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Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 28,
  • Issue 5,
  • pp. 427-430
  • (1974)

Infrared Spectra of Trimethylamine-Carbon Monoxide-Borane and Its Deuterated Derivatives

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Abstract

Low temperature infrared spectral data are given for the adducts H<sub>3</sub>BC(O)N(CH<sub>3</sub>)<sub>3</sub>, D<sub>3</sub>BC(O)N(CH<sub>3</sub>)<sub>3</sub>, H<sub>3</sub>BC(O)N(CD<sub>3</sub>)<sub>3</sub>, D<sub>3</sub>BC(O)N(CD<sub>3</sub>)<sub>3</sub> over the range 3000 to 300 cm<sup>−1</sup>. Boron-11 NMR data are given for H<sub>3</sub>BCO and H<sub>3</sub>BC(O)N(CH<sub>3</sub>)<sub>3</sub>. The spectra allow the assignment of the structure of the adducts as (CH<sub>3</sub>)<sub>3</sub>N→C=O→BH<sub>3</sub>.

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