.66766
12
4058.43714
0
29
30
3494.0976
29
3443.62259
-4
3494.24195
-1
3443.65877
8
4032.54376
-11
4058.19318
3
30
31
3494.60603
4
3442.47913
2
3442.51944
-14
4031.41018
-25
4057.94112
5
31
32
*3495.10450
17
3441.32558
6
3495.26524
-1
3441.37066
3
*4084.04618
14
4030.26729
6
32
33
*3495.59263
28
3440.1620
13
3495.76183
7
3440.21183
-3
*4084.54504
28
4029.11441
14
4057.41277
10
33
34
*3496.07228
224
*3438.98828
11
*3496.24836
18
3439.0433
3
*4085.03574
229
*4027.95168
11
4057.13647
12
34
35
*3496.53710
-31
*3437.80472
29
*3496.72491
39
3437.86495
8
*4085.51186
-25
4026.77933
20
*4056.8526
64
35
36
*3496.99428
-16
*3436.61295
230
*3497.192
123
*4085.98064
-11
*4025.59914
218
*4056.55996
45
36
37
3497.44113
-2
*3435.4068
-8
*3497.64602
-93
*3435.47912
39
4086.43943
7
*4024.40474
-32
*4056.26105
206
37
38
3497.87750
-3
*3434.1927
-34
*3498.09258
-48
*3434.27300
200
4086.88798
4
*4023.20311
-33
38
39
3498.30354
-5
3432.96915
-7
*3498.52873
-37
*3433.05254
-98
4087.32654
5
4021.99196
-15
*4055.63305
-76
39
40
3498.71935
2
3431.73516
-24
*3498.9545
-58
*3431.82555
-74
4087.75504
3
4020.77093
-15
*4055.30902
-14
40
41
3499.12474
-1
3430.4914
-20
*3499.37077
-23
*3430.58932
-2
4019.54040
5
41
42
3499.51988
3
*3499.7767
-17
*3429.3425
-18
4088.58192
-4
4018.29995
1
*4054.63572
-3
42
43
3499.90465
2
3427.97426
17
3500.17265
-5
*3428.08612
-20
4017.04958
-26
*4054.2867
-31
43
44
3500.27916
6
3426.70042
2
*3426.82013
-14
4015.78996
-11
44
45
3500.64332
5
3425.41687
11
3500.9344
16
3425.54452
-4
4014.52061
-4
45
46
3500.99707
-5
3424.12322
3
*3501.30022
25
3424.25916
-2
4013.2413
-27
46
47
3501.34068
1
3422.81970
-0
*3501.65625
57
3422.96423
6
4011.95266
-18
47
48
3501.67392
-1
3421.50662
31
*3502.0021
71
*3421.65971
18
4010.65442
-6
*4052.0272
75
48
49
3501.99671
-17
3420.18310
9
*3502.33805
97
*3420.34568
39
49
50
3502.30956
1
3418.84972
-12
*3502.66405
126
*3419.02218
73
4008.02884
-6
50
51
3502.61215
23
3417.50686
7
*3502.98002
151
*3417.68892
88
51
52
3502.90398
-4
3416.15381
-7
*3503.2866
235
*3416.34620
114
52
53
3503.18584
-0
3414.79114
1
*3503.58354
352
*3414.99424
169
53
54
3503.45736
-3
3413.41840
-15
*3503.87088
504
*3413.63302
251
54
55
3503.71875
7
3412.03610
-5
*3504.1510
929
*3412.2627
374
55
56
3503.96982
12
*3504.42655
1891
*3410.88304
512
56
57
3504.21065
17
*3504.55976
-10388
57
58
3407.83004
-14
*3504.891
-1873
*3408.10612
1866
58
59
*3504.66168
38
*3505.13539
-1052
*3406.5750
-10308
59
60
*3504.8720
63
3404.97736
-3
*3505.36502
-718
*3405.2402
-1908
60
61
*3505.07245
124
*3403.5364
1
*3505.58310
-551
61
62
*3505.26262
178
62
63
*3505.44401
374
*3505.99184
-343
*3400.94181
-481
63
64
*3505.61777
827
*3399.1588
359
*3399.4860
-438
64
65
*3397.6791
363
*3506.35571
-199
65
66
*3505.8345
-8293
*3396.5474
-260
66
67
*3506.0289
-2724
*3394.70917
2207
3506.6792
-113
*3395.06326
-265
67
68
3506.8283
35
68
69
*3391.629
-3131
3506.9668
99
3392.068
-203
69
70
*3506.3984
-1302
3507.096
207
70
71
*3506.4953
-1430
*3388.5812
-1407
3389.0397
231
71
72
*3506.5849
-1278
*3387.0347
-1375
3387.508
66
72
73
*3506.6611
-1457
3507.4245
457
73
74
3506.7315
-1209
*3383.9134
-1294
3507.5143
509
3384.4244
448
74
75
3506.7820
-1945
3507.5952
637
75
O – C are the observed minus the computed frequencies in cm-1 × 105. Transitions denoted with asterisks are perturbed and were not included in the frequency analysis.
Table XIX
Observed Line Positions (cm-1) of the 0600–0000,0620(e)–0000, 0710–0110, and 0730–0110 Bands of 14N216O and the 0600–0000 Band of 15N14N16Oa
O – C are the observed minus the computed frequencies in cm-1 × 105.
δ is the difference between the observed frequency and the observed position of the transition of the perturbing band Values of δ are given in cm-1.
Table XX
Computed Line Positions (cm-1) of the 0002–0000 and 0002–1000 Bands of 14N216Oa
J
0002–0000 Band
0002–1000 Band
J
R Branch
O – C
P Branch
O – C
R Branch
O – C
P Branch
O – C
0
4418.20195
-1
3133.29861
19
0
1
4419.01232
-1
4416.53973
-3
3134.11249
-13
3131.63990
-0
1
2
4419.80887
-4
4415.68789
-2
3134.91606
-4
3130.79508
-8
2
3
4420.59158
-3
4414.82224
-3
3135.70930
-7
3129.93997
-3
3
4
4421.36045
-3
4413.94278
3136.49222
-5
3129.07455
3
4
5
4422.11547
-2
4413.04951
3137.26480
-1
3128.19884
-2
5
6
4422.85665
-4
4412.14244
3138.02705
-8
3127.31284
-1
6
7
4423.58399
-2
4411.22158
3138.77896
-7
3126.41655
-7
7
8
4424.29746
-2
4410.28693
3139.52052
5
3125.50999
-5
8
9
4424.99708
-1
4409.33849
3140.25173
2
3124.59314
-1
9
10
4425.68283
-0
4408.37626
2
3140.97259
0
3123.66602
-3
10
11
4426.35472
-2
4407.40026
3141.68309
-1
3122.72862
2
11
12
4427.01274
-1
4406.41048
3142.38322
-1
3121.78096
-3
12
13
4427.65689
0
4405.40694
3143.07299
0
3120.82304
2
13
14
4428.28715
-0
4404.38963
3143.75238
2
3119.85485
1
14
15
4428.90354
1
4403.35856
3144.42139
1
3118.87641
-7
15
16
4429.50604
0
4402.31373
-1
3145.08002
-8
3117.88771
2
16
17
4430.09465
-1
4401.25516
3
3145.72826
0
3116.88877
1
17
18
4430.66937
1
4400.18284
1
3146.36610
-9
3115.87957
18
19
4431.23019
1
4399.09677
5
3146.99355
0
3114.86013
1
19
20
4431.77711
1
4397.99697
1
3147.61059
-9
3113.83046
0
20
21
4432.31012
3
4396.88344
3148.21722
-6
3112.79054
1
21
22
4432.82923
2
4395.75619
4
3148.81343
2
3111.74039
-2
22
23
4433.33443
2
4394.61521
3
3149.39923
-4
3110.68000
20
23
24
4433.82572
1
4393.46051
3149.97459
5
3109.60939
5
24
25
4434.30308
3
4392.29210
4
3150.53953
2
3108.52854
0
25
26
4434.76653
2
4391.10998
3
3151.09402
3
3107.43748
-16
26
27
4435.21605
3
4389.91416
7
3151.63808
3
3106.33619
-1
27
28
4435.65164
2
4388.70465
3152.17168
2
3105.22468
28
29
4436.07330
2
4387.48144
3152.69482
10
3104.10296
8
29
30
4436.48103
0
4386.24454
5
3153.20750
11
3102.97102
30
31
4436.87481
-0
4384.99397
3153.70972
6
3101.82887
4
31
32
4437.25466
2
4383.72971
3154.20145
9
3100.67651
-11
32
33
4437.62056
1
4382.45178
2
3154.68271
11
3099.51394
33
34
4437.97251
1
4381.16019
3155.15348
9
3098.34116
-9
34
35
4438.31051
1
4379.85494
3155.61375
5
3097.15817
7
35
36
4438.63456
1
4378.53602
2
3156.06352
-16
3095.96498
36
37
4438.94465
0
4377.20346
3156.50278
3094.76158
-15
37
38
4439.24078
-3
4375.85725
3156.93152
6
3093.54800
0
38
39
4439.52294
0
4374.49740
3157.34974
10
3092.32421
9
39
40
4439.79114
-4
4373.12392
3
3157.75743
6
3091.09021
10
40
41
4440.04536
-4
4371.73680
3158.15458
-11
3089.84602
18
41
42
4440.28562
0
4370.33607
-7
3158.54118
-15
3088.59163
17
42
43
4440.51189
-8
4368.92171
-4
3158.91723
3087.32705
15
43
44
4440.72419
-0
4367.49374
-6
3159.28272
3086.05226
44
45
4440.92251
-5
4366.05216
0
3159.63763
3084.76728
45
46
4441.10681
-10
4364.59697
3159.98196
3083.47210
46
47
4441.27718
7
4363.12819
3160.31571
3082.16672
47
48
4441.43353
4361.64582
-1
3160.63886
3080.85115
48
49
4441.57589
4360.14987
3160.95140
3079.52537
49
50
4441.70425
-21
4358.64033
3161.25333
3078.18940
50
51
4441.81862
4357.11722
0
3161.54463
3076.84323
51
52
4441.91898
4355.58053
3161.82529
3075.48685
52
53
4442.00533
4354.03029
3162.09531
3074.12027
53
54
4442.07768
4352.46649
-4
3162.35468
3072.74349
54
55
4442.13602
4350.88913
-3
3162.60338
3071.35649
55
56
4442.18034
4349.29823
17
3162.84140
3069.95929
56
57
4442.21065
4347.69379
3163.06874
3068.55188
57
58
4442.22694
4346.07581
3163.28538
58
59
4442.22921
4344.44430
59
60
4442.21745
4342.79927
-10
60
61
4442.19167
4341.14073
61
62
4442.15186
4339.46867
33
62
63
4442.09802
4337.78311
63
64
4442.03015
4336.08404
17
64
65
4441.94824
4334.37149
65
66
4441.85229
4332.64544
66
67
4441.74230
4330.90592
67
68
4441.61826
4329.15292
-23
68
69
4441.48018
4327.38645
69
70
4441.32805
4325.60651
70
71
4441.16187
4323.81312
71
72
4440.98163
4322.00628
72
73
4440.78735
4320.18599
73
74
4440.57900
4318.35226
74
O – C are the observed minus the computed frequencies in cm-1 × 105.
Table XXI
Computed Line Positions (cm-1) of the 1201–0000 and 1201–0200 Bands of N216Oa
O – C are the observed minus the computed frequencies in cm−1 × 105. Transitions denoted by asterisks are perturbed and measured frequencies of these were not included in the analysis.
From Ref. 10. Values given within parentheses are their quoted uncertainties (in the last digits) in the computed values.