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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 22,
  • Issue 1,
  • pp. 58-60
  • (1968)

Use of Alkyl-Bending Vibration Frequencies as an Aid in the Characterization of Alkyladamantane Structures

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Abstract

We have previously shown that bridgehead-substituted methyl and ethyl adamantanes can be characterized and identified using a combination of infrared and nuclear-magnetic-resonance (NMR) spectroscopy and mass spectrometry. Although NMR is the most useful diagnostic tool in alkyladamantane structural determinations, the infrared spectra exhibit certain diagnostically useful medium-intensity absorption bands in the 1338–1385-cm<sup>−1</sup> region.

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