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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 38,
  • Issue 6,
  • pp. 857-860
  • (1984)

Raman and Resonance Raman Spectroscopy of Selected Rare-Earth Sesquioxides

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Abstract

Raman spectra of three readily available C-type stoichiometric rare-earth sesquioxide powders of composition Ln<sub>2</sub>O<sub>3</sub> are presented. Some correlations of spectra with body-cell structure and infrared absorption spectra have been made. Spectra of Eu<sub>2</sub>O<sub>3</sub>, Dy<sub>2</sub>O<sub>3</sub>, and Tm<sub>2</sub>O<sub>3</sub> display several new peaks that have not as yet been reported. Assignments of certain peaks to electronic Raman and resonance Raman transitions are discussed.

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