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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 23,
  • Issue 1,
  • pp. 12-16
  • (1969)

Vibrational Spectra of Triphenyl Compounds of Group VA Elements

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Abstract

The infrared and Raman spectra of triphenyl compounds of Group VA elements PPh<sub>3</sub>, AsPh<sub>3</sub>, SbPh<sub>3</sub>, and BiPh<sub>3</sub> (Ph represents the phenyl group), have been reported in the 530–100 cm<sup>−1</sup> region. The metal–phenyl stretching and bending vibrations have been assigned with the aid of approximate normal coordinate analysis and depolarization ratios of Raman lines.

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