Expand this Topic clickable element to expand a topic
Skip to content
Optica Publishing Group
  • Applied Spectroscopy
  • Vol. 34,
  • Issue 3,
  • pp. 327-331
  • (1980)

Laser Raman Spectra and Normal Coordinate Analysis of Some Uranyl Tetrachloride Complexes

Not Accessible

Your library or personal account may give you access


Laser Raman spectra of uranyl tetrachloride complexes [K<sub>2</sub>UO<sub>2</sub>Cl<sub>4</sub>, Rb<sub>2</sub>UO<sub>2</sub>Cl<sub>4</sub>, (Cs<sub>2</sub>UO<sub>2</sub>Cl<sub>4</sub>, (NH<sub>4</sub>)<sub>2</sub>UO<sub>2</sub>Cl<sub>4</sub>] have been measured in the region from 3500 to 10 cm<sup>−1</sup>. Vibrational assignments as well as normal coordinate analyses have been carried out with the assumption that all the complexes contain discrete (UO<sub>2</sub>Cl<sub>4</sub>)<sup>2-</sup> ions belonging to a point group D<sub>4h</sub>. To understand the nature of the uranyl bonds in the complexes, approximate π-bonding energies of such bonds have been estimated from the U—O stretching force constants. The reliability of the values obtained are discussed in detail on the basis of Mulliken's magic formula.

PDF Article
More Like This
Laser-induced fluorescence of uranyl complexes in aqueous solutions: the role of diffusion-controlled excited states annihilation

Gleb Budylin, Evgeny Shirshin, Victor Fadeev, Vladimir Petrov, and Stepan Kalmykov
Opt. Express 21(18) 20517-20528 (2013)

Some complex spectra of simple atoms

W. R. S. Garton and J.-P. Connerade
J. Opt. Soc. Am. B 5(10) 2119-2124 (1988)

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an Optica member, or as an authorized user of your institution.

Contact your librarian or system administrator
Login to access Optica Member Subscription

Select as filters

Select Topics Cancel
© Copyright 2024 | Optica Publishing Group. All rights reserved, including rights for text and data mining and training of artificial technologies or similar technologies.