Table I
Vibrational Oscillator Strength Sources
System Source O Schumann–Runge R. W. Nicholls, Can. J. Phys. 38, 1705 (1960) NO gamma D. J. Flinn, R. J. Spindler, S. Fifer, and M. Kelly, J. Quant. Spectry. Radiative Transfer 4, 271 (1964) NO beta D. J. Flinn, R. J. Spindler, S. Fifer, and M. Kelly, J. Quant. Spectry. Radiative Transfer 4, 271 (1964) NO delta H. A. Ory, J. Chem. Phys. 40, 562 (1964) NO epsilon H. A. Ory, J. Chem. Phys. 40, 562 (1964) N2 first positive R. W. Nicholls, J. Res. Natl. Bur. Std. 65A, 451 (1961) N2 second positive R. W. Nicholls, J. Res. Natl. Bur. Std. 65A, 451 (1961) N2 birge hopfield 2 R. W. Nicholls, J. Quant. Spectry. Radiative Transfer 2, 433 (1962) N2 + first negative R. W. Nicholls, J. Res. Natl. Bur. Std. 65A, 451 (1961)
Table II
Electronic Oscillator Strengths
System f valueSource O2 Schumann–Runge 0.21 D. W. O. Heddle, J. Chem. Phys. 32, 1889 (1960) NO gamma 0.0025 G. W. Bethke, J. Chem. Phys. 31, 662 (1959) NO beta 0.0024 H. A. Ory, J. Chem. Phys. 40, 562 (1964) NO delta 0.0167 H. A. Ory, J. Chem. Phys. 40, 562 (1964) NO epsilon 0.0141 H. A. Ory, J. Chem. Phys. 40, 562 (1964) N2 first, positive 0.0027 W. H. Wurster, J. Chem. Phys. 36, (1962) N2 second positive 0.057 V. H. Reis, J. Quant. Spectry. Radiative Transfer 4, 783 (1964) N2 Birge Hopfield 2 0.22 Computed from K. L. Wray and J. D. Teare, J. Chem. Phys. 36, 2582 (1962) N2 + first negative 0.35 R. G. Bennett and F. W. Dalby, J. Chem. Phys. 36, 399 (1962)
Table III
Van der Waals Constants for the O2 B Statea
v NO N2 + N2 O2 0 −110 −83 −68 1 −119 −85 −70 2 −97 −82 −66 3 −81 −79 −62 4 −81 −80 −63 5 −74 −79 −61 6 −72 −79 −61 7 −69 −79 −61 8 −66 −79 −61 9 −62 −69 −56 10 −64 −79 −61 11 −62 −69 −60 12 −62 −79 −60
a All numbers should be multiplied by 10
−60 .
Table IV
Van der Waals Constants for the NO A Statea
v NO N2 + O2 0 −72 −50 −46 1 −76 −52 −47 2 −80 −54 −49 3 −85 −57 −51 4 −90 −59 −53 5 −96 −62 −56 6 −103 −66 −59 7 −111 −69 −62 8 −121 −74 −65 9 −133 −79 −70 10 −149 −86 −75 11 −170 −94 −82 12 −200 −106 −92
a All numbers should be multiplied by 10
−60 .
Table V
Van der Waals Constants for the NO B Statea
v N 2 + N2 O2 0 −74 −51 −47 1 −76 −52 −48 2 −78 −53 −48 3 −79 −54 −49 4 −81 −55 −50 5 −83 −56 −51 6 −85 −57 −52 7 −87 −58 −53 8 −89 −59 −54 9 −91 −60 −54 10 −94 −61 −55 11 −97 −63 −56 12 −99 −64 −57
a All numbers should be multiplied by 10
−60 .
Table VI
Van der Waals Constants for the N2 A Statea
v NO N2 + N2 O2 0 −43 −70 −52 −48 1 −44 −72 −53 −49 2 −45 −73 −54 −50 3 −45 −75 −55 −51 4 −45 −77 −56 −51 5 −56 −78 −57 −52 6 −47 −80 −58 −53 7 −47 −82 −59 −54 8 −47 −83 −60 −55 9 −48 −85 −61 −55 10 −49 −87 −62 −56 11 −49 −89 −63 −57 12 −50 −90 −64 −58
a All numbers should be multiplied by 10
−60 .
Table VII
Van der Waals Constants for the N2 B Statea
v NO N2 + N2 O2 0 −67 −85 −64 −59 1 −69 −88 −65 −60 2 −69 −90 −67 −62 3 −69 −93 −68 −63 4 −69 −95 −69 −64 5 −57 −96 −67 −61 6 −57 −98 −69 −63 7 −58 −101 −70 −64 8 −58 −104 −72 −65 9 −59 −107 −73 −67 10 −60 −110 −75 −68 11 −61 −114 −77 −70 12 −62 −117 −79 −71
a All numbers should be multiplied by 10
−60 .
Table VIII
Van der Waals Constants for the N2 C Statea
v NO N2 + N2 O2 0 −95 −157 −102 −92 1 −98 −166 −107 −96 2 −101 −175 −111 −99 3 −105 −185 −116 −104 4 −109 −197 −122 −108 5 −92 −205 −123 −108 6 −97 −220 −130 −114 7 −103 −237 −140 −121 8 −110 −258 −148 −129 9 −117 −281 −159 −137 10 −126 −310 −171 −148 11 −138 −346 −186 −161 12 −152 −393 −206 −177
a All numbers should be multiplied by 10
−60 .
Table IX
Van der Waals Constants for the N2 + B Statea
v NO N2 O2 0 −166 −60 −59 1 −167 −62 −60 2 −166 −62 −61 3 −171 −64 −62 4 −171 −65 −63 5 −168 −66 −63 6 −152 −64 −61 7 −145 −62 −59 8 −123 −59 −55 9 −116 −58 −55 10 −118 −61 −56 11 −110 −60 −56 12 −94 −58 −53
a All numbers should be multiplied by 10
−60 .
Table X
Van der Waals Constants for the NO X Statea
v N2 + N2 O2 0 −38 −31 −29 1 −39 −31 −19 2 −39 −31 −30 3 −40 −32 −30 4 −41 −32 −31 5 −42 −33 −31 6 −43 −33 −31 7 −43 −34 −32 8 −44 −34 −32 9 −45 −35 −33 10 −46 −35 −33 11 −48 −36 −34 12 −49 −37 −34
a All numbers should be multiplied by 10
−60 .
Table XI
Van der Waals Constants for the O2 X Statea
v NO N2 + N2 O2 0 −69 −47 −43 −42 1 −74 −48 −45 −44 2 −60 −47 −42 −41 3 −50 −46 −40 −38 4 −50 −46 −40 −39 5 −45 −46 −39 −38 6 −45 −46 −39 −38 7 −43 −47 −39 −38 8 −41 −47 −39 −38 9 −41 −47 −40 −38 10 −40 −48 −40 −38 11 −39 −48 −40 −38 12 −39 −49 −40 −39
a All numbers should be multiplied by 10
−60 .
Table XII
Van der Waals Constants for the N2 − X Statea
v NO N2 + N2 O2 0 −122 −44 −45 −45 1 −122 −45 −45 −45 2 −120 −45 −45 −45 3 −120 −46 −46 −46 4 −119 −47 −46 −46 5 −116 −47 −46 −46 6 −105 −46 −44 −44 7 −94 −45 −42 −41 8 −80 −44 −39 −37 9 −75 −44 −38 −36 10 −76 −45 −39 −37 11 −68 −45 −38 −36 12 −56 −44 −35 −33
a All numbers should be multiplied by 10
−60 .
Table XIII
Half-Widths in the N2 First Positive System. Temperature 8000°K. Relative Density 10. Units are sec−1 . Numbers Should be Multiplied by 1010
v
v ′0 1 2 3 4 5 6 7 8 9 10 11 12 0 4.61 4.46 4.30 4.14 3.98 3.79 3.58 3.37 3.12 2.83 2.47 1.99 0.49 1 4.76 4.61 4.47 4.32 4.16 3.99 3.80 3.60 3.39 3.13 2.84 2.49 2.00 2 5.00 4.87 4.74 4.61 4.47 4.31 4.15 3.98 3.80 3.60 3.37 3.12 2.83 3 5.12 4.99 4.86 4.74 4.61 4.46 4.30 4.15 3.98 3.79 3.59 3.37 3.11 4 5.23 5.11 4.99 4.86 4.74 4.60 4.45 4.30 4.15 3.97 3.78 3.59 3.36 5 4.88 4.74 4.60 4.47 4.33 4.17 4.00 3.84 3.66 3.45 3.21 2.97 2.66 6 5.11 4.98 4.85 4.73 4.61 4.46 4.31 4.16 4.00 3.82 3.62 3.43 3.19 7 5.23 5.11 4.98 4.87 4.75 4.61 4.46 4.32 4.17 4.00 3.82 3.64 3.43 8 5.43 5.32 5.20 5.09 4.98 4.85 4.72 4.59 4.46 4.31 4.14 3.99 3.80 9 5.54 5.43 5.32 5.21 5.11 4.98 4.85 4.73 4.61 4.46 4.31 4.16 3.99 10 5.74 5.64 5.53 5.43 5.33 5.21 5.09 4.98 4.87 4.73 4.59 4.46 4.31 11 5.93 5.83 5.73 5.64 5.54 5.43 5.32 5.21 5.11 4.98 4.85 4.73 4.59 12 6.11 6.02 5.92 5.83 5.74 5.64 5.53 5.43 5.33 5.21 5.09 4.98 4.85
Table XIV
Half-Widths in the O2 Schumann–Runge System. Temperature 8000°K. Relative Density 10. Units are sec−1 . Numbers Should be Multiplied by 1010
v
v ′0 1 2 3 4 5 6 7 8 9 10 11 12 0 6.07 5.86 6.22 6.44 6.44 6.54 6.54 6.55 6.56 6.48 6.49 6.49 6.49 1 6.30 6.10 6.43 6.64 6.64 6.74 6.74 6.75 6.76 6.68 6.69 6.69 6.69 2 5.80 5.57 5.96 6.20 6.20 6.31 6.31 6.32 6.33 6.25 6.25 6.26 6.26 3 5.25 4.96 5.45 5.73 5.73 5.86 5.86 5.88 5.89 5.80 5.80 5.81 5.81 4 5.35 5.07 5.55 5.83 5.83 5.95 5.95 5.97 5.98 5.89 5.90 5.90 5.90 5 5.02 4.52 5.28 5.58 5.58 5.72 5.72 5.73 5.75 5.65 5.66 5.67 5.67 6 4.97 4.72 5.25 5.56 5.56 5.70 5.70 5.72 5.73 5.64 5.65 5.65 5.65 7 4.73 4.81 5.21 5.53 5.53 5.67 5.67 5.69 5.71 5.61 5.62 5.63 5.63 8 4.97 4.87 5.15 5.50 5.50 5.65 5.65 5.67 5.68 5.59 5.60 5.61 5.61 9 4.49 4.30 4.48 4.93 4.94 5.10 5.10 5.12 5.14 5.03 5.04 5.05 5.05 10 5.02 4.90 5.10 5.47 5.47 5.63 5.63 5.65 5.67 5.57 5.58 5.59 5.59 11 4.96 4.81 4.94 5.35 5.35 5.51 5.51 5.53 5.55 5.45 5.46 5.47 5.47 12 4.96 4.81 4.94 5.35 5.35 5.51 5.51 5.53 5.55 5.45 5.46 5.47 5.47
Table XV
Half-Widths in the N2 Second Positive System. Temperature 8000°K. Relative Density 10. Units are sec−1 . Numbers Should be Multiplied by 1010
v
v ′0 1 2 3 4 5 6 7 8 9 10 11 12 0 7.02 6.93 6.79 6.72 6.65 6.89 6.74 6.66 6.51 6.42 6.25 6.07 5.89 1 7.37 7.29 7.16 7.10 7.03 7.25 7.12 7.04 6.90 6.82 6.67 6.51 6.34 2 7.64 7.56 7.44 7.38 7.31 7.52 7.40 7.33 7.20 7.12 6.98 6.83 6.67 3 7.96 7.89 7.77 7.71 7.65 7.85 7.73 7.67 7.54 7.47 7.34 7.20 7.06 4 8.31 8.24 8.14 8.08 8.03 8.21 8.10 8.04 7.92 7.86 7.74 7.61 7.48 5 8.23 8.16 8.06 8.00 7.95 8.15 8.05 7.98 7.87 7.81 7.68 7.55 7.42 6 8.63 8.56 8.46 8.41 8.36 8.55 8.45 8.39 8.29 8.23 8.11 8.00 7.88 7 9.14 9.08 8.99 8.94 8.90 9.07 8.98 8.92 8.83 8.77 8.67 8.56 8.46 8 9.53 9.48 9.39 9.35 9.31 9.47 9.38 9.33 9.24 9.19 9.09 9.00 8.90 9 10.00 9.97 9.89 9.85 9.81 9.96 9.88 9.83 9.75 9.70 9.62 9.53 9.43 10 10.50 10.40 10.40 10.30 10.30 10.40 10.40 10.30 10.20 10.20 10.10 10.00 9.99 11 11.10 11.00 11.00 10.90 10.90 11.00 10.90 10.90 10.80 10.80 10.70 10.60 10.60 12 11.80 11.80 11.70 11.60 11.60 11.70 11.70 11.60 11.60 11.50 11.50 11.40 11.30
Table XVI
Half-Widths in the NO Gamma System. Temperature 8000°K. Relative Density 10. Units are sec−1 . Numbers Should be Multiplied by 1010
v
v ′0 1 2 3 4 5 6 7 8 9 10 11 12 0 4.88 4.88 4.88 4.78 4.77 4.67 4.67 4.56 4.56 4.44 4.44 4.32 4.19 1 5.08 5.08 5.08 4.98 4.98 4.88 4.88 4.77 4.77 4.67 4.67 4.55 4.44 2 5.27 5.27 5.27 5.17 5.17 5.08 5.08 4.98 4.98 4.88 4.88 4.77 4.67 3 5.53 5.53 5.53 5.45 5.45 5.36 5.36 5.27 5.27 5.17 5.17 4.08 4.98 4 5.70 5.70 5.70 5.62 5.62 5.53 5.53 5.45 5.45 5.36 5.36 5.27 5.17 5 5.94 5.94 5.94 5.86 5.86 5.78 5.78 5.70 5.70 5.62 5.62 5.53 5.45 6 6.23 6.23 6.23 6.16 6.16 6.09 6.09 6.01 6.01 5.94 5.94 5.86 5.78 7 6.44 6.44 6.44 6.37 6.37 6.30 6.30 6.23 6.23 6.16 6.16 6.09 6.01 8 6.77 6.77 6.77 6.70 6.70 6.64 6.64 6.57 6.57 6.51 6.51 6.44 6.37 9 7.07 7.07 7.07 7.01 7.01 6.95 6.95 6.89 6.89 6.83 6.83 6.77 6.70 10 7.47 7.47 7.47 7.41 7.41 7.36 7.36 7.30 7.30 7.24 7.24 7.19 7.13 11 7.88 7.88 7.88 7.83 7.83 7.78 7.78 7.73 7.73 7.68 7.68 7.63 7.57 12 8.45 8.45 8.45 8.41 8.41 8.36 8.36 8.32 8.32 8.27 8.27 8.22 8.18
Table XVII
Half-Widths in the NO Beta System. Temperature 8000°K. Relative Density 10. Units are sec−1 . Numbers Should be Multiplied by 1010
v
v ′0 1 2 3 4 5 6 7 8 9 10 11 12 0 4.98 4.9 4.98 4.88 4.88 4.78 4.78 4.67 4.67 4.56 4.56 4.44 4.32 1 5.08 5.08 5.08 4.98 4.98 4.88 4.88 4.78 4.78 4.67 4.67 4.56 4.44 2 5.17 5.17 5.17 5.03 5.08 4.98 4.98 4.88 4.88 4.77 4.77 4.67 4.56 3 5.27 5.27 5.27 5.17 5.17 5.08 5.08 4.98 4.98 4.88 4.88 4.77 4.67 4 5.36 5.36 5.36 5.27 5.27 5.17 5.17 5.08 5.08 4.98 4.98 4.88 4.78 5 5.45 5.45 5.45 5.36 5.36 5.27 5.27 5.17 5.17 5.08 5.08 4.98 4.88 6 5.53 5.53 5.53 5.45 5.45 5.36 5.36 5.27 5.27 5.17 5.17 5.08 4.98 7 5.62 5.62 5.62 5.53 5.53 5.45 5.45 5.36 5.36 5.27 5.27 5.17 5.08 8 5.70 5.70 5.70 5.62 5.62 5.53 5.53 5.45 5.45 5.36 5.36 5.27 5.18 9 5.78 5.78 5.78 5.70 5.70 5.62 5.62 5.53 5.53 5.45 5.45 5.36 5.27 10 5.86 5.86 5.86 5.78 5.78 5.70 5.70 5.62 5.62 5.53 5.53 5.45 5.36 11 6.01 6.01 6.01 5.94 5.93 5.86 5.86 5.78 5.78 5.70 5.70 5.62 5.53 12 6.09 6.09 6.09 6.01 6.01 5.94 5.94 5.86 5.86 5.78 5.78 5.70 5.62
Table XVIII
Half-Widths in the N2 First Negative System. Temperature 8000°K. Relative Density 10. Units are sec−1 . Numbers Should be Multiplied by 1010
v
v ′0 1 2 3 4 5 6 7 8 9 10 11 12 0 5.13 5.13 5.15 5.03 5.03 5.05 5.35 5.62 5.99 6.11 6.01 6.13 6.45 1 5.37 5.37 5.38 5.27 5.27 5.29 5.57 5.83 6.18 6.29 6.20 6.32 6.63 2 5.36 5.36 5.38 5.26 5.27 5.29 5.57 5.83 6.18 6.29 6.20 6.32 6.62 3 5.61 5.61 5.62 5.51 5.52 5.53 5.80 6.05 6.38 6.48 6.39 6.51 6.80 4 5.71 5.71 5.72 5.62 5.62 5.64 5.90 6.14 6.46 6.57 6.48 6.60 6.88 5 5.79 5.79 5.80 5.70 5.71 5.72 5.98 6.21 6.54 6.64 6.55 6.67 6.95 6 5.47 5.47 5.49 5.39 5.39 5.42 5.69 5.95 6.29 6.40 6.31 6.43 6.73 7 5.20 5.20 5.22 5.11 5.12 5.14 5.44 5.72 6.08 6.20 6.10 6.23 6.54 8 4.47 4.47 4.55 4.43 4.45 4.52 4.92 5.25 5.67 5.80 5.69 5.84 6.18 9 4.50 4.50 4.46 4.32 4.29 4.06 4.72 5.08 5.52 5.66 5.55 5.70 6.06 10 4.82 4.82 4.75 4.64 4.59 4.64 5.09 5.42 5.83 5.96 5.86 6.00 6.83 11 4.85 4.85 4.82 4.70 4.68 4.63 4.84 5.24 5.68 5.81 5.71 5.86 6.20 12 4.77 4.77 4.75 4.62 4.61 4.58 4.71 4.55 5.32 5.48 5.36 5.54 5.92
Table XIX
Half-Widths in the N2 First Positive System. Temperature 8000°K. Relative Density 10−1 . Units are sec−1 . Numbers Should be Multiplied by 108
v
v ′0 1 2 3 4 5 6 7 8 9 10 11 12 0 1.87 1.81 1.74 1.67 1.59 1.51 1.42 1.33 1.22 1.09 0.93 0.72 0.04 1 1.93 1.87 1.81 1.74 1.67 1.59 1.51 1.42 1.33 1.22 1.09 0.94 0.72 2 2.04 1.99 1.93 1.87 1.81 1.74 1.67 1.59 1.51 1.42 1.33 1.22 1.09 3 2.09 2.04 1.99 1.93 1.87 1.81 1.74 1.67 1.59 1.51 1.42 1.33 1.21 2 2.14 2.09 2.04 1.99 1.93 1.87 1.81 1.74 1.67 1.59 1.51 1.42 1.32 5 2.03 1.98 1.92 1.86 1.80 1.73 1.66 1.58 1.50 1.41 1.31 1.20 1.07 6 2.13 2.08 2.03 1.97 1.92 1.86 1.79 1.73 1.66 1.58 1.50 1.41 1.31 7 2.18 2.13 2.08 2.03 1.98 1.92 1.86 1.79 1.73 1.66 1.58 1.50 1.41 8 2.28 2.23 2.18 2.13 2.08 2.03 1.97 1.92 1.86 1.79 1.73 1.66 1.58 9 2.32 2.28 2.23 2.18 2.13 2.08 2.03 1.97 1.92 1.86 1.79 1.73 1.66 10 2.41 2.36 2.32 2.28 2.23 2.18 2.13 2.08 2.03 1.97 1.92 1.86 1.79 11 2.49 2.45 2.41 2.36 2.32 2.28 2.23 2.18 2.13 2.08 2.03 1.97 1.92 12 2.57 2.53 2.49 2.45 2.41 2.36 2.32 2.28 2.23 2.18 2.13 2.08 2.03